General Information
Version
6.11
Revision date
2024-09-07
Product name
Bromomethane-d3
CAS No.
1111-88-2
1.2.1 Relevant identified uses
Laboratory chemicals, Synthesis of substances
1.2.2. Uses advised against
The product is being supplied under the TSCA R&D Exemption
Emergency telephone
800-424-9300, +1-703- 527-3887
Icons in SDS
Company Information
company name
Sigma-Aldrich Inc
GHS Information
Signal word
Warning
Hazard Codes
Hazard statements (CLP)
H221, H280, H315, H319, H335, H341, H373, H400, H411, H420
Hazard statements
Code
Statements
H221
Flammable gas
Section 2
SECTION 2: Hazards identification
Classification of the substance or mixture
Signal word
Warning
Hazard statements
H221 Flammable gas. H280 Contains gas under pressure; may explode if heated. H315 Causes skin irritation. H319 Causes serious eye irritation. H335 May cause respiratory irritation. H341 Suspected of causing genetic defects. H373 May cause damage to organs (Central nervous system) through prolonged or repeated exposure. H400 Very toxic to aquatic life. H411 Toxic to aquatic life with long lasting effects. H420 Harms public health and the environment by destroying ozone in the upper atmosphere.
Precautionary statements
P201 Obtain special instructions before use. P202 Do not handle until all safety precautions have been read and understood. P210 Keep away from heat/ sparks/ open flames/ hot surfaces. No smoking. P260 Do not breathe gas. P264 Wash skin thoroughly after handling. P271 Use only outdoors or in a well-ventilated area. P273 Avoid release to the environment. P280 Wear protective gloves/ protective clothing/ eye protection/ face protection. P302 + P352 IF ON SKIN: Wash with plenty of soap and water. P304 + P340 + P312 IF INHALED: Remove person to fresh air and keep comfortable for breathing. Call a POISON CENTER/ doctor if you feel unwell. P305 + P351 + P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P308 + P313 IF exposed or concerned: Get medical advice/ attention. P332 + P313 If skin irritation occurs: Get medical advice/ attention. P337 + P313 If eye irritation persists: Get medical advice/ attention. P362 Take off contaminated clothing and wash before reuse. P377 Leaking gas fire: Do not extinguish, unless leak can be stopped safely. P381 Eliminate all ignition sources if safe to do so. P391 Collect spillage. P403 + P233 Store in a well-ventilated place. Keep container tightly closed. P405 Store locked up. P410 + P403 Protect from sunlight. Store in a well-ventilated place. P501 Dispose of contents/ container to an approved waste disposal plant. P502 Refer to manufacturer/ supplier for information on recovery/ recycling.
2.3 Other hazards
- none
2.1 Classification of the substance or mixture
GHS Classification in accordance with 29 CFR 1910 (OSHA HCS) Flammable gases (Category 2), H221 Gases under pressure (Liquefied gas), H280 Skin irritation (Category 2), H315 Eye irritation (Category 2A), H319 Germ cell mutagenicity (Category 2), H341 Specific target organ toxicity - single exposure (Category 3), Respiratory system, H335 Specific target organ toxicity - repeated exposure (Category 2), Central nervous system, H373 Short-term (acute) aquatic hazard (Category 1), H400 Long-term (chronic) aquatic hazard (Category 2), H411 Hazardous to the ozone layer (Category 1), H420 For the full text of the H-Statements mentioned in this Section, see Section 16.