Note: Ingredients listed on restricted chemical lists
EC/CAS
203-726-8/109-99-9
Name of the chemical
Tetrahydrofuran (618/2012)
Concentration
70-90%
General Information
Version
5.0
Revision date
2012-12-04
Product name
Allylmagnesium chloride solution
supplier name
Sigma-Aldrich
Emergency telephone
+1 800-325-5832, +1 800-325-5052, 1-800-521-8956
Icons in SDS
Company Information
company name
Sigma-Aldrich
GHS Information
Signal word
Danger
Hazard Codes
Hazard statements (CLP)
H225, H260, H300, H313, H314, H335+H336, H373, H412
Hazard statements
Code
Statements
H225
Highly Flammable liquid and vapour
Section 2
SECTION 2: Hazards identification
NFPA Rating Emergency Overview
Signal word
Danger
Hazard statements
H225 Highly flammable liquid and vapour. H260 In contact with water releases flammable gases which may ignite spontaneously. H300 Fatal if swallowed. H313 May be harmful in contact with skin. H314 Causes severe skin burns and eye damage. H335 + H336 May cause respiratory irritation, and drowsiness or dizziness. H373 May cause damage to organs through prolonged or repeated exposure. H412 Harmful to aquatic life with long lasting effects.
Precautionary statements
P210 Keep away from heat/sparks/open flames/hot surfaces. - No smoking. P223 Keep away from any possible contact with water, because of violent reaction and possible flash fire. P231 + P232 Handle under inert gas. Protect from moisture. P261 Avoid breathing dust/ fume/ gas/ mist/ vapours/ spray. P264 Wash hands thoroughly after handling. P273 Avoid release to the environment. P280 Wear protective gloves/ protective clothing/ eye protection/ face protection. P305 + P351 + P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P310 Immediately call a POISON CENTER or doctor/ physician. P370 + P378 In case of fire: Use dry sand, dry chemical or alcohol-resistant foam for extinction. P422 Store contents under inert gas.
Other hazards
Reacts violently with water., May form explosive peroxides HMIS Classification
Health hazards
Chronic Health Hazard: Flammability * 3
Physical hazards
NFPA Rating Health hazard: Fire Reactivity Hazard Special hazard
Potential health effects
Inhalation May be harmful if inhaled. Material is extremely destructive to the tissue of the mucous membranes and upper respiratory tract. Vapours may cause drowsiness and dizziness. Skin Eyes Ingestion May be harmful if absorbed through skin. Causes skin burns. Causes eye burns. May be fatal if swallowed.
2.1 Classification of the substance or mixture
Flammable liquids (Category 2) Substances, which in contact with water, emit flammable gases (Category 1) Acute toxicity, Oral (Category 2) Acute toxicity, Dermal (Category 5) Skin corrosion (Category 1B) Serious eye damage (Category 1) Specific target organ toxicity - single exposure (Category 3) Specific target organ toxicity - repeated exposure (Category 2) Acute aquatic toxicity (Category 3)