General Information
Revision date
2010-11-21
Product name
3-Bromothiophene for synthesis
CAS No.
872-31-1
REACH No
is
Icons in SDS
Company Information
company name
Merck KGaA
e-mail address of the competent person responsible for the Safety Data Sheet
prodsafe@merckgroup.com
GHS Information
Signal word
Danger
Hazard Codes
Hazard statements (CLP)
H226, H301, H310, H310+H330, H330, H335, H411
Hazard statements
Code
Statements
H226
Flammable liquid and vapour
Section 2
CLP CLASSIFICATION
Flammable liquid, Category 3, H226 Acute toxicity, Category 1, Inhalation, H330 Chronic aquatic toxicity, Category 2, H411 Specific target organ toxicity - single exposure, Category 3, H335 Acute toxicity, Category 2, Dermal, H310 Acute toxicity, Category 3, Oral, H301 For the full text of the H-Statements mentioned in this Section, see Section 16.
2.1 Classification of the substance or mixture
67/548/EEC or 1999/45/EC) R10 T; R23/24/25 Xi; R37 N; R51/53 For the full text of the R-phrases mentioned in this Section, see Section 16.
2.2 Label elements
REGULATION (EC) No 1272/2008) (67/548/EEC or 1999/45/EC)
Signal word
Danger Danger
Hazard statements
H226 Flammable liquid and vapour. H301 Toxic if swallowed. H310 + H330 Fatal in contact with skin or if inhaled. H335 May cause respiratory irritation. H411 Toxic to aquatic life with long lasting effects. H301 Toxic if swallowed. H310 + H330 Fatal in contact with skin or if inhaled.
Precautionary statements
P210 Keep away from heat/sparks/open flames/hot surfaces. - No smoking. P273 Avoid release to the environment. P280 Wear protective gloves/ protective clothing. P302 + P352 IF ON SKIN: Wash with plenty of soap and water. P304 + P340 IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing. P309 + P310 IF exposed or if you feel unwell: Immediately call a POISON CENTER or doctor/physician. Reduced labelling (≤125 ml) P280 Wear protective gloves/ protective clothing. P309 + P310 IF exposed or if you feel unwell: Immediately call a POISON CENTER or doctor/physician. CAS-No. 872-31-1
Hazard pictograms
T Toxic T Toxic
R-phrase(s)
10-23/24/25-37- Flammable. Toxic by inhalation, in contact with skin and if 51/53 swallowed. Irritating to respiratory system. Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment. 10-23/24/25 Flammable. Toxic by inhalation, in contact with skin and if swallowed.
S-phrase(s)
36/37-45-61 Wear suitable protective clothing and gloves. In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible). Avoid release to the environment. Refer to special instructions/ Safety data sheets. EC-No. 212-821-3 Reduced labelling (≤125 ml) 36/37-45 Wear suitable protective clothing and gloves. In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible).
2.3 Other hazards
None known.