9-0-0+11Fe

Hazard statements (CLP)

H302, H315, H319

Code

Statements

H302

Harmful if swallowed

Health hazards

Acute Tox. 4 - H302 Skin Irrit. 2 - H315 Eye Irrit. 2 - H319

Environmental hazards

Not Classified

Signal word

Warning

Hazard statements

H302 Harmful if swallowed. H315 Causes skin irritation. H319 Causes serious eye irritation.

Precautionary statements

P264 Wash contaminated skin thoroughly after handling. P270 Do not eat, drink or smoke when using this product. P280 Wear protective gloves/protective clothing/eye protection/face protection. P301+P310 IF SWALLOWED: Immediately call a POISON CENTER/doctor. P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P501 Dispose of contents/container in accordance with national regulations.

Contains

Ferrous Sulphate 18%

Supplemental label elements

P302+P352 IF ON SKIN: Wash with plenty of water. P321 Specific treatment (see medical advice on this label). P330 Rinse mouth. P332+P313 If skin irritation occurs: Get medical advice/attention. P337+P313 If eye irritation persists: Get medical advice/attention. P362+P364 Take off contaminated clothing and wash it before reuse.

2.3 Other hazards

This substance is not classified as PBT or vPvB according to current EU criteria. 3.2. Mixtures Ferrous Sulphate 18% 30-60% CAS number 7720-78-7 EC number 231-753-5 REACHregistration number:01-2119513203-57-XXXX

2.1 Classification of the substance or mixture

67/548/EEC or 1999/45/EC) Acute Tox. 4 - H302 Xn; R22. Xi; R36/38 Skin Irrit. 2 - H315 Eye Irrit. 2 - H319 SSP Single Superphosphate 10-30% CAS number 8011-76-5 EC number 232-379-5 REACHregistration number 01-2119488967-11-XXXX (67/548/EEC or 1999/45/EC) Eye Irrit. 2 - H319 Xi; R41 The Full Text for all R-Phrases and Hazard Statements are Displayed in Section 16. SECTION4:Firstaidmeasures 4.1. Description of first aid measures Inhalation Get medical attention if symptoms are severe or persist. Ingestion Rinse mouth thoroughly with water. Do not induce vomiting unless under the direction of medical personnel. Get medical attention if symptoms are severe or persist. Skin contact Wash skin thoroughly with soap and water or use an approved skin cleanser. Get medical attention if symptoms are severe or persist after washing. Eye contact Rinse immediately with plenty of water. Remove contact lenses, if present and easy to do. Continue rinsing. Continue to rinse for at least 10 minutes. Get medical attention if symptoms are severe or persist after washing. 4.2. Most important symptoms and effects, both acute and delayed Inhalation Dust in high concentrations may irritate the respiratory system. Ingestion May be harmful if swallowed. Gastrointestinal symptoms, including upset stomach. Skin contact May cause irritation. Prolonged contact may cause redness, irritation and dry skin. Eye contact Prolonged or repeated exposure may cause severe irritation. May cause severe eye irritation. 4.3. Indication of any immediate medical attention and special treatment needed Notes for the doctor Treat symptomatically. 5.1. Extinguishing media Suitable extinguishing media The product is not flammable. Use fire-extinguishing media suitable for the surrounding fire. Unsuitable extinguishing media Not applicable. 5.2. Special hazards arising from the substance or mixture Specific hazards None known. 5.3. Advice for firefighters Protective actions during firefighting No specific firefighting precautions known. Special protective equipment for firefighters Use protective equipment appropriate for surrounding materials. 6.1. Personal precautions, protective equipment and emergency procedures Personal precautions Avoid inhalation of dust and contact with skin and eyes. Use suitable respiratory protection if ventilation is inadequate. Wear suitable protective equipment, including gloves, goggles/face shield, respirator, boots, clothing or apron, as appropriate. Take care as floors and other surfaces may become slippery. 6.2. Environmental precautions Environmental precautions The product is slowly degradable. The product is not expected to be hazardous to the environment. Avoid the spillage or runoff entering drains, sewers or watercourses. 6.3. Methods and material for containment and cleaning up Methods for cleaning up Take care as floors and other surfaces may become slippery. Collect and dispose of spillage as indicated in Section 13. 6.4. Reference to other sections Reference to other sections For personal protection, see Section 8. For waste disposal, see Section 13. 7.1. Precautions for safe handling Usage precautions Read label before use. Wear appropriate clothing to prevent repeated or prolonged skin contact. Avoid inhalation of dust and contact with skin and eyes. Advice on general occupational hygiene Wash hands thoroughly after handling. Wash at the end of each work shift and before eating, smoking and using the toilet. 7.2. Conditions for safe storage, including any incompatibilities Storage precautions Store in a dry place. 7.3. Specific end use(s) Specific end use(s) The identified uses for this product are detailed in Section 1.2. 8.1. Control parameters Occupational exposure limits Ammonium Sulphate Long-term exposure limit (8-hour TWA): LTEL 10Mg/m3 Ferrous Sulphate 18% Long-term exposure limit (8-hour TWA): WEL 1 mg/m3 Short-term exposure limit (15-minute): WEL 2 mg/m3 Coating Oil Long-term exposure limit (8-hour TWA): WEL 5 mg/m3 inhalable fraction WEL = Workplace Exposure Limit SSP Single Superphosphate (CAS: 8011-76-5) DNEL Workers - Inhalation; Long term systemic effects: 3.1 mg/m³ Workers - Dermal; Long term systemic effects: 17.4 mg/kg/day General population - Inhalation; Long term systemic effects: 0.9 mg/m³ General population - Oral; Long term systemic effects: 2.1 mg/kg/day General population - Dermal; Long term systemic effects: 10.4 mg/kg/day PNEC - Fresh water; 1.7 mg/l - Marine water; 0.17 mg/m³ - Intermittent release; 17 mg/l - STP; 10 mg/l 8.2. Exposure controls Protective equipment Appropriate engineering controls All handling should only take place in well-ventilated areas. Eye/face protection Wear eye protection. Hand protection Wear protective gloves. Other skin and body protection Wear appropriate clothing to prevent repeated or prolonged skin contact. Hygiene measures Wash hands thoroughly after handling. Do not eat, drink or smoke when using this product. Respiratory protection No specific recommendations. 9.1. Information on basic physical and chemical properties Appearance Granules. Colour Beige to dark brown or black. Odour Mild. Odour threshold Not determined. pH Slightly Acidic Melting point Not relevant. Initial boiling point and range Not relevant. Flash point Not relevant. Evaporation rate Not relevant. Flammability (solid, gas) The product is not flammable. Vapour pressure Not relevant. Vapour density Not relevant. Relative density Not relevant. Solubility(ies) Not known. Partition coefficient Not known. Auto-ignition temperature Not relevant. Decomposition Temperature Not relevant. Viscosity Not relevant. Explosive properties Not relevant. Oxidising properties Does not meet the criteria for classification as oxidising.

Further information

No information required. 10.1. Reactivity No test data specifically related to reactivity available for this product or its ingredients. 10.2. Chemical stability Stability Stable when stored in a dry place. 10.3. Possibility of hazardous reactions No potentially hazardous reactions known. 10.4. Conditions to avoid There are no known conditions that are likely to result in a hazardous situation. 10.5. Incompatible materials Materials to avoid None known. 10.6. Hazardous decomposition products None known.