3-Bromothiophene for synthesis

Merck KGaA

Revision date : 2010-11-21

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GHS02 GHS06 GHS07 GHS09
Health risk rating 5
Safety risk rating 2
Environmental risk rating 4

General Information

Revision date

2010-11-21

Product name

3-Bromothiophene for synthesis

CAS No.

872-31-1

REACH No

is

Icons in SDS

Company Information

company name

Merck KGaA

e-mail address of the competent person responsible for the Safety Data Sheet

prodsafe@merckgroup.com

GHS Information

Signal word

Danger

Hazard Codes

Hazard statements (CLP)

H226, H301, H310, H310+H330, H330, H335, H411

Hazard statements

Code

Statements

H226

Flammable liquid and vapour

Section 2

CLP CLASSIFICATION

Flammable liquid, Category 3, H226 Acute toxicity, Category 1, Inhalation, H330 Chronic aquatic toxicity, Category 2, H411 Specific target organ toxicity - single exposure, Category 3, H335 Acute toxicity, Category 2, Dermal, H310 Acute toxicity, Category 3, Oral, H301 For the full text of the H-Statements mentioned in this Section, see Section 16.

2.1 Classification of the substance or mixture

67/548/EEC or 1999/45/EC) R10 T; R23/24/25 Xi; R37 N; R51/53 For the full text of the R-phrases mentioned in this Section, see Section 16.

2.2 Label elements

REGULATION (EC) No 1272/2008) (67/548/EEC or 1999/45/EC)

Signal word

Danger Danger

Hazard statements

H226 Flammable liquid and vapour. H301 Toxic if swallowed. H310 + H330 Fatal in contact with skin or if inhaled. H335 May cause respiratory irritation. H411 Toxic to aquatic life with long lasting effects. H301 Toxic if swallowed. H310 + H330 Fatal in contact with skin or if inhaled.

Precautionary statements

P210 Keep away from heat/sparks/open flames/hot surfaces. - No smoking. P273 Avoid release to the environment. P280 Wear protective gloves/ protective clothing. P302 + P352 IF ON SKIN: Wash with plenty of soap and water. P304 + P340 IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing. P309 + P310 IF exposed or if you feel unwell: Immediately call a POISON CENTER or doctor/physician. Reduced labelling (≤125 ml) P280 Wear protective gloves/ protective clothing. P309 + P310 IF exposed or if you feel unwell: Immediately call a POISON CENTER or doctor/physician. CAS-No. 872-31-1

Hazard pictograms

T Toxic T Toxic

R-phrase(s)

10-23/24/25-37- Flammable. Toxic by inhalation, in contact with skin and if 51/53 swallowed. Irritating to respiratory system. Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment. 10-23/24/25 Flammable. Toxic by inhalation, in contact with skin and if swallowed.

S-phrase(s)

36/37-45-61 Wear suitable protective clothing and gloves. In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible). Avoid release to the environment. Refer to special instructions/ Safety data sheets. EC-No. 212-821-3 Reduced labelling (≤125 ml) 36/37-45 Wear suitable protective clothing and gloves. In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible).

2.3 Other hazards

None known.

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