4440 BLACK

SECTION 2: Hazards identification

OSHA IDENTIFICATION EMERGENCY OVERVIEW

HMIS® ratings

SYSTEM

NFPA Ratings

SYSTEM Health: 3 Health: 3 Flammability: 3 Reactivity: 0 Protection: B POTENTIAL HEALTH CONSIDERATIONS LIKELY ROUTES OF ENTRY: Contact; Inhalation; Absorption; Ingestion Page 3. 3. HAZARDS IDENTIFICATION (Cont.) (Cont.) TARGET ORGANS: Eyes; Skin; Kidneys; Lungs; Blood; Respiratory Tract; Nervous System; Digestive Tract; POTENTIAL IMMEDIATE EFFECTS FROM OVEREXPOSURE EYE CONTACT Can cause severe eye irritation, tearing and reddening, but not likely to permanently injure eye tissue. Temporary vision impairment (cloudy or blurred vision) is possible. Can cause mechanical irritation if dusts are generated. SKIN CONTACT Can cause severe skin irritation, defatting, and dermatitis. Not likely to cause permanent damage. Contact with product at elevated temperatures may result in thermal burns. SKIN ABSORBTION Toxic if absorbed through the skin causing systemic damage. INHALATION Toxic by inhalation, can cause severe irritation or burns, pulmonary edema or lung inflamation. Central nervous system effects such as dizziness, weakness, fatigue, nausea, headache, unconsciousness and even asphyxiation are possible. Vapors and/or aerosols which may be formed at elevated temperatures may be irritating to eyes and respiratory tract. High concentrations in immediate area can displace oxygen and can cause dizziness, unconsciousness and even death with longer exposure. INGESTION Toxic. If swallowed, may cause abdominal discomfort, nausea, vomiting, diarrhea and systemic poisoning. Aspiration of material into the lungs can cause chemical pneumonitis which can be fatal. POTENTIAL LONG-TERM EFFECTS FROM OVEREXPOSURE:

Cancer information

None of the substances in this product have been shown to cause cancer. Not a carcinogen according to NTP, IARC or OSