4-Chloro-2-methylaniline

Sigma-Aldrich Chemical Pvt Limited

Revision date : 2026-04-17

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GHS06 GHS08 GHS09
Health risk rating 5
Safety risk rating 1
Environmental risk rating 5

Note: Ingredients listed on restricted chemical lists

EC/CAS

202-441-6/95-69-2

Name of the chemical

4-Chlor-o-toluidin

Concentration

>=90-<=100

General Information

Version

7.0

Revision date

2026-04-17

Product name

4-Chloro-2-methylaniline

CAS No.

95-69-2

Icons in SDS

GHS06 GHS08 GHS09 M004 M009 M017

Company Information

company name

Sigma-Aldrich Chemical Pvt Limited

GHS Information

Signal word

Danger

Hazard Codes

Hazard statements (CLP)

H301, H301+H311+H331, H311, H331, H341, H350, H400, H410

Hazard statements

Code

Statements

H301

Toxic if swallowed

Section 2

SECTION 2: Hazards identification

Regulation (EC) No. 1272/2008 Classification of the substance or mixture

Signal word

Danger Danger

Hazard statements

H301 + H311 + H331 Toxic if swallowed, in contact with skin or if inhaled. H341 Suspected of causing genetic defects. H350 May cause cancer. H410 Very toxic to aquatic life with long lasting effects. H350 May cause cancer. H341 Suspected of causing genetic defects. H301 + H311 + H331 Toxic if swallowed, in contact with skin or if inhaled.

Precautionary statements

P273 Avoid release to the environment. P280 Wear protective gloves/ protective clothing/ eye protection/ face protection. P280 Wear protective gloves/ protective clothing/ eye protection/ face protection. P301 + P310 + P330 IF SWALLOWED: Immediately call a POISON CENTER/ doctor. Rinse mouth. P302 + P352 + P312 IF ON SKIN: Wash with plenty of water. Call a POISON CENTER/ doctor if you feel unwell. P304 + P340 + P311 IF INHALED: Remove person to fresh air and keep comfortable for breathing. Call a POISON CENTER/ doctor. P308 + P313 IF exposed or concerned: Get medical advice/ attention.

Response

P301 + P310 + P330 IF SWALLOWED: Immediately call a POISON CENTER/ doctor. Rinse mouth. P302 + P352 + P312 IF ON SKIN: Wash with plenty of water. Call a POISON CENTER/ doctor if you feel unwell. P304 + P340 + P311 IF INHALED: Remove person to fresh air and keep comfortable for breathing. Call a POISON CENTER/ doctor. P308 + P313 IF exposed or concerned: Get medical advice/ attention.

Additional information

Restricted to professional users. Reduced Labelling (<= 125 ml)

Supplemental label elements

none

2.3 Other hazards

This substance/mixture contains no components considered to be either persistent, bioaccumulative and toxic (PBT), or very persistent and very bioaccumulative (vPvB) at levels of 0.1% or higher.

ECOLOGICAL INFORMATION

The substance/mixture does not contain components considered to have endocrine disrupting properties according to REACH Article 57(f) or Commission Delegated regulation (EU) 2017/2100 or Commission Regulation (EU) 2018/605 at levels of 0.1% or higher.

TOXICOLOGICAL INFORMATION

The substance/mixture does not contain components considered to have endocrine disrupting properties according to REACH Article 57(f) or Commission Delegated regulation (EU) 2017/2100 or Commission Regulation (EU) 2018/605 at levels of 0.1% or higher.

2.1 Classification of the substance or mixture

Classification (REGULATION (EC) No 1272/2008) Carcinogenicity, Category 1B H350: May cause cancer. Germ cell mutagenicity, Category 2 H341: Suspected of causing genetic defects. Short-term (acute) aquatic hazard, H400: Very toxic to aquatic life. Category 1 Long-term (chronic) aquatic hazard, H410: Very toxic to aquatic life with long Category 1 lasting effects. Acute toxicity, Category 3 H331: Toxic if inhaled. Acute toxicity, Category 3 H311: Toxic in contact with skin. Acute toxicity, Category 3 H301: Toxic if swallowed.

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