MasterRoc RBA 387 PART B

Hazard statements (CLP)

H315, H317, H320, H332, H334, H335, H373

Code

Statements

H315

Causes skin irritation

SECTION 2: Hazards identification

GHS Classification GHS classification in accordance with the Hazardous Products Regulations Acute toxicity (Inhalation) Category 4 Skin corrosion/irritation Category 2 Serious eye damage/eye Category 2B irritation Respiratory sensitization Category 1 Skin sensitization Category 1 Specific target organ toxicity Category 3 (respiratory tract irritation) - single exposure Specific target organ toxicity Category 2 (Olfactory organs, Respiratory system) - repeated exposure (Inhala- tion)

Signal word

Danger

Hazard statements

H320 Causes eye irritation. H315 Causes skin irritation. H332 Harmful if inhaled. H334 May cause allergy or asthma symptoms or breathing diffi- culties if inhaled. H317 May cause an allergic skin reaction. H335 May cause respiratory irritation. H373 May cause damage to organs (Olfactory organs, Respira- tory system) through prolonged or repeated exposure if inhaled.

Prevention

P280 Wear protective gloves. P271 Use only outdoors or in a well-ventilated area. P260 Do not breathe dust or mist. P284 In case of inadequate ventilation wear respiratory protec- tion. P272 Contaminated work clothing should not be allowed out of the workplace. P264 Wash face, hands and any exposed skin thoroughly after handling.

Response

P312 Call a POISON CENTER or doctor/ physician if you feel unwell. P305 + P351 + P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P304 + P340 IF INHALED: Remove person to fresh air and keep comfortable for breathing. P314 Get medical advice/ attention if you feel unwell. P303 + P352 IF ON SKIN (or hair): Wash with plenty of soap and water. P333 + P311 If skin irritation or rash occurs: Call a POISON CENTER or doctor/physician. P332 + P313 If skin irritation occurs: Get medical advice/ atten- tion. P362 + P364 Take off contaminated clothing and wash it before reuse. P337 + P313 If eye irritation persists: Get medical advice/ atten- tion.

Storage

P403 + P233 Store in a well-ventilated place. Keep container tightly closed. P405 Store locked up.

Disposal

P501 Dispose of contents/container to appropriate hazardous waste collection point.

2.3 Other hazards

CONTAINS ISOCYANATES. INHALATION OF ISOCYANATE MISTS OR VAPORS MAY CAUSE RESPIRATORY IRRITATION, BREATHLESSNESS, CHEST DISCOMFORT AND REDUCED PULMONARY FUNCTION. OVEREXPOSURE WELL ABOVE THE PEL MAY RESULT IN BRONCHITIS, BRONCHIAL SPASMS AND PULMONARY EDEMA. LONG-TERM EXPOSURE TO ISOCYANATES HAS BEEN REPORTED TO CAUSE LUNG DAMAGE, INCLUDING REDUCED LUNG FUNCTION WHICH MAY BE PERMANENT. ACUTE OR CHRONIC OVEREXPOSURE TO ISOCYANATES MAY CAUSE SENSITIZATION IN SOME INDIVIDUALS, RESULTING IN ALLERGIC RESPIRATORY REACTIONS INCLUDING WHEEZING, SHORTNESS OF BREATH AND DIFFICULTY BREATHING. ANIMAL TESTS INDICATE THAT SKIN CONTACT MAY PLAY A ROLE IN CAUSING RESPIRATORY SENSITIZATION.