7224

Hazard statements (CLP)

H228

Code

Statements

H228

Flammable solid

Hazardous Ingredients

COMPONENT CAS # PCT (WT) Castor oil, hydrogenated 8001-78-3 1-5 Formaldehyde 50-00-0 O.1-1 Trade secret TSOQO00-11-6 0.5-1.5 Cyclohexane- 1,2-dicarboxylic anhydride 85-42-7 1-5 N-butyl alcohol 71-36-3 1-5 Tributyl phosphate 126-73-8 20-40 2-methyl-1-propanol 78-83-1 O.1-1 Exposure and physical property information is presented in Section 9. TE the total percentage is less than 100, the balance of this product is not considered to be hazardous as defined in

SECTION 2: Hazards identification

IDENTIFICATION EMERGENCY OVERVIEW

HMIS® ratings

SYSTEM

NFPA Ratings

SYSTEM Health: 3 Health: 3 Flammability: 1 Flammability: 1 Reactivity: a Reactivity: 1 Protection: B POTENTIAL HEALTH CONSIDERATIONS LIKELY ROUTES OF ENTRY: Absorption; Inhalation; Contact; Ingestion TARGET ORGANS: Skin; Nervous System; Respiratory Tract; Eyes; Lungs; Kidneys; Blood; Page 2 OF 10 3. IDENTIFICATION (Cont.)} Liver; Bladder; Heart; POTENTIAL IMMEDIATE EFFECTS FROM OVEREXPOSURE EYE CONTACT Can cause severe eye irritation, tearing and reddening, but not likely to permanently injure eye tissue. Temporary vision impairment (cloudy or blurred vision) is possible. SKIN CONTACT Corrosive to skin tissue, can cause chemical burns. Skin Sensitizer! Avoid exposure. If sensitized, repeated exposures will result in skin irritation, even at very low concentrations. SKIN ABSORBTION Toxic if absorbed through the skin causing systemic damage. TNHALATION Can cause severe respiratory irritation, dizziness, weakness, fatigue, nausea, headache and possible unconsciousness. Respiratory Sensitizer! Avoid exposure. If sensitized, repeated exposures will result in respiratory irritation and shortness of breath, even at very low concentrations. These asthma-type symptoms may develop immediately or be delayed up to several hours. INGESTION Toxic. If swallowed, may cause abdominal discomfort, nausea, vomiting, diarrhea and systemic poisoning. Aspiration of material into the lungs can cause chemical pneumonitis which can be fatal. Upon ingestion of a large quantity of this material, visual disturbances may occur. Onset of the response may be delayed. POTENTIAL LONG-TERM EFFECTS FROM OVEREXPOSURE

Contains

a substance that is a possible cancer hazard based on human studies. No IARC cancer hazard information available. a substance which is classified by ACGIH as A2: Suspected human carcinogen. No NTP cancer hazard information available. No a substance that is a possible reproductive hazard based on tests with laboratory animals.

Additional information

HEALTH HAZARD Formaldehyde: Exposure to formaldehyde vapor at concentrations >1 ppm may cause significant irritation of the eyes and respiratory tract. Irritation threshold is about 0.3 ppm. Formaldehyde was found to be weakly active in Page 3 OF 10 3. IDENTIFICATION (Cont...) in vitro genotoxicity tests, but inactive in vivo. Lifetime inhalation of formaldehyde vapor at concentrations above 5 ppm for 6 hours/day caused nasal tumors in laboratory animals. Tributyl phosphate: TBP was found not to be neurotoxic either acutely at 1000 mg/kg or after three months of exposure at up to 325 mg/kg/day. Assuming similar absorption of TBP by oral and inhalation routes of exposure and a breathing rate of approximately 170 mL/min, these values are approximately equivalent to inhalation exposures of 4900 mg/cu m acutely and 1590 mg/cu m per day subchronically. The ACGIH TLV (TWA) for TBP is 2.2 mg/cu m. This indicates that a minimum of a 700-fold safety factor exists for TBP as a potential neurotoxin(1). Large doses have been reported to cause dyspnea, weakness, pulmonary edema, and twitching in rats. Chronic inhalation of large doses can lead to general poisoning with paralysis, urinary bladder hyperplasia, and increased liver weight.(1) Healy, C.E.; Beyrouty, P.C.; and Broxup, B.R., Am. Ind. Hyg. Assoc J. 56:349-355 (1995). Tsobutyl alcohol: Administration by subcutaneous injection or by gavage has been reported to cause an increased incidence of benign and malignant tumors in rats. No human findings are available. MEDICAL CONDITIONS POTENTIALLY AGGRAVATED BY OVEREXPOSURE