8829 H BLACK

SECTION 2: Hazards identification

OSHA IDENTIFICATION EMERGENCY OVERVIEW

HMIS® ratings

SYSTEM

NFPA Ratings

SYSTEM Health: 1 Health: 1 Flammability: 1 Reactivity: 0 Protection: B POTENTIAL HEALTH CONSIDERATIONS LIKELY ROUTES OF ENTRY: Contact; Inhalation TARGET ORGANS: Eyes; Kidneys; Skin; Digestive Tract; Nervous System; Blood; Liver; POTENTIAL IMMEDIATE EFFECTS FROM OVEREXPOSURE EYE CONTACT Page 3. 3. HAZARDS IDENTIFICATION (Cont.) (Cont.) Can cause severe eye irritation, tearing and reddening, but not likely to permanently injure eye tissue. Temporary vision impairment (cloudy or blurred vision) is possible. Can cause mechanical irritation if dusts are generated. SKIN CONTACT Can cause minor skin irritation, defatting, and dermatitis. SKIN ABSORBTION Toxic if absorbed through the skin causing systemic damage. INHALATION Can cause respiratory irritation, dizziness, weakness, fatigue, nausea, headache and possible unconsciousness. INGESTION Irritating to mouth, throat, and stomach. Can cause abdominal discomfort, nausea, vomiting and diarrhea. POTENTIAL LONG-TERM EFFECTS FROM OVEREXPOSURE:

Cancer information

Contains a substance that caused cancer in laboratory animals. See Section 11. REPRODUCTIVE SYSTEM INFORMATION None of the substances have been shown to cause reproductive system disorders. ADDITIONAL HEALTH HAZARD INFORMATION Triethyl phosphate: This substance may cause nerve damage but to a lesser extent compared to other cholinesterase-inhibiting compounds. MEDICAL CONDITIONS POTENTIALLY AGGRAVATED BY OVEREXPOSURE ____________________________________________________________________ 4. 4. FIRST FIRST AID AID MEASURES MEASURES EYE CONTACT Immediately flush eyes with plenty of water for at least 20 minutes retracting eyelids often. Get immediate medical attention. SKIN CONTACT Wash skin with soap and water. Remove contaminated clothing and launder. Get medical attention if irritation develops or persists. INHALATION Remove to fresh air. If not breathing, perform rescue breathing and, if available, have a trained person administer oxygen. Get medical attention immediately. INGESTION Page 4. 4. FIRST FIRST AID AID MEASURES MEASURES (Cont.) (Cont.) Emergency personnel should be contacted immediately and be provided with this MSDS. For ingestion of small quantities of chemicals, the risk associated with inducing vomiting usually exceeds the poisoning risk. Get medical attention immediately. Contact a poison information service. Do not induce vomiting. Never give anything by mouth to an unconscious person. ____________________________________________________________________ 5. 5. FIRE FIRE FIGHTING FIGHTING MEASURES MEASURES FLAMMABILITY DATA FLASH POINT: 210 F, 98 C EXPLOSIVE/FLAMMABILITY LIMITS ESTIMATED FROM INGREDIENTS: LOWER LIMIT: 0.8 % UPPER LIMIT: 10.0 % AUTOIGNITION TEMPERATURE ESTIMATED FROM INGREDIENTS: 394 F, 201 C GENERAL HAZARDS Material may ignite if heated to temperatures above the flash point in the presence of a source of ignition. EXTINGUISHING MEDIA Use alcohol foam, carbon dioxide (CO2) or dry chemical. Water may not be effective to extinguish fire. Use water spray to cool fire-exposed containers and to protect personnel. FIRE FIGHTING INSTRUCTIONS Do not enter fire area without proper protection including self-contained breathing apparatus and full protective equipment. Fight fire from a safe distance and a protected location. Heat may build pressure and rupture closed containers, spreading fire and increasing risk of burns or injuries. Use water spray/fog for cooling. Even if material is water soluble, it may not be practical to extinguish fire by water dilution. Notify authorities if liquid enters sewers or other public waters. HAZARDOUS COMBUSTION PRODUCTS carbon dioxide; carbon monoxide; sulfur containing gases; phosphorus compounds ____________________________________________________________________ 6. 6. ACCIDENTAL ACCIDENTAL RELEASE RELEASE MEASURES MEASURES SPILL CLEAN-UP PROCEDURES Prevent the spread of any spill to minimize harm to human health and the environment. Dike with suitable absorbent material. Wear complete and proper personal protective equipment and ventilate the area. HEALTH CONSIDERATIONS AND PROTECTIVE EQUIPMENT Information on the selection and use of personal protective equipment is found in Section 8 of this msds. Personal protective equipment needs must be evaluated based on information provided on this sheet and the special circumstances created by the spill including; material spilled, quantity, the Page 6. 6. ACCIDENTAL ACCIDENTAL RELEASE RELEASE MEASURES MEASURES (Cont.) (Cont.) area in which it occurred and the expertise of employees in the area responding to the spill. Never exceed any occupational exposure limits and consider that the evaporation of volatile solvents can lead to the displacement of air creating an environment that can cause asphxyiation. ____________________________________________________________________ 7. 7. HANDLING HANDLING AND AND STORAGE

