Note: Ingredients listed on restricted chemical lists
EC/CAS
205-500-4/141-78-6
Name of the chemical
acetic acid, ethyl ester
Concentration
≥40<60%
EC/CAS
202-966-0/101-68-8
Name of the chemical
4,4’-Methylenediphenyl diisocyanate
Concentration
≥0.1<1% >=5% >=5% >=5%
EC/CAS
247-722-4/26471-62-5
Name of the chemical
m-Tolylidendiisocyanat
Concentration
≥ 0.025 < 0.1 %
General Information
Version
1.1 (en
Revision date
2022-11-08
Product name
Sika Primer-209 D
supplier name
Mercedes-Benz AG
Manufacturer Name
Sika Automotive GmbH
Emergency telephone
EHS_Automotive@de.sika.com +49 173 6774799
Icons in SDS
Company Information
company name
Mercedes-Benz AG
e-mail address of the competent person responsible for the Safety Data Sheet
mercedes-benz-sdb@mercedes-benz.com, EHS_Automotive@de.sika.com
GHS Information
Signal word
Danger
Hazard Codes
Hazard statements (CLP)
H225, H317, H319, H334, H336
Hazard statements
Code
Statements
H225
Highly Flammable liquid and vapour
Section 2
SECTION 2: Hazards identification
CLP CLASSIFICATION
Classification according to Regulation (EC) No 1272/2008 [CLP] ]] Classification procedure Flam. Liq. 2, H225 Eye Irrit. 2, H319 Resp. Sens. 1, H334 Skin Sens. 1, H317 STOT SE 3, H336
Hazard statements
H225 Highly flammable liquid and vapour. H317 May cause an allergic skin reaction. H319 Causes serious eye irritation. H334 May cause allergy or asthma symptoms or breathing difficulties if inhaled. H336 May cause drowsiness or dizziness. H225 Highly flammable liquid and vapour. H317 May cause an allergic skin reaction. H319 Causes serious eye irritation. H334 May cause allergy or asthma symptoms or breathing difficulties if inhaled. H336 May cause drowsiness or dizziness.
2.2 Label elements
Labelling
Hazardous Ingredients
ethyl acetate, Aromatic polyisocyanate, 4,4'-methylenediphenyl diisocyanate, m-tolylidene diisocyanate
Hazard pictograms
GHS02 GHS07 GHS08
Signal word
Danger
Precautionary statements
P102 Keep out of reach of children. P210 Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking. P261 Avoid breathing mist/vapours/spray. P280 Wear protective gloves/eye protection. P304 + P340 IF INHALED: Remove person to fresh air and keep comfortable for breathing. P312 Call a POISON CENTER/doctor if you feel unwell. P342 + P311 If experiencing respiratory symptoms: Call a POISON CENTER/doctor. P370 + P378 In case of fire use dry sand, dry powder or alcohol-resistant foam to extinguish.
Supplemental label elements
EUH066 Repeated exposure may cause skin dryness or cracking.
Special rules for supplemental label elements for certain mixtures
EUH204 Contains isocyanates. May produce an allergic reaction. As of 24 August 2023, appropriate training must be carried out prior to industrial or commercial use.
Potential health effects
People who have an allergic reaction to isocyanates should avoid handling this product.
Results of PBT and vPvB assessment
The substances in the mixture do not meet the PBT/vPvB criteria according to REACH, annex XIII. Der Stoff/dieses Gemisch enthält keine Bestandteile, die gemäß REACH Artikel 57(f) oder der delegierten Verordnung (EU) 2017/2100 der Kommission oder der delegierten Verordnung (EU) 2018/605 der Kommission in Mengen von 0,1 % oder mehr endokrinschädliche Eigenschaften aufweisen.
