Boron trichloride solution

Sigma-Aldrich Inc

Revision date : 2026-01-02

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GHS02 GHS06 GHS08 GHS05
Health risk rating 5
Safety risk rating 4
Environmental risk rating 1

Note: Ingredients listed on restricted chemical lists

EC/CAS

200-659-6/67-56-1

Name of the chemical

Methanol

Concentration

>=70-<90 603-001- >=10% 3-<10%

General Information

Version

7.6

Revision date

2026-01-02

Product name

Boron trichloride solution

REACH No

This

Emergency telephone

800-424-9300, +1-703- 527-3887

Icons in SDS

GHS02 GHS05 GHS06 GHS08 M004 M010 M011 M017

Company Information

company name

Sigma-Aldrich Inc

GHS Information

Signal word

Danger

Hazard Codes

Hazard statements (CLP)

H225, H300, H311, H311+H331, H314, H318, H331, H360FD, H370

Hazard statements

Code

Statements

H225

Highly Flammable liquid and vapour

Section 2

SECTION 2: Hazards identification

Regulation (EC) No. 1272/2008 Classification of the substance or mixture

Signal word

Danger Danger

Hazard statements

H225 Highly flammable liquid and vapour. H300 Fatal if swallowed. H311 + H331 Toxic in contact with skin or if inhaled. H314 Causes severe skin burns and eye damage. H360FD May damage fertility. May damage the unborn child. H370 Causes damage to organs (Eyes, Central nervous system). H300 Fatal if swallowed. H370 Causes damage to organs. H314 Causes severe skin burns and eye damage. H360FD May damage fertility. May damage the unborn child. H311 + H331 Toxic in contact with skin or if inhaled.

Supplemental label elements

EUH014 Reacts violently with water. EUH014 Reacts violently with water.

Precautionary statements

P201 Obtain special instructions before use. P210 Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking. P280 Wear protective gloves/ protective clothing/ eye protection/ face protection. P201 Obtain special instructions before use. P280 Wear protective gloves/ protective clothing/ eye protection/ face protection. P303 + P361 + P353 IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water. P304 + P340 + P310 IF INHALED: Remove person to fresh air and keep comfortable for breathing. Immediately call a POISON CENTER/ doctor. P305 + P351 + P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.

Response

P303 + P361 + P353 IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water. P304 + P340 + P310 IF INHALED: Remove person to fresh air and keep comfortable for breathing. Immediately call a POISON CENTER/ doctor. P305 + P351 + P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.

Hazardous Ingredients

Methanol Boron chloride Reduced Labelling (<= 125 ml)

2.3 Other hazards

This substance/mixture contains no components considered to be either persistent, bioaccumulative and toxic (PBT), or very persistent and very bioaccumulative (vPvB) at levels of 0.1% or higher.

ECOLOGICAL INFORMATION

The substance/mixture does not contain components considered to have endocrine disrupting properties according to REACH Article 57(f) or Commission Delegated regulation (EU) 2017/2100 or Commission Regulation (EU) 2018/605 at levels of 0.1% or higher.

TOXICOLOGICAL INFORMATION

The substance/mixture does not contain components considered to have endocrine disrupting properties according to REACH Article 57(f) or Commission Delegated regulation (EU) 2017/2100 or Commission Regulation (EU) 2018/605 at levels of 0.1% or higher.

2.1 Classification of the substance or mixture

Classification (REGULATION (EC) No 1272/2008) Flammable liquids, Category 2 H225: Highly flammable liquid and vapour. Acute toxicity, Category 2 H300: Fatal if swallowed. Acute toxicity, Category 3 H331: Toxic if inhaled. Acute toxicity, Category 3 H311: Toxic in contact with skin. Skin corrosion, Sub-category 1B H314: Causes severe skin burns and eye damage. Serious eye damage, Category 1 H318: Causes serious eye damage. Reproductive toxicity, Category 1B H360FD: May damage fertility. May damage the unborn child. Specific target organ toxicity - H370: Causes damage to organs. single exposure, Category 1, Eyes, Central nervous system

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