General Information
Version
8.7
Revision date
2025-12-27
Product name
4-Azidoanisole solution
1.2.1 Relevant identified uses
Laboratory chemicals, Synthesis of substances
1.2.2. Uses advised against
The product is being supplied under the TSCA R&D Exemption
Emergency telephone
800-424-9300, +1-703- 527-3887
Icons in SDS
Company Information
company name
Sigma-Aldrich Inc
GHS Information
Signal word
Danger
Hazard Codes
Hazard statements (CLP)
H225, H302, H315, H317
Hazard statements
Code
Statements
H225
Highly Flammable liquid and vapour
Section 2
SECTION 2: Hazards identification
Other hazards
Explosive when dry
Signal word
Danger
Hazard statements
H225 Highly flammable liquid and vapour. H302 Harmful if swallowed. H315 Causes skin irritation. H317 May cause an allergic skin reaction.
Prevention
P210 Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking. P233 Keep container tightly closed. P240 Ground and bond container and receiving equipment. P241 Use explosion-proof electrical/ ventilating/ lighting P242 Use non-sparking tools. P243 Take action to prevent static discharges. P261 Avoid breathing mist or vapours. P264 Wash skin thoroughly after handling. P270 Do not eat, drink or smoke when using this product. P272 Contaminated work clothing must not be allowed out of the workplace. P280 Wear protective gloves/ protective clothing/ eye protection/ face protection.
Response
P301 + P312 + P330 IF SWALLOWED: Call a POISON CENTER/ doctor if you feel unwell. Rinse mouth. P303 + P361 + P353 IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water/ shower. P333 + P313 If skin irritation or rash occurs: Get medical advice/ attention. P370 + P378 In case of fire: Use dry sand, dry chemical or alcohol-resistant foam to extinguish.
Storage
P403 + P235 Store in a well-ventilated place. Keep cool.
Disposal
P501 Dispose of contents/ container to an approved waste disposal plant.
2.1 Classification of the substance or mixture
(29 CFR 1910.1200) Hazards for the product as supplied Flammable liquids : Category 2 Acute toxicity (Oral) : Category 4 Skin irritation : Category 2 Skin sensitisation : Category 1 Other hazards Explosive when dry.