Storage

HANDLING Avoid contact with material, avoid breathing vapors, use only in a well ventilated area. Store in a cool, dry place. Isolate from incompatible materials. ____________________________________________________________________ 8. 8. EXPOSURE EXPOSURE CONTROLS CONTROLS AND AND PERSONAL PERSONAL PROTECTION PROTECTION ENGINEERING CONTROLS Local exhaust ventilation or other engineering controls are normally required when handling or using this product to keep exposure to airborne contaminants below the TLV, PEL, or other recommended exposure limit and/or maintain operator comfort. These controls should be explosion-proof when exhausting flammable vapors. Facilities storing or using this material should be equipped with an eyewash and safety shower. RESPIRATORY PROTECTION If air monitoring indicates airborne concentrations at or above the limits, or symptoms of inhalation over-exposure occur, a respiratory protection program may be required. Engineering controls to reduce the exposure below acceptable limits are usually preferable to a respirator program. EYE PROTECTION Chemically resistant safety glasses with side shields must be worn when handling this product. Contact lenses should not be worn. An eye wash station should be available. SKIN PROTECTION Depending upon conditions of use, wear protective gloves and other protective equipment. Inspect gloves for chemical break-through and replace as needed. Clean equipment thoroughly after each use. Appropriate gloves to be used for MARKEM products that are mixtures have not been determined. Glove type(s) for ingredients present at 10% or more (if known) are: Nitrile ____________________________________________________________________ 9. 9. PHYSICAL PHYSICAL AND AND CHEMICAL CHEMICAL PROPERTIES PROPERTIES - - PRODUCT PRODUCT MIXTURE MIXTURE APPEARANCE: Liquid, semi-solid, or solid COLOR: See description in Section 1. ODOR: Mild solvent odor SPECIFIC GRAVITY(g/ml): 1.06 Page 9. 9. PHYSICAL PHYSICAL AND AND CHEMICAL CHEMICAL PROPERTIES PROPERTIES - - PRODUCT PRODUCT MIXTURE MIXTURE (Cont.) (Cont.) PERCENT VOLATILE: 37 VOC CONTENT: Not Determined VAPOR PRESSURE(mmHg): <0.01 BOILING PT OR RANGE: ND pH: ND VISCOSITY: ND VAPOR DENSITY: Heavier than air FREEZING POINT: ND EVAPORATION RATE: 0.01-0.1 (n-Butyl acetate = 1) ____________________________________________________________________ 9.1 9.1 EXPOSURE, EXPOSURE, PHYSICAL PHYSICAL AND AND CHEMICAL CHEMICAL PROPERTIES PROPERTIES FOR FOR INGREDIENTS INGREDIENTS COMPONENT ACGIH OSHA TWA\CEIL STEL TWA CEIL 1333-86-4 3.5 mg/m3 NE 3.5 mg/m3 NE 124-17-4 NE 78-40-0 NE SPECIFIC EVAP RATE WATER VAPOR GRAVITY N-BUTYL SOLUBILITY PRESSURE COMPONENT CAS NUMBER ACETATE=1 % mmHg 1333-86-4 1.800 ND Insoluble ND 124-17-4 0.981 0.01 6.5% .04 mmHg @ 20°C 78-40-0 1.070 ND 100% <1 ____________________________________________________________________ 10. 10. STABILITY STABILITY AND AND REACTIVITY REACTIVITY STABILITY Stable under normal conditions. CONDITIONS TO AVOID Elevated temperatures in combination with sparks, open flames, or other sources of ignition. INCOMPATIBILITY strong oxidizing agents; acids; caustics (bases) HAZARDOUS DECOMPOSITION PRODUCTS carbon dioxide; carbon monoxide; sulfur containing gases; phosphorus compounds ____________________________________________________________________ 11. 11. TOXICOLOGICAL TOXICOLOGICAL INFORMATION INFORMATION Carbon black: NTP: Not classified OSHA: Not classified ACGIH: Not classifiable as a human carcinogen (A4) IARC: Carbon black is possibly carcinogenic to humans (Group 2B) Page 11. 11. TOXICOLOGICAL TOXICOLOGICAL INFORMATION INFORMATION (Cont.) (Cont.) Evaluation: There is inadequate evidence in humans for the carcinogenicity of carbon black. There is sufficient evidence in experimental animals for the carcinogenicity of carbon black. There is sufficient evidence in experimental animals for the carcinogenicity of carbon black extracts. Overall evaluation: Carbon black is possibly carcinogenic to humans (Group 2B) [IARC. Monographs on the Evaluation of the Carcinogenic Risk of Chemicals to Man. Geneva: World Health Organization, International Agency for Research on Cancer,1972-PRESENT. (Multivolume work).,p. 65 247 (1996)]. LC50 (inhalation, rat): 27000 mg/m3 (27 mg/L) (1-hour exposure). CHRONIC INHALATION: Hamsters, mice, guinea pigs, rabbits and monkeys exposed to carbon blacks (channel black or furnace black) at concentrations of 85 mg/m3 (channel black) and 56 mg/m3 (furnace black) intermittently for periods up to 3000 hours (13,000 hours for monkeys) showed no significant effects other than accumulation of dusts in the lungs. The channel black contained extremely low levels of benzene-extractable material and the furnace black contained 0.28% extractable material. ____________________________________________________________________ 12. 12. ECOLOGICAL ECOLOGICAL INFORMATION INFORMATION Triethyl phosphate: If released to soil, will likely leach into groundwater. Triethyl phosphate released to water will not evaporate, adsorb strongly to sediments, or hydrolyze. ____________________________________________________________________ 13. 13. DISPOSAL DISPOSAL CONSIDERATIONS CONSIDERATIONS Dispose of by incineration or waste water treatment following Federal, State, Provincial, or Local regulations. ____________________________________________________________________ 14. 14. TRANSPORT TRANSPORT INFORMATION, INFORMATION, DOT DOT and and IATA: IATA: DOT & IATA: NOT RESTRICTED ____________________________________________________________________ 15. 15. REGULATORY REGULATORY INFORMATION INFORMATION Those ingredients appearing on the following list that do not appear in Section 2 are present at <0.1% for carcinogens, <1% for other hazardous substances, or are not considered hazardous in this product. UNITED STATES OF AMERICA FEDERAL REGULATIONS CERCLA: The following components have CERCLA reportable quantities: CASRN DESCRIPTION None RCRA: The following components are subject to RCRA land disposal restrictions: CASRN DESCRIPTION None Page 15. 15. REGULATORY REGULATORY INFORMATION INFORMATION (Cont.) (Cont.) SARA TITLE III SECTION 302 Extremely Hazardous Substances (EHS) CASRN DESCRIPTION None SECTION 311/312 Community Right to Know CASRN DESCRIPTION None SARA HAZARD CATEGORY INFORMATION FIRE: NO SUDDEN RELEASE OF PRESSURE: NO REACTIVE: NO IMMEDIATE (ACUTE) HEALTH HAZARD: NO DELAYED (CHRONIC) HEALTH HAZARD: NO SECTION 313 Toxic Chemical Release Inventory Reporting (TRI) CASRN DESCRIPTION None TSCA SECTION 8(b) Inventory: All chemicals in this product appear in the inventory or are exempt from the listing requirements. SECTION 12(b) Export: The following chemicals are subject to export reporting CASRN DESCRIPTION 124-17-4 2-(2-BUTOXYETHOXY)ETHYL ACETATE STATE REGULATIONS CALIFORNIA SAFE DRINKING WATER AND TOXIC ENFORCEMENT ACT (PROPOSITION 65) The following chemical(s) in this product are known to the State of California to cause cancer: CASRN DESCRIPTION None The following chemical(s) in this product are known to the State of California to be hazards to reproductive health: CASRN DESCRIPTION None MASSACHUSETTS Right to Know Law CASRN DESCRIPTION % 1333-86-4 CARBON BLACK 10-30 NEW JERSEY Right to Know Law CASRN DESCRIPTION % 1333-86-4 CARBON BLACK 10-30 PENNSYLVANIA Right to Know Law CASRN DESCRIPTION % 1333-86-4 CARBON BLACK 10-30 CANADA WHMIS: The following components are WHMIS Workplace Hazardous Materials: CASRN DESCRIPTION % 1333-86-4 CARBON BLACK 10-30 KOREA All chemicals appear on the Korean Existing and Evaluated Chemicals Inventory unless otherwise listed. Chemicals appearing on the Korean Harmful Substances List: None Page 15. 15. REGULATORY REGULATORY INFORMATION INFORMATION (Cont.) (Cont.) Chemicals appearing on the Korean Observational Chemicals List: None Chemicals appearing on the Korean Industrial Safety and Health List: None ____________________________________________________________________ 16. 16. OTHER