4-Methylcyclohexanone

Sigma-Aldrich Chemie GmbH

Revision date : 2026-09-28

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GHS02 GHS07
Health risk rating 3
Safety risk rating 2
Environmental risk rating 1

General Information

Version

6.7

Revision date

2026-09-28

Product name

4-Methylcyclohexanone

CAS No.

589-92-4

Emergency telephone

+1 703 527 3887, +44 20 3885 0382, +65 3163 8374, +55 11 4349 1359

Icons in SDS

GHS02 GHS07 M004 M009 M010 M011 M017

Company Information

company name

Sigma-Aldrich Chemie GmbH

GHS Information

Signal word

Warning

Hazard Codes

Hazard statements (CLP)

H226, H302

Hazard statements

Code

Statements

H226

Flammable liquid and vapour

Section 2

SECTION 2: Hazards identification

Regulation (EC) No. 1272/2008 Classification of the substance or mixture

Signal word

Warning Warning

Hazard statements

H226 Flammable liquid and vapour. H302 Harmful if swallowed. none

Precautionary statements

P210 Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking. P233 Keep container tightly closed. P240 Ground and bond container and receiving equipment. P241 Use explosion-proof electrical/ ventilating/ lighting equipment. P242 Use non-sparking tools. none

Response

P301 + P312 IF SWALLOWED: Call a POISON CENTER/ doctor if you feel unwell. Reduced Labelling (<= 125 ml)

Supplemental label elements

none

2.3 Other hazards

This substance/mixture contains no components considered to be either persistent, bioaccumulative and toxic (PBT), or very persistent and very bioaccumulative (vPvB) at levels of 0.1% or higher.

ECOLOGICAL INFORMATION

The substance/mixture does not contain components considered to have endocrine disrupting properties according to REACH Article 57(f) or Commission Delegated regulation (EU) 2017/2100 or Commission Regulation (EU) 2018/605 at levels of 0.1% or higher.

TOXICOLOGICAL INFORMATION

The substance/mixture does not contain components considered to have endocrine disrupting properties according to REACH Article 57(f) or Commission Delegated regulation (EU) 2017/2100 or Commission Regulation (EU) 2018/605 at levels of 0.1% or higher.

2.1 Classification of the substance or mixture

Classification (REGULATION (EC) No 1272/2008) Flammable liquids, Category 3 H226: Flammable liquid and vapour. Acute toxicity, Category 4 H302: Harmful if swallowed.

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