7132 BLACK

SECTION 2: Hazards identification

OSHA IDENTIFICATION EMERGENCY OVERVIEW

HMIS® ratings

SYSTEM

NFPA Ratings

SYSTEM Health: 3 Health: 3 Flammability: 1 Reactivity: 0 Protection: B POTENTIAL HEALTH CONSIDERATIONS LIKELY ROUTES OF ENTRY: Contact; Inhalation TARGET ORGANS: Eyes; Kidneys; Skin; Digestive Tract; Nervous System; Blood; Liver; Page 3. 3. HAZARDS IDENTIFICATION (Cont.) (Cont.) Respiratory Tract; Heart; Pancreas; POTENTIAL IMMEDIATE EFFECTS FROM OVEREXPOSURE EYE CONTACT Can cause severe eye irritation, tearing and reddening, but not likely to permanently injure eye tissue. Temporary vision impairment (cloudy or blurred vision) is possible. Can cause mechanical irritation if dusts are generated. SKIN CONTACT Can cause minor skin irritation, defatting or dermatitis. Skin Sensitizer! Avoid exposure. If sensitized, repeated exposures will result in skin irritation, even at very low concentrations. SKIN ABSORBTION Toxic if absorbed through the skin causing systemic damage. INHALATION Toxic by inhalation, can cause severe irritation or burns, pulmonary edema or lung inflamation. Central nervous system effects such as dizziness, weakness, fatigue, nausea, headache, unconsciousness and even asphyxiation are possible. Respiratory Sensitizer! Avoid exposure. If sensitized, repeated exposures will result in respiratory irritation and shortness of breath, even at very low concentrations. These asthma-type symptoms may develop immediately or be delayed up to several hours. INGESTION Toxic. If swallowed, may cause abdominal discomfort, nausea, vomiting, diarrhea and systemic poisoning. POTENTIAL LONG-TERM EFFECTS FROM OVEREXPOSURE:

Cancer information

Contains a substance that can cause cancer in laboratory animals at high oral doses. Not a carcinogen according to NTP, IARC, or OSHA. REPRODUCTIVE SYSTEM INFORMATION None of the substances in this product have been shown to cause reproductive system disorders. ADDITIONAL HEALTH HAZARD INFORMATION Bis (Tributyltin) Oxide: This substance may be absorbed through skin in toxic amounts and may be fatal if swallowed. Cobalt: IARC has classified cobalt and cobalt compounds as Group 2B carcinogens. Group 2B carcinogens are possibly carcinogenic to humans. Methyl Ethyl Ketoxime (MEKO): This substance has the potential to cause methmoglobin, cataract formation, and histopathological changes in the upper respiratory tract. MEKO is a known rodent liver carcinogen. Alcohol metabolism may be inhibited by MEKO. Page 3. 3. HAZARDS IDENTIFICATION (Cont.) (Cont.) MEDICAL CONDITIONS POTENTIALLY AGGRAVATED BY OVEREXPOSURE No data found ____________________________________________________________________ 4. 4. FIRST FIRST AID AID MEASURES MEASURES EYE CONTACT Immediately flush eyes with plenty of water for at least 20 minutes retracting eyelids often. Get immediate medical attention. SKIN CONTACT Wash skin with soap and water. Remove contaminated clothing and launder. Get medical attention if irritation develops or persists. INHALATION Remove to fresh air. If not breathing, perform rescue breathing and, if available, have a trained person administer oxygen. Get medical attention immediately. INGESTION Emergency personnel should be contacted immediately and be provided with this MSDS. For ingestion of small quantities of chemicals, the risk associated with inducing vomiting usually exceeds the poisoning risk. Get medical attention immediately. Contact a poison information service. Do not induce vomiting. Never give anything by mouth to an unconscious person. ____________________________________________________________________ 5. 