8829 BRITE BLUE

SECTION 2: Hazards identification

OSHA IDENTIFICATION EMERGENCY OVERVIEW

HMIS® ratings

SYSTEM

NFPA Ratings

SYSTEM Health: 3 Health: 3 Flammability: 1 Reactivity: 0 Protection: B POTENTIAL HEALTH CONSIDERATIONS LIKELY ROUTES OF ENTRY: Inhalation; Contact TARGET ORGANS: Kidneys; Eyes; Skin; Digestive Tract; Nervous System; Blood; Liver; POTENTIAL IMMEDIATE EFFECTS FROM OVEREXPOSURE Page 3. 3. HAZARDS IDENTIFICATION (Cont.) (Cont.) EYE CONTACT Can cause severe eye irritation, tearing and reddening, but not likely to permanently injure eye tissue. Temporary vision impairment (cloudy or blurred vision) is possible. SKIN CONTACT Can cause minor skin irritation, defatting or dermatitis. SKIN ABSORBTION Toxic if absorbed through the skin causing systemic damage. INHALATION Toxic by inhalation, can cause severe irritation or burns, pulmonary edema or lung inflamation. Central nervous system effects such as dizziness, weakness, fatigue, nausea, headache, unconsciousness and even asphyxiation are possible. INGESTION Toxic. If swallowed, may cause abdominal discomfort, nausea, vomiting, diarrhea and systemic poisoning. Aspiration of material into the lungs can cause chemical pneumonitis which can be fatal. POTENTIAL LONG-TERM EFFECTS FROM OVEREXPOSURE:

Cancer information

Contains a substance that is a possible cancer hazard based on human studies. REPRODUCTIVE SYSTEM INFORMATION None of the substances in this product have been shown to cause reproductive system disorders. ADDITIONAL HEALTH HAZARD INFORMATION Bis (Tributyltin) Oxide: This substance may be absorbed through skin in toxic amounts and may be fatal if swallowed. Triethyl phosphate: This substance may cause nerve damage but to a lesser extent compared to other cholinesterase-inhibiting compounds. MEDICAL CONDITIONS POTENTIALLY AGGRAVATED BY OVEREXPOSURE No data found ____________________________________________________________________ 4. 4. FIRST FIRST AID AID MEASURES MEASURES EYE CONTACT Immediately flush eyes with plenty of water for at least 20 minutes retracting eyelids often. Get immediate medical attention. SKIN CONTACT Wash skin with soap and water. Remove contaminated clothing and launder. Get medical attention if irritation develops or persists. INHALATION Page 4. 4. FIRST FIRST AID AID MEASURES MEASURES (Cont.) (Cont.) Remove to fresh air. If not breathing, perform rescue breathing and, if available, have a trained person administer oxygen. Get medical attention immediately. INGESTION Emergency personnel should be contacted immediately and be provided with this MSDS. For ingestion of small quantities of chemicals, the risk associated with inducing vomiting usually exceeds the poisoning risk. Get medical attention immediately. Contact a poison information service. Do not induce vomiting. Never give anything by mouth to an unconscious person. ____________________________________________________________________ 5. 5. FIRE FIRE FIGHTING FIGHTING MEASURES MEASURES FLAMMABILITY DATA FLASH POINT: 210 F, 98 C EXPLOSIVE/FLAMMABILITY LIMITS ESTIMATED FROM INGREDIENTS: LOWER LIMIT: 0.8 % UPPER LIMIT: 10.0 % AUTOIGNITION TEMPERATURE ESTIMATED FROM INGREDIENTS: 394 F, 201 C GENERAL HAZARDS Vapors may be ignited by heat, sparks, flames or other sources of ignition if heated above the flash point. Vapors are heavier than air and may travel to a source of ignition and flash back. Container may explode in heat of fire. Empty container may still contain residual material that can ignite and/or explode. Do not pressurize, cut, weld, braze, solder, drill, grind, or expose empty container to heat, flame, sparks, static electricity, or other sources of ignition. EXTINGUISHING MEDIA Use alcohol foam, carbon dioxide (CO2) or dry chemical. Water may not be effective to extinguish fire. Use water spray to cool fire-exposed containers and to protect personnel. FIRE FIGHTING INSTRUCTIONS Do not enter fire area without proper protection including self-contained breathing apparatus and full protective equipment. Fight fire from a safe distance and a protected location. Heat may build pressure and rupture closed containers, spreading fire and increasing risk of burns or injuries. Use water spray/fog for cooling. Even if material is water soluble, it may not be practical to extinguish fire by water dilution. Notify authorities if liquid enters sewers or other public waters. HAZARDOUS COMBUSTION PRODUCTS carbon dioxide; carbon monoxide; phosphorus compounds Page 6. 6. ACCIDENTAL ACCIDENTAL RELEASE RELEASE MEASURES MEASURES SPILL CLEAN-UP PROCEDURES Shut off ignition sources; smoking, flames or other sources of ignition must not be permitted in the area. Small Spills: Take up with sand or other noncombustible absorbent material and put into properly labeled containers for disposal. Large Spills: Dike ahead of liquid spill area to minimize migration and vapor generation. Ventilate the area. Get professional help from outside contractors, the fire department or your trained spill brigade. HEALTH CONSIDERATIONS AND PROTECTIVE EQUIPMENT Information on the selection and use of personal protective equipment is found in Section 8 of this msds. Personal protective equipment needs must be evaluated based on information provided on this sheet and the special circumstances created by the spill including; material spilled, quantity, the area in which it occurred and the expertise of employees in the area responding to the spill. Never exceed any occupational exposure limits and consider that the evaporation of volatile solvents can lead to the displacement of air creating an environment that can cause asphxyiation. ____________________________________________________________________ 7. 7. HANDLING HANDLING AND AND STORAGE

