Note: Ingredients listed on restricted chemical lists
General Information
Revision date
2010-11-21
Product name
Anilinium chloride for synthesis
CAS No.
142-04-1
REACH No
is
Icons in SDS
Company Information
company name
Merck KGaA
e-mail address of the competent person responsible for the Safety Data Sheet
prodsafe@merckgroup.com
GHS Information
Signal word
Danger
Hazard Codes
Hazard statements (CLP)
H301, H301+H311+H331, H311, H317, H318, H331, H341, H351, H372, H400
Hazard statements
Code
Statements
H301
Toxic if swallowed
Section 2
CLP CLASSIFICATION
Carcinogenicity, Category 2, H351 Germ cell mutagenicity, Category 2, H341 Acute toxicity, Category 3, Inhalation, H331 Acute toxicity, Category 3, Dermal, H311 Acute toxicity, Category 3, Oral, H301 Specific target organ toxicity - repeated exposure, Category 1, H372 Serious eye damage, Category 1, H318 Skin sensitization, Category 1, H317 Acute aquatic toxicity, Category 1, H400 For the full text of the H-Statements mentioned in this Section, see Section 16.
2.1 Classification of the substance or mixture
67/548/EEC or 1999/45/EC) Carc.Cat.3; R40 Mut.Cat.3; R68 T; R23/24/25 T; R48/23/24/25 Xi; R41 R43 N; R50 For the full text of the R-phrases mentioned in this Section, see Section 16.
2.2 Label elements
REGULATION (EC) No 1272/2008) (67/548/EEC or 1999/45/EC)
Signal word
Danger Danger
Hazard statements
H301 + H311 + H331 Toxic if swallowed, in contact with skin or if inhaled. H317 May cause an allergic skin reaction. H318 Causes serious eye damage. H341 Suspected of causing genetic defects. H351 Suspected of causing cancer. H372 Causes damage to organs through prolonged or repeated exposure. H400 Very toxic to aquatic life. H301 + H311 + H331 Toxic if swallowed, in contact with skin or if inhaled. H317 May cause an allergic skin reaction. H318 Causes serious eye damage. H341 Suspected of causing genetic defects. H351 Suspected of causing cancer. H372 Causes damage to organs through prolonged or repeated exposure.
Precautionary statements
P273 Avoid release to the environment. P280 Wear protective gloves/ protective clothing/ eye protection/ face protection. P302 + P352 IF ON SKIN: Wash with plenty of soap and water. P304 + P340 IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing. P305 + P351 + P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P309 + P310 IF exposed or if you feel unwell: Immediately call a POISON CENTER or doctor/physician. Reduced labelling (≤125 ml) P280 Wear protective gloves/ protective clothing/ eye protection/ face protection. P302 + P352 IF ON SKIN: Wash with plenty of soap and water. P305 + P351 + P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Index-No. 612-009-00-2
Hazard pictograms
T Toxic N Dangerous for the environment T Toxic N Dangerous for the environment
R-phrase(s)
23/24/25-40-41-43- Toxic by inhalation, in contact with skin and if swallowed. 48/23/24/25-68-50 Limited evidence of a carcinogenic effect. Risk of serious damage to eyes. May cause sensitization by skin contact. Toxic: danger of serious damage to health by prolonged exposure through inhalation, in contact with skin and if swallowed. Possible risk of irreversible effects. Very toxic to aquatic organisms. 23/24/25-40-41-43- Toxic by inhalation, in contact with skin and if swallowed. Limited 48/23/24/25-68 evidence of a carcinogenic effect. Risk of serious damage to eyes. May cause sensitization by skin contact. Toxic: danger of serious damage to health by prolonged exposure through inhalation, in contact with skin and if swallowed. Possible risk of irreversible effects.
S-phrase(s)
26-27-36/37/39-45- In case of contact with eyes, rinse immediately with plenty of 61-63 water and seek medical advice. Take off immediately all contaminated clothing. Wear suitable protective clothing, gloves and eye/face protection. In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible). Avoid release to the environment. Refer to special instructions/ Safety data sheets. In case of accident by inhalation: remove casualty to fresh air and keep at rest. EC-No. 205-519-8 EC Label Reduced labelling (≤125 ml) 26-36/37/39-45 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Wear suitable protective clothing, gloves and eye/face protection. In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible).
2.3 Other hazards
None known.