5. FIRE FIRE FIGHTING FIGHTING MEASURES MEASURES FLAMMABILITY DATA FLASH POINT: 237 F, 113 C EXPLOSIVE/FLAMMABILITY LIMITS ESTIMATED FROM INGREDIENTS: LOWER LIMIT: 0.7 % UPPER LIMIT: 5.0 % AUTOIGNITION TEMPERATURE ESTIMATED FROM INGREDIENTS: 394 F, 201 C GENERAL HAZARDS Vapors may be ignited by heat, sparks, flames or other sources of ignition giving rise to a Class B fire. Vapors are heavier than air and may travel to a source of ignition and flash back. Container may explode in heat of fire. Empty container may still contain residual material that can ignite and/or result in an explosion. Do not pressurize, cut, weld, braze, solder, drill, grind, or expose empty container to heat, flame, sparks, static electricity, or other sources of ignition. EXTINGUISHING MEDIA Use alcohol foam, carbon dioxide (CO2) or dry chemical. Water may not be effective to extinguish fire. Use water spray to cool fire-exposed containers and to protect personnel. FIRE FIGHTING INSTRUCTIONS Do not enter fire area without proper protection including self-contained Page 5. 5. FIRE FIRE FIGHTING FIGHTING MEASURES MEASURES (Cont.) (Cont.) breathing apparatus and full protective equipment. Fight fire from a safe distance and a protected location. Heat may build pressure and rupture closed containers, spreading fire and increasing risk of burns or injuries. Water may be ineffective in firefighting due to low flash point and limited miscibility with water. Flammable/combustible components of this material may be lighter than water and burn while floating on the surface. Use water spray/fog for cooling. Even if material is water soluble, it may not be practical to extinguish fire by water dilution. Notify authorities if liquid enters sewers or other public waters. HAZARDOUS COMBUSTION PRODUCTS carbon dioxide; carbon monoxide; sulfur containing gases ____________________________________________________________________ 6. 6. ACCIDENTAL ACCIDENTAL RELEASE RELEASE MEASURES MEASURES SPILL CLEAN-UP PROCEDURES Shut off ignition sources; smoking, flames or other sources of ignition must not be permitted in the area. Small Spills: Take up with sand or other noncombustible absorbent material and put into properly labeled containers for disposal. Large Spills: Dike ahead of liquid spill area to minimize migration and vapor generation. Ventilate the area. Get professional help from outside contractors, the fire department or your trained spill brigade. HEALTH CONSIDERATIONS AND PROTECTIVE EQUIPMENT Information on the selection and use of personal protective equipment is found in Section 8 of this msds. Personal protective equipment needs must be evaluated based on information provided on this sheet and the special circumstances created by the spill including; material spilled, quantity, the area in which it occurred and the expertise of employees in the area responding to the spill. Never exceed any occupational exposure limits and consider that the evaporation of volatile solvents can lead to the displacement of air creating an environment that can cause asphxyiation. ____________________________________________________________________ 7. 7. HANDLING HANDLING AND AND STORAGE