Storage

HANDLING Avoid contact with material, avoid breathing vapors, use only in a well ventilated area, use bonding and grounding when transferring this material. Store in a cool dry ventilated location, away from oxidizers, heat, flame or other incompatible conditions. Keep container(s) closed if possible. ____________________________________________________________________ 8. 8. EXPOSURE EXPOSURE CONTROLS CONTROLS AND AND PERSONAL PERSONAL PROTECTION PROTECTION ENGINEERING CONTROLS Local exhaust ventilation or other engineering controls are normally required when handling or using this product to keep exposure to airborne contaminants below the TLV, PEL, or other recommended exposure limit and/or maintain operator comfort. These controls should be explosion-proof when exhausting flammable vapors. Facilities storing or using this material should be equipped with an eyewash and safety shower. RESPIRATORY PROTECTION If air monitoring indicates airborne concentrations at or above the limits, or symptoms of inhalation over-exposure occur, a respiratory protection program may be required. Engineering controls to reduce the exposure below acceptable limits are usually preferable to a respirator program. EYE PROTECTION Chemically resistant safety glasses with side shields must be worn when handling this product. Further eye protection such as chemical splash goggles and/or face shield must be worn when the possibility exists for eye contact due to splashing or spraying liquid or airborne particles. Contact lenses Page 8. 8. EXPOSURE EXPOSURE CONTROLS CONTROLS AND AND PERSONAL PERSONAL PROTECTION PROTECTION (Cont.) (Cont.) should not be worn. An eye wash station should be available. SKIN PROTECTION Depending upon conditions of use, wear protective gloves and other protective equipment. Inspect gloves for chemical break-through and replace as needed. Clean equipment thoroughly after each use. Appropriate gloves to be used for MARKEM products that are mixtures have not been determined. Glove type(s) for ingredients present at 10% or more (if known) are: Nitrile ____________________________________________________________________ 9. 9. PHYSICAL PHYSICAL AND AND CHEMICAL CHEMICAL PROPERTIES PROPERTIES - - PRODUCT PRODUCT MIXTURE MIXTURE APPEARANCE: Liquid COLOR: Blue ODOR: Mild solvent odor SPECIFIC GRAVITY(g/ml): 1.30 PERCENT VOLATILE: 28 VOC CONTENT: Not Determined VAPOR PRESSURE(mmHg): <0.01 BOILING PT OR RANGE: ND pH: ND VISCOSITY: ND VAPOR DENSITY: Heavier than air FREEZING POINT: ND EVAPORATION RATE: 0.01-0.1 (n-Butyl acetate = 1) ____________________________________________________________________ 9.1 9.1 EXPOSURE, EXPOSURE, PHYSICAL PHYSICAL AND AND CHEMICAL CHEMICAL PROPERTIES PROPERTIES FOR FOR INGREDIENTS INGREDIENTS COMPONENT ACGIH OSHA TWA\CEIL STEL TWA CEIL 56-35-9 0.1 skin NE 124-17-4 NE 64742-95-6 NE NE 78-40-0 NE SPECIFIC EVAP RATE WATER VAPOR GRAVITY N-BUTYL SOLUBILITY PRESSURE COMPONENT CAS NUMBER ACETATE=1 % mmHg 56-35-9 1.170 ND No data ND 124-17-4 0.981 0.01 6.5% .04 mmHg @ 20°C 64742-95-6 0.750 ND No data ND 78-40-0 1.070 ND 100% 1.33 mbar @ 40 C Page 10. 10. STABILITY STABILITY AND AND REACTIVITY REACTIVITY STABILITY Stable under normal conditions. CONDITIONS TO AVOID Elevated temperatures in combination with sparks, open flames, or other sources of ignition. INCOMPATIBILITY acids; caustics (bases); strong oxidizing agents; HAZARDOUS DECOMPOSITION PRODUCTS carbon dioxide; carbon monoxide; phosphorus compounds ____________________________________________________________________ 11. 