Aniline for synthesis

Merck KGaA

Revision date : 2010-04-11

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GHS05 GHS06 GHS07 GHS08 GHS09
Health risk rating 4
Safety risk rating 1
Environmental risk rating 4

Note: Ingredients listed on restricted chemical lists

EC/CAS

62-53-3

Name of the chemical

Anilin

Concentration

N/A

EC/CAS

200-539-3

Name of the chemical

Anilin

Concentration

N/A

General Information

Revision date

2010-04-11

Product name

Aniline for synthesis

CAS No.

62-53-3

REACH No

is

Emergency telephone

Please contact the regional company representation in your country

Icons in SDS

GHS05 GHS06 GHS08 GHS09 T050

Company Information

company name

Merck KGaA

e-mail address of the competent person responsible for the Safety Data Sheet

prodsafe@merckgroup.com

GHS Information

Signal word

Danger

Hazard Codes

Hazard statements (CLP)

H301, H311, H317, H318, H331, H341, H351, H372, H400

Hazard statements

Code

Statements

H301

Toxic if swallowed

Section 2

CLP CLASSIFICATION

Carcinogenicity, Category 2, H351 Germ cell mutagenicity, Category 2, H341 Acute toxicity, Category 3, Inhalation, H331 Acute toxicity, Category 3, Dermal, H311 Acute toxicity, Category 3, Oral, H301 Specific target organ toxicity - repeated exposure, Category 1, H372 Serious eye damage, Category 1, H318 Skin sensitization, Category 1, H317 Acute aquatic toxicity, Category 1, H400 For the full text of the H-Statements mentioned in this Section, see Section 16.

2.1 Classification of the substance or mixture

67/548/EEC or 1999/45/EC) Carc.Cat.3; R40 Mut.Cat.3; R68 T; R23/24/25 - 48/23/24/25 Xi; R41 R43 N; R50 For the full text of the R-phrases mentioned in this Section, see Section 16.

2.2 Label elements

REGULATION (EC) No 1272/2008) (67/548/EEC or 1999/45/EC)

Signal word

Danger Danger

Hazard statements

H351 Suspected of causing cancer. H341 Suspected of causing genetic defects. H331 Toxic if inhaled. H311 Toxic in contact with skin. H301 Toxic if swallowed. H372 Causes damage to organs through prolonged or repeated exposure. H318 Causes serious eye damage. H317 May cause an allergic skin reaction. H400 Very toxic to aquatic life. H351 Suspected of causing cancer. H341 Suspected of causing genetic defects. H331 Toxic if inhaled. H311 Toxic in contact with skin. H301 Toxic if swallowed. H372 Causes damage to organs through prolonged or repeated exposure. H318 Causes serious eye damage. H317 May cause an allergic skin reaction.

Precautionary statements

P273 Avoid release to the environment. P280 Wear protective gloves/ protective clothing/ eye protection/ face protection. P308 + P313 IF exposed or concerned: Get medical advice/ attention. P302 + P352 IF ON SKIN: Wash with plenty of soap and water. P305 + P351 + P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P309 + P310 IF exposed or if you feel unwell: Immediately call a POISON CENTER or doctor/physician. Reduced labelling (≤125 ml) P280 Wear protective gloves/ protective clothing/ eye protection/ face protection. P308 + P313 IF exposed or concerned: Get medical advice/ attention. P302 + P352 IF ON SKIN: Wash with plenty of soap and water. P305 + P351 + P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P309 + P310 IF exposed or if you feel unwell: Immediately call a POISON CENTER or doctor/physician. Index-No. 612-008-00-7

Hazard pictograms

T Toxic N Dangerous for the environment T Toxic N Dangerous for the environment

R-phrase(s)

23/24/25-40-41-43- Toxic by inhalation, in contact with skin and if swallowed. 48/23/24/25-68-50 Limited evidence of a carcinogenic effect. Risk of serious damage to eyes. May cause sensitization by skin contact. Toxic: danger of serious damage to health by prolonged exposure through inhalation, in contact with skin and if swallowed. Possible risk of irreversible effects. Very toxic to aquatic organisms. 23/24/25-40-41-43- Toxic by inhalation, in contact with skin and if swallowed. Limited 48/23/24/25-68 evidence of a carcinogenic effect. Risk of serious damage to eyes. May cause sensitization by skin contact. Toxic: danger of serious damage to health by prolonged exposure through inhalation, in contact with skin and if swallowed. Possible risk of irreversible effects.

S-phrase(s)

26-27-36/37/39-45- In case of contact with eyes, rinse immediately with plenty of 46-61-63 water and seek medical advice. Take off immediately all contaminated clothing. Wear suitable protective clothing, gloves and eye/face protection. In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible). If swallowed, seek medical advice immediately and show this container or label. Avoid release to the environment. Refer to special instructions/ Safety data sheets. In case of accident by inhalation: remove casualty to fresh air and keep at rest. EC-No. 200-539-3 EC Label Reduced labelling (≤125 ml) 26-36/37/39-45 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Wear suitable protective clothing, gloves and eye/face protection. In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible).

2.3 Other hazards

None known.

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