Storage

HANDLING Avoid contact with material, avoid breathing vapors, use only in a well ventilated area, use bonding and grounding when transferring this material. Store in a cool dry ventilated location, away from sources of ignition or other incompatible conditions. Keep container(s) closed if possible. ____________________________________________________________________ 8. 8. EXPOSURE EXPOSURE CONTROLS CONTROLS AND AND PERSONAL PERSONAL PROTECTION PROTECTION ENGINEERING CONTROLS Local exhaust ventilation or other engineering controls are normally required when handling or using this product to keep exposure to airborne contaminants below the TLV, PEL, or other recommended exposure limit and/or maintain operator comfort. These controls should be explosion-proof when exhausting Page 8. 8. EXPOSURE EXPOSURE CONTROLS CONTROLS AND AND PERSONAL PERSONAL PROTECTION PROTECTION (Cont.) (Cont.) flammable vapors. RESPIRATORY PROTECTION If air monitoring indicates airborne concentrations at or above the limits, or symptoms of inhalation over-exposure occur, a respiratory protection program may be required. Engineering controls to reduce the exposure below acceptable limits are usually preferable to a respirator program. EYE PROTECTION Chemical splash goggles and a face shield must be worn when handling this product. Contact lenses should not be worn. An eye wash station should be available. SKIN PROTECTION Prevent skin contact by wearing gloves and other protective equipment. Inspect gloves for chemical break-through and replace if detected. Clean protective equipment thoroughly after each use. Do not remove from workplace. an emergency shower in the area is recommended. Appropriate gloves to be used for MARKEM products that are mixtures have not been determined. Glove type(s) for ingredients present at 10% or more (if known) are: Nitrile ____________________________________________________________________ 9. 9. PHYSICAL PHYSICAL AND AND CHEMICAL CHEMICAL PROPERTIES PROPERTIES - - PRODUCT PRODUCT MIXTURE MIXTURE APPEARANCE: Liquid COLOR: Black ODOR: Characteristic SPECIFIC GRAVITY(g/ml): 1.03 PERCENT VOLATILE: 13 VOC CONTENT: Not Determined VAPOR PRESSURE(mmHg): <0.01 BOILING PT OR RANGE: ND pH: ND VISCOSITY: ND VAPOR DENSITY: Heavier than air FREEZING POINT: ND EVAPORATION RATE: 0.01-0.1 (n-Butyl acetate = 1) ____________________________________________________________________ 9.1 9.1 EXPOSURE, EXPOSURE, PHYSICAL PHYSICAL AND AND CHEMICAL CHEMICAL PROPERTIES PROPERTIES FOR FOR INGREDIENTS INGREDIENTS COMPONENT ACGIH OSHA TWA\CEIL STEL TWA CEIL 56-35-9 0.1 skin NE 1333-86-4 3.5 mg/m3 NE 3.5 mg/m3 NE 61789-51-3 0.1 mg/m3 NE NE 27253-31-2 0.1 mg/m3 NE NE 124-17-4 NE 96-29-7 NE 8052-41-3 100 ppm NE 100 ppm NE Page EXPOSURE, EXPOSURE, PHYSICAL PHYSICAL AND AND CHEMICAL CHEMICAL PROPERTIES PROPERTIES FOR FOR INGREDIENTS INGREDIENTS (Cont.) (Cont.) SPECIFIC EVAP RATE WATER VAPOR GRAVITY N-BUTYL SOLUBILITY PRESSURE COMPONENT CAS NUMBER ACETATE=1 % mmHg 56-35-9 1.170 ND No data ND 1333-86-4 1.800 ND Insoluble ND 61789-51-3 0.900 ND 0 ND 27253-31-2 1.000 ND No data ND 124-17-4 0.981 0.01 6.5% .04 mmHg @ 20°C 96-29-7 0.920 ND No data 2 mm Hg 8052-41-3 0.758 ND No data 1.1 mmHg @ 20°C ____________________________________________________________________ 10. 10. STABILITY STABILITY AND AND REACTIVITY REACTIVITY STABILITY Stable under normal conditions. CONDITIONS TO AVOID Heat, sparks, open flame, other ignition sources, oxidizing conditions, and elevated temperatures. INCOMPATIBILITY strong oxidizing agents; acids; caustics (bases) HAZARDOUS DECOMPOSITION PRODUCTS carbon dioxide; carbon monoxide; sulfur containing gases ____________________________________________________________________ 11. 11. TOXICOLOGICAL TOXICOLOGICAL INFORMATION INFORMATION Bis (Tributyltin) Oxide: Eye rabbit 50 ug/24H, Effect Severe Oral LD50 rat: 194 mg/kg (1983) / 122 mg/kg (1981-82) Carbon black: NTP: Not classified OSHA: Not classified ACGIH: Not classifiable as a human carcinogen (A4) IARC: Carbon black is possibly carcinogenic to humans (Group 2B) Evaluation: There is inadequate evidence in humans for the carcinogenicity of carbon black. There is sufficient evidence in experimental animals for the carcinogenicity of carbon black. There is sufficient evidence in experimental animals for the carcinogenicity of carbon black extracts. Overall evaluation: Carbon black is possibly carcinogenic to humans (Group 2B) [IARC. Monographs on the Evaluation of the Carcinogenic Risk of Chemicals to Man. Geneva: World Health Organization, International Agency for Research on Cancer,1972-PRESENT. (Multivolume work).,p. 65 247 (1996)]. LC50 (inhalation, rat): 27000 mg/m3 (27 mg/L) (1-hour exposure). CHRONIC INHALATION: Hamsters, mice, guinea pigs, rabbits and monkeys exposed to carbon blacks (channel black or furnace black) at concentrations of Page 11. 