Note: Ingredients listed on restricted chemical lists
EC/CAS
202-966-0/101-68-8
Name of the chemical
4,4’-Methylenediphenyl diisocyanate
Concentration
>0,1<1
EC/CAS
223-861-6/4098-71-9
Name of the chemical
3-isocyanatomethyl-3,5,5-trimethylcyclohexyl isocyanate
Concentration
>0,5<2
General Information
Revision date
2016-06-10
Product name
Primer
Emergency telephone
+49 (0)711 17-0, +33 1 76 84 04 04, +49 30 192 40
Icons in SDS
Company Information
company name
Daimler AG
e-mail address of the competent person responsible for the Safety Data Sheet
Mercedes-Benz-SDB@daimler.com
GHS Information
Signal word
Danger
Hazard Codes
Hazard statements (CLP)
H225, H317, H319, H332, H334, H336
Hazard statements
Code
Statements
H225
Highly Flammable liquid and vapour
Section 2
SECTION 2: Hazards identification
Regulation (EC) No. 1272/2008 Classification of the substance or mixture
Hazard statements
H225 Highly flammable liquid and vapour. H317 May cause an allergic skin reaction. H319 Causes serious eye irritation. H332 Harmful if inhaled. H334 May cause allergy or asthma symptoms or breathing difficulties if inhaled. H336 May cause drowsiness or dizziness. H225 Highly flammable liquid and vapour. H317 May cause an allergic skin reaction. H319 Causes serious eye irritation. H332 Harmful if inhaled. H334 May cause allergy or asthma symptoms or breathing difficulties if inhaled. H336 May cause drowsiness or dizziness.
Signal word
Danger
Precautionary statements
General P102 Keep out of reach of children.
Prevention
P210 Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking. P261 Avoid breathing dust/fume/gas/mist/vapours/spray. P261 Avoid breathing mist/vapours/spray. P271 Use only outdoors or in a well-ventilated area. P280 Wear protective gloves/protective clothing/eye protection. P284 Wear respiratory protection.
Response
P303 + P361 + IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/ P353 shower. P304 + P340 IF INHALED: Remove person to fresh air and keep comfortable for breathing. P305 + P351 + IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and P338 easy to do. Continue rinsing. P333 + P313 If skin irritation or rash occurs: Get medical advice/attention. P337 + P313 If eye irritation persists: Get medical advice/attention. P342 + P311 If experiencing respiratory symptoms: Call a POISON CENTER/doctor. P362 + P364 Take off contaminated clothing and wash it before reuse. P370 + P378 In case of fire: Use dry sand, dry chemical or alcohol-resistant foam to extinguish.
Storage
P403 + P233 Store in a well-ventilated place. Keep container tightly closed.
Disposal
P501 Dispose of contents/container in accordance with regional regulations.
Hazardous Ingredients
3-isocyanatomethyl-3,5,5-trimethylcyclohexyl isocyanate, 4,4'-methylenediphenyl diisocyanate, butanone
Supplemental label elements
Health properties Repeated exposure may cause skin dryness or cracking.
Special rules for supplemental label elements for certain mixtures
Contains isocyanates. May produce an allergic reaction.
2.3 Other hazards
Information pertaining to special dangers for human and environment Persons allergic to isocyanates should avoid contact with the material.
Results of PBT and vPvB assessment
The substances in the mixture do not meet the PBT/vPvB criteria according to REACH, annex XIII.
2.1 Classification of the substance or mixture
Classification according to Regulation (EC) No 1272/2008 [CLP/GHS] Hazard classes and Hazard Hazard Statements Classification procedure categories Flam. Liq. 2 H225 Acute Tox. 4 H332 Eye Irrit. 2 H319 Resp. Sens. 1 H334 Skin Sens. 1 H317 STOT SE 3 H336 Hazard statements for physical hazards H225 Highly flammable liquid and vapour. Hazard statements for health hazards H317 May cause an allergic skin reaction. H319 Causes serious eye irritation. H332 Harmful if inhaled. H334 May cause allergy or asthma symptoms or breathing difficulties if inhaled. H336 May cause drowsiness or dizziness.