Primer

Daimler AG

Revision date : 2016-06-10

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GHS02 GHS07 GHS08
Health risk rating 5
Safety risk rating 3
Environmental risk rating 1

Note: Ingredients listed on restricted chemical lists

EC/CAS

202-966-0/101-68-8

Name of the chemical

4,4’-Methylenediphenyl diisocyanate

Concentration

>0,1<1

EC/CAS

223-861-6/4098-71-9

Name of the chemical

3-isocyanatomethyl-3,5,5-trimethylcyclohexyl isocyanate

Concentration

>0,5<2

General Information

Revision date

2016-06-10

Product name

Primer

Emergency telephone

+49 (0)711 17-0, +33 1 76 84 04 04, +49 30 192 40

Icons in SDS

GHS02 GHS07 GHS08

Company Information

company name

Daimler AG

e-mail address of the competent person responsible for the Safety Data Sheet

Mercedes-Benz-SDB@daimler.com

GHS Information

Signal word

Danger

Hazard Codes

Hazard statements (CLP)

H225, H317, H319, H332, H334, H336

Hazard statements

Code

Statements

H225

Highly Flammable liquid and vapour

Section 2

SECTION 2: Hazards identification

Regulation (EC) No. 1272/2008 Classification of the substance or mixture

Hazard statements

H225 Highly flammable liquid and vapour. H317 May cause an allergic skin reaction. H319 Causes serious eye irritation. H332 Harmful if inhaled. H334 May cause allergy or asthma symptoms or breathing difficulties if inhaled. H336 May cause drowsiness or dizziness. H225 Highly flammable liquid and vapour. H317 May cause an allergic skin reaction. H319 Causes serious eye irritation. H332 Harmful if inhaled. H334 May cause allergy or asthma symptoms or breathing difficulties if inhaled. H336 May cause drowsiness or dizziness.

Signal word

Danger

Precautionary statements

General P102 Keep out of reach of children.

Prevention

P210 Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking. P261 Avoid breathing dust/fume/gas/mist/vapours/spray. P261 Avoid breathing mist/vapours/spray. P271 Use only outdoors or in a well-ventilated area. P280 Wear protective gloves/protective clothing/eye protection. P284 Wear respiratory protection.

Response

P303 + P361 + IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/ P353 shower. P304 + P340 IF INHALED: Remove person to fresh air and keep comfortable for breathing. P305 + P351 + IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and P338 easy to do. Continue rinsing. P333 + P313 If skin irritation or rash occurs: Get medical advice/attention. P337 + P313 If eye irritation persists: Get medical advice/attention. P342 + P311 If experiencing respiratory symptoms: Call a POISON CENTER/doctor. P362 + P364 Take off contaminated clothing and wash it before reuse. P370 + P378 In case of fire: Use dry sand, dry chemical or alcohol-resistant foam to extinguish.

Storage

P403 + P233 Store in a well-ventilated place. Keep container tightly closed.

Disposal

P501 Dispose of contents/container in accordance with regional regulations.

Hazardous Ingredients

3-isocyanatomethyl-3,5,5-trimethylcyclohexyl isocyanate, 4,4'-methylenediphenyl diisocyanate, butanone

Supplemental label elements

Health properties Repeated exposure may cause skin dryness or cracking.

Special rules for supplemental label elements for certain mixtures

Contains isocyanates. May produce an allergic reaction.

2.3 Other hazards

Information pertaining to special dangers for human and environment Persons allergic to isocyanates should avoid contact with the material.

Results of PBT and vPvB assessment

The substances in the mixture do not meet the PBT/vPvB criteria according to REACH, annex XIII.

2.1 Classification of the substance or mixture

Classification according to Regulation (EC) No 1272/2008 [CLP/GHS] Hazard classes and Hazard Hazard Statements Classification procedure categories Flam. Liq. 2 H225 Acute Tox. 4 H332 Eye Irrit. 2 H319 Resp. Sens. 1 H334 Skin Sens. 1 H317 STOT SE 3 H336 Hazard statements for physical hazards H225 Highly flammable liquid and vapour. Hazard statements for health hazards H317 May cause an allergic skin reaction. H319 Causes serious eye irritation. H332 Harmful if inhaled. H334 May cause allergy or asthma symptoms or breathing difficulties if inhaled. H336 May cause drowsiness or dizziness.

SDS Library

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Up-to-date – Your SDS get updated to latest versions.
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Safety – One-click access to first aid information.
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Labels – Generate Secondary Container Labels with just one click.