11. TOXICOLOGICAL TOXICOLOGICAL INFORMATION INFORMATION (Cont.) (Cont.) 85 mg/m3 (channel black) and 56 mg/m3 (furnace black) intermittently for periods up to 3000 hours (13,000 hours for monkeys) showed no significant effects other than accumulation of dusts in the lungs. The channel black contained extremely low levels of benzene-extractable material and the furnace black contained 0.28% extractable material. Methyl ethyl ketoxime: Oral LD50 rat: 930 mg/kg Odorless mineral spirits: LC50 (rat): greater than 5500 mg/m3 (880 ppm) (whole body exposure for 4 hours). LC50 (rat): greater than 8200 mg/m3 (1300 ppm). LD50 (oral, rat): greater than 5 g/kg. LD50 (dermal, rabbit): greater than 3 g/kg. ____________________________________________________________________ 12. 12. ECOLOGICAL ECOLOGICAL INFORMATION INFORMATION bis-(Tributyltin) oxide: LC50 Pimephales promelas (fathead minnow) 2.7 ug/l/96 hr. If released to soil, it will be expected to strongly bind to soil; therefore, it should not leach through soil. If released to water, it will be expected to mainly exist as tributyltin cation. Tributyltin cation will be expected to strongly bind to soil and sediment and to strongly bioconcentrate in various aquatic organisms. ____________________________________________________________________ 13. 13. DISPOSAL DISPOSAL CONSIDERATIONS CONSIDERATIONS Dispose of by incineration or waste water treatment following Federal, State, Local or Provincial regulations. ____________________________________________________________________ 14. 14. TRANSPORT TRANSPORT INFORMATION, INFORMATION, DOT DOT and and IATA: IATA: DOT & IATA: NOT RESTRICTED ____________________________________________________________________ 15. 15. REGULATORY REGULATORY INFORMATION INFORMATION Those ingredients appearing on the following list that do not appear in Section 2 are present at <0.1% for carcinogens, <1% for other hazardous substances, or are not considered hazardous in this product. UNITED STATES OF AMERICA FEDERAL REGULATIONS CERCLA: The following components have CERCLA reportable quantities: CASRN DESCRIPTION None RCRA: The following components are subject to RCRA land disposal restrictions: CASRN DESCRIPTION None SARA TITLE III Page 15. 15. REGULATORY REGULATORY INFORMATION INFORMATION (Cont.) (Cont.) SECTION 302 Extremely Hazardous Substances (EHS) CASRN DESCRIPTION None SECTION 311/312 Community Right to Know CASRN DESCRIPTION 56-35-9 BIS(TRIBUTYLTIN)OXIDE SARA HAZARD CATEGORY INFORMATION FIRE: NO SUDDEN RELEASE OF PRESSURE: NO REACTIVE: NO IMMEDIATE (ACUTE) HEALTH HAZARD: YES DELAYED (CHRONIC) HEALTH HAZARD: NO SECTION 313 Toxic Chemical Release Inventory Reporting (TRI) CASRN DESCRIPTION 56-35-9 BIS(TRIBUTYLTIN)OXIDE 1 TSCA SECTION 8(b) Inventory: All chemicals in this product appear in the inventory or are exempt from the listing requirements. SECTION 12(b) Export: The following chemicals are subject to export reporting CASRN DESCRIPTION 124-17-4 2-(2-BUTOXYETHOXY)ETHYL ACETATE 96-29-7 METHYL ETHYL KETOXIME STATE REGULATIONS CALIFORNIA SAFE DRINKING WATER AND TOXIC ENFORCEMENT ACT (PROPOSITION 65) The following chemical(s) in this product are known to the State of California to cause cancer: CASRN DESCRIPTION None The following chemical(s) in this product are known to the State of California to be hazards to reproductive health: CASRN DESCRIPTION None MASSACHUSETTS Right to Know Law CASRN DESCRIPTION % 56-35-9 BIS(TRIBUTYLTIN)OXIDE 0.5-1.5 1333-86-4 CARBON BLACK 7-13 111-77-3 DIETHYLENE GLYCOL METHYL ETHER 0.01-0.1 8052-41-3 STODDARD SOLVENT 1-5 NEW JERSEY Right to Know Law CASRN DESCRIPTION % 1333-86-4 CARBON BLACK 7-13 61789-51-3 COBALT NAPHTHENATE 0.5-1.5 8052-41-3 STODDARD SOLVENT 1-5 PENNSYLVANIA Right to Know Law CASRN DESCRIPTION % 1333-86-4 CARBON BLACK 7-13 111-77-3 ETHANOL, 2-(2-METHOXYETHOXY)- 0.01-0.1 8052-41-3 STODDARD SOLVENT 1-5 CANADA WHMIS: The following components are WHMIS Workplace Hazardous Materials: CASRN DESCRIPTION % Page 15. 15. REGULATORY REGULATORY INFORMATION INFORMATION (Cont.) (Cont.) 56-35-9 BIS(TRIBUTYLTIN)OXIDE 0.5-1.5 1333-86-4 CARBON BLACK 7-13 8052-41-3 STODDARD SOLVENT 1-5 KOREA All chemicals appear on the Korean Existing and Evaluated Chemicals Inventory unless otherwise listed. Chemicals appearing on the Korean Harmful Substances List: None Chemicals appearing on the Korean Observational Chemicals List: None Chemicals appearing on the Korean Industrial Safety and Health List: None ____________________________________________________________________ 16. 16. OTHER