11. TOXICOLOGICAL TOXICOLOGICAL INFORMATION INFORMATION Bis (Tributyltin) Oxide: Eye rabbit 50 ug/24H, Effect Severe Oral LD50 rat: 194 mg/kg (1983) / 122 mg/kg (1981-82) Triethyl phosphate: Oral LD50 rat 1600 mg/kg, Effect Behaviroal (General anesthetic) Inhalation LCLo rat: 28000 ppm/6H ____________________________________________________________________ 12. 12. ECOLOGICAL ECOLOGICAL INFORMATION INFORMATION Triethyl phosphate: If released to soil, will likely leach into groundwater. Triethyl phosphate released to water will not evaporate, adsorb strongly to sediments, or hydrolyze. ____________________________________________________________________ 13. 13. DISPOSAL DISPOSAL CONSIDERATIONS CONSIDERATIONS Dispose of by incineration or waste water treatment following Federal, State, Provincial, or Local regulations. ____________________________________________________________________ 14. 14. TRANSPORT TRANSPORT INFORMATION, INFORMATION, DOT DOT and and IATA: IATA: DOT & IATA: NOT RESTRICTED ____________________________________________________________________ 15. 15. REGULATORY REGULATORY INFORMATION INFORMATION Those ingredients appearing on the following list that do not appear in Section 2 are present at <0.1% for carcinogens, <1% for other hazardous substances, or are not considered hazardous in this product. UNITED STATES OF AMERICA FEDERAL REGULATIONS CERCLA: The following components have CERCLA reportable quantities: CASRN DESCRIPTION Page 15. 15. REGULATORY REGULATORY INFORMATION INFORMATION (Cont.) (Cont.) None RCRA: The following components are subject to RCRA land disposal restrictions: CASRN DESCRIPTION None SARA TITLE III SECTION 302 Extremely Hazardous Substances (EHS) CASRN DESCRIPTION None SECTION 311/312 Community Right to Know CASRN DESCRIPTION 56-35-9 BIS(TRIBUTYLTIN)OXIDE SARA HAZARD CATEGORY INFORMATION FIRE: NO SUDDEN RELEASE OF PRESSURE: NO REACTIVE: NO IMMEDIATE (ACUTE) HEALTH HAZARD: NO DELAYED (CHRONIC) HEALTH HAZARD: NO SECTION 313 Toxic Chemical Release Inventory Reporting (TRI) CASRN DESCRIPTION 56-35-9 BIS(TRIBUTYLTIN)OXIDE 0 TSCA SECTION 8(b) Inventory: All chemicals in this product appear in the inventory or are exempt from the listing requirements. SECTION 12(b) Export: The following chemicals are subject to export reporting CASRN DESCRIPTION 124-17-4 2-(2-BUTOXYETHOXY)ETHYL ACETATE STATE REGULATIONS CALIFORNIA SAFE DRINKING WATER AND TOXIC ENFORCEMENT ACT (PROPOSITION 65) The following chemical(s) in this product are known to the State of California to cause cancer: CASRN DESCRIPTION None The following chemical(s) in this product are known to the State of California to be hazards to reproductive health: CASRN DESCRIPTION None MASSACHUSETTS Right to Know Law CASRN DESCRIPTION % 112926-00-8 PRECIPITATED SILICA 1-5 56-35-9 BIS(TRIBUTYLTIN)OXIDE 0.1-1 1309-48-4 MAGNESIUM OXIDE FUME 0.01-0.1 13463-67-7 TITANIUM DIOXIDE 10-30 NEW JERSEY Right to Know Law CASRN DESCRIPTION % 1309-48-4 MAGNESIUM OXIDE 0.01-0.1 13463-67-7 TITANIUM DIOXIDE 10-30 PENNSYLVANIA Right to Know Law CASRN DESCRIPTION % 112926-00-8 PRECIPITATED SILICA 1-5 1309-48-4 MAGNESIUM OXIDE (MGO) 0.01-0.1 13463-67-7 TITANIUM OXIDE (TIO2) 10-30 Page 15. 15. REGULATORY REGULATORY INFORMATION INFORMATION (Cont.) (Cont.) CANADA WHMIS: The following components are WHMIS Workplace Hazardous Materials: CASRN DESCRIPTION % 56-35-9 BIS(TRIBUTYLTIN)OXIDE 0.1-1 KOREA All chemicals appear on the Korean Existing and Evaluated Chemicals Inventory unless otherwise listed. Chemicals appearing on the Korean Harmful Substances List: None Chemicals appearing on the Korean Observational Chemicals List: None Chemicals appearing on the Korean Industrial Safety and Health List: None ____________________________________________________________________ 16. 16. OTHER