Numbers MTAR-13

Hazard statements (CLP)

H224, H280, H304, H315, H319, H336, H340, H361, H373, H401, H411

Code

Statements

H224

Extremely flammable liquid and vapour

2.3 Other hazards

Flammable, Target Organs Effect, Irritant, Teratogen Target Organs Peripheral Liquids, Kidney, Testes

2.1 Classification of the substance or mixture

Health: Eye Irritation (Category 2B) Skin Irritation (Category 2) Reproductive Toxicity (Category 2) Specific Target Organ Toxicity-single exposure (Category 3)

Hazard pictograms

Flammable

Health hazards

Exclamation Mark 1 * Flammability 4

Hazard statements

H224 Extremely flammable liquid and vapor. H280 Contains gas under pressure, may explode if heated. H304 May be fatal if swallowed and enters airways. H315 Causes skin irritation. H319 Causes serious eye irritation. H336 May cause drowsiness or dizziness. H340 May cause genetic defects. H361 Suspected of damaging fertility or the unborn child. H373 May cause damage to organs through prolonged or repeated exposure. H401 Toxic to aquatic life. H411 Toxic to aquatic life with long lasting effects.

Precautionary statements

General: P210 Keep away from heat, sparks, open flames, hot surfaces and No Smoking. P261 Avoid breathing dust, fume, gas, mist, vapors, spray. P281 Use personal protective equipment as required. P403+P233 Store in a well-ventilated place,. Keep container tightly closed. P403+P235 Store in a well-ventilated place. Keep Cool. P410 Protect from sunlight.

Physical hazards

1

NFPA Ratings

Toxicity 2 Fire 4 Reactivity 0

Prevention

P201 Obtain Special instructions before use. P202 Do not handle until all safety precautions have been read and understood. P210 Keep away from heat, sparks, open flames, hot surfaces. No Smoking. P233 Keep container tightly closed. P240 Ground/Bond container and receiving equipment. P241 Use explosion-Proof electrical, ventilating, lighting equipment. P242 Use only non-sparking tools. P243 Take precautionary measures against static discharge. P260 Do not breathe dust, fume, gas, mist, vapors, spray. P264 Wash hands, forearms, and other exposed areas thoroughly after handing. P271 Use only outdoors or in a well ventilated area. P273 Avoid release to the environment. P280 Wear protective gloves, protective clothing, eye protection, face protection. P284 Wear respiratory protection.

Response

P301+310 IF SWALLOWED: Immediately call a POISON CENTER or doctor/physician. P302+352 IF ON SKIN: Wash with plenty of soap and water. P303+P361+P353 IF ON SKIN (or hair): Remove/Take off all contaminated clothing immediately. Rinse skin with water/shower. P304+P340 IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. P305+P351+P338 IF IN EYES Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P308+P313: If exposed or concerned, Get medical advice /attention. P312 Call a Poison Center or Doctor/Physician if you feel unwell. P314 Get medical advice/attention if you feel unwell. P321 Specific Treatment (see section 4) P331 Do NOT induce vomiting. P332+P313 If Skin irritation occurs, Get medical advice/attention. P333+P313 If skin irritation or rash occurs, Get medical advice/attention. P337+P313 If eye irritation persists, Get medical advice/attention. P342+P311 Take off contaminated clothing and wash before reuse. P377 Leaking gas fire, Do not extinguish unless leak can be stopped safely. P391 Eliminate all ignition sources if safe to do so.

Disposal

P501 Dispose of contents/container according to local, regional, national, and international regulations. Emergency Overview Immediate Concerns: DANGER! Extremely Flammable liquid and vapor. Vapor may cause flash fire and explosion. Contents under pressure. Harmful or fatal if swallowed. Intentional misuse or deliberate inhalation may cause death without warning. Vapor reduces oxygen available for breathing and is heavier than air. Vapors may cause dizziness, headache, nausea, drowsiness, unconsciousness and respiratory irritation. Can cause eye and skin irritation.

Potential health effects

Eyes: Can cause severe eye irritation and corneal damage. Skin: Cause defatting and skin irritation. Can cause dermatitis. Skin Absorption: May be absorbed through the skin in harmful amounts. Ingestion: Can cause gastrointestinal irritation, nausea and vomiting Aspiration of material into the lungs may cause chemical pneumonitis, which can be fatal. Harmful or fatal if swallowed Inhalation: May cause nose or throat irritation, High concentrations may lead to central nervous system effects (drowsiness, dizziness, nausea, headaches, paralysis and loss of consciousness) Routes of Entry: Eye Contact, Ingestion, Inhalation, Skin Absorption, and Skin Contact Target Organ Statement: Central Nervous Systems (CNS) Irritancy: Eyes, nose, throat, respiratory tract, and skin irritation.