1,4-Dioxane solution

Sigma-Aldrich Inc

Revision date : 2023-12-07

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GHS07 GHS08 GHS02
Health risk rating 5
Safety risk rating 3
Environmental risk rating 3

General Information

Version

8.4

Revision date

2023-12-07

Product name

1,4-Dioxane solution

1.2.1 Relevant identified uses

Laboratory chemicals, Synthesis of substances

Emergency telephone

800-424-9300, +1-703- 527-3887

Icons in SDS

GHS02 GHS07 GHS08 M004 M009 M010 M011 M017

Company Information

company name

Sigma-Aldrich Inc

GHS Information

Signal word

Danger

Hazard Codes

Hazard statements (CLP)

H225, H304, H315, H319, H340, H350, H372, H401, H412

Hazard statements

Code

Statements

H225

Highly Flammable liquid and vapour

Section 2

SECTION 2: Hazards identification

Classification of the substance or mixture

Signal word

Danger

Hazard statements

H225 Highly flammable liquid and vapor. H304 May be fatal if swallowed and enters airways. H315 Causes skin irritation. H319 Causes serious eye irritation. H340 May cause genetic defects. H350 May cause cancer. H372 Causes damage to organs (Blood) through prolonged or repeated exposure. H401 Toxic to aquatic life. H412 Harmful to aquatic life with long lasting effects.

Precautionary statements

P201 Obtain special instructions before use. P202 Do not handle until all safety precautions have been read and understood. P210 Keep away from heat/ sparks/ open flames/ hot surfaces. No smoking. P233 Keep container tightly closed. P240 Ground/bond container and receiving equipment. P241 Use explosion-proof electrical/ ventilating/ lighting/ equipment. P242 Use only non-sparking tools. P243 Take precautionary measures against static discharge. P260 Do not breathe mist or vapors. P264 Wash skin thoroughly after handling. P270 Do not eat, drink or smoke when using this product. P273 Avoid release to the environment. P280 Wear protective gloves/ protective clothing/ eye protection/ face protection. P301 + P310 IF SWALLOWED: Immediately call a POISON CENTER/ doctor. P303 + P361 + P353 IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water/ shower. P305 + P351 + P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P308 + P313 IF exposed or concerned: Get medical advice/ attention. P331 Do NOT induce vomiting. P332 + P313 If skin irritation occurs: Get medical advice/ attention. P337 + P313 If eye irritation persists: Get medical advice/ attention. P362 Take off contaminated clothing and wash before reuse. P370 + P378 In case of fire: Use dry sand, dry chemical or alcohol-resistant foam to extinguish. P403 + P235 Store in a well-ventilated place. Keep cool. P405 Store locked up. P501 Dispose of contents/ container to an approved waste disposal plant.

2.3 Other hazards

- none

2.1 Classification of the substance or mixture

GHS Classification in accordance with 29 CFR 1910 (OSHA HCS) Flammable liquids (Category 2), H225 Skin irritation (Category 2), H315 Eye irritation (Category 2A), H319 Germ cell mutagenicity (Category 1B), H340 Carcinogenicity (Category 1A), H350 Specific target organ toxicity - repeated exposure (Category 1), Blood, H372 Aspiration hazard (Category 1), H304 Short-term (acute) aquatic hazard (Category 2), H401 Long-term (chronic) aquatic hazard (Category 3), H412 For the full text of the H-Statements mentioned in this Section, see Section 16.

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