8810-B

Hazard statements (CLP)

H315, H317, H319, H332, H334, H335, H373

Code

Statements

H315

Causes skin irritation

SECTION 2: Hazards identification

Classification of the substance or mixture Acute Toxicity (Inhalation) - Category 4 H332 Harmful if inhaled Skin Irritation - Category 2 H315 Causes skin irritation Eye damage/irritation – Category 2A H319 Causes serious eye irritation Sensitization - respiratory – Category 1 H334 May cause allergy or asthma symptoms or breathing difficulties if inhaled Sensitization - skin – Category 1 H317 May cause an allergic skin reaction Specific target organ toxicity (single exposure) – Category H335 May cause respiratory irritation Specific target organ toxicity (repeated exposure) – H373 May cause damage to organs through prolonged Category 2 or repeated exposure Contd. on page 2) CA Contd. of page 1)

2.2 Label elements

The product is classified and labeled according to the Globally Harmonized System (GHS).

Hazard pictograms

GHS07 GHS08

Signal word

Danger

Hazardous Ingredients

diphenylmethanediisocyanate,isomeres and homologues 4,4'-methylenediphenyl diisocyanate

Hazard statements

H332 Harmful if inhaled. H315 Causes skin irritation. H319 Causes serious eye irritation. H334 May cause allergy or asthma symptoms or breathing difficulties if inhaled. H317 May cause an allergic skin reaction. H335 May cause respiratory irritation. H373 May cause damage to organs through prolonged or repeated exposure.

Precautionary statements

P260 Do not breathe mist, vapors, or spray. P264 Wash thoroughly after handling. P271 Use only outdoors or in a well-ventilated area. P272 Contaminated work clothing should not be allowed out of the workplace. P280 Wear protective gloves, protective clothing, and eye protection. P284 [In case of inadequate ventilation] wear respiratory protection. P302+P352 IF ON SKIN: Wash with plenty of water. P304+P340 IF INHALED: Remove person to fresh air and keep comfortable for breathing. P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P312 Call a POISON CENTER or doctor if you feel unwell. P333+P313 If skin irritation or rash occurs: Get medical advice. P337+P313 If eye irritation persists: Get medical advice. P342+P311 If experiencing respiratory symptoms: Call a POISON CENTER or doctor. P362+P364 Take off contaminated clothing and wash it before reuse. P403+P233 Store in a well-ventilated place. Keep container tightly closed. P405 Store locked up. P501 Dispose of contents and container in accordance with local, regional, and national regulations.

Other hazards

Not available CA (Contd. on page 3) (Contd. of page 2)

2.1 Classification of the substance or mixture

Acute Toxicity (Inhalation) - Category 4 H332 Harmful if inhaled. Skin Irritation - Category 2 H315 Causes skin irritation. Eye damage/irritation – Category 2A H319 Causes serious eye irritation. Sensitization - respiratory – Category 1 H334 May cause allergy or asthma symptoms or breathing difficulties if inhaled. Sensitization - skin – Category 1 H317 May cause an allergic skin reaction. Specific target organ toxicity (single exposure) – Category H335 May cause respiratory irritation. 3 Specific target organ toxicity (repeated exposure) – H373 May cause damage to organs through prolonged Category 2 or repeated exposure. (Contd. on page 2) CA (Contd. of page 1)