Note: Ingredients listed on restricted chemical lists
EC/CAS
67-56-1
Name of the chemical
Methanol
Concentration
>=80-<=100
General Information
Version
6.9
Revision date
2025-05-20
Product name
Boron trifluoride methanol complex solution
1.2.1 Relevant identified uses
Laboratory chemicals, Synthesis of substances
1.2.2. Uses advised against
The product is being supplied under the TSCA R&D Exemption
Emergency telephone
800-424-9300, +1-703- 527-3887
Icons in SDS
Company Information
company name
Sigma-Aldrich Inc
GHS Information
Signal word
Danger
Hazard Codes
Hazard statements (CLP)
H225, H301+H311, H314, H330, H370, H373
Hazard statements
Code
Statements
H225
Highly Flammable liquid and vapour
Section 2
SECTION 2: Hazards identification
Other hazards
Strong hydrogen fluoride-releaser
Signal word
Danger
Hazard statements
H225 Highly flammable liquid and vapour. H301 + H311 Toxic if swallowed or in contact with skin. H314 Causes severe skin burns and eye damage. H330 Fatal if inhaled. H370 Causes damage to organs (Eyes, Central nervous system). H373 May cause damage to organs (Kidney) through prolonged or repeated exposure if inhaled.
Supplemental label elements
Corrosive to the respiratory tract.
Prevention
P210 Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking. P233 Keep container tightly closed. P240 Ground and bond container and receiving equipment. P241 Use explosion-proof electrical/ ventilating/ lighting P242 Use non-sparking tools. P243 Take action to prevent static discharges. P260 Do not breathe mist or vapours. P264 Wash skin thoroughly after handling. P270 Do not eat, drink or smoke when using this product. P271 Use only outdoors or in a well-ventilated area. P280 Wear protective gloves, protective clothing, eye protection and face protection. P284 Wear respiratory protection.
Response
P301 + P310 + P330 IF SWALLOWED: Immediately call a POISON CENTER/ doctor. Rinse mouth. P301 + P330 + P331 IF SWALLOWED: Rinse mouth. Do NOT induce vomiting. P303 + P361 + P353 IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water/ shower. P304 + P340 + P310 IF INHALED: Remove person to fresh air and keep comfortable for breathing. Immediately call a POISON CENTER/ doctor. P305 + P351 + P338 + P310 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Immediately call a POISON CENTER/ doctor. P314 Get medical advice/ attention if you feel unwell. P361 + P364 Take off immediately all contaminated clothing and wash it before reuse. P370 + P378 In case of fire: Use dry sand, dry chemical or alcohol-resistant foam to extinguish.
Storage
P403 + P233 Store in a well-ventilated place. Keep container tightly closed. P403 + P235 Store in a well-ventilated place. Keep cool. P405 Store locked up.
Disposal
P501 Dispose of contents/ container to an approved waste disposal plant.
2.1 Classification of the substance or mixture
(29 CFR 1910.1200) Flammable liquids : Category 2 Acute toxicity (Oral) : Category 3 Acute toxicity : Category 2 (Inhalation) Acute toxicity (Dermal) : Category 3 Skin corrosion : Sub-category 1A Serious eye damage : Category 1 Specific target organ : Category 1 (Eyes, Central nervous system) toxicity - single exposure Specific target organ : Category 2 (Kidney) toxicity - repeated exposure (Inhalation) Other hazards Strong hydrogen fluoride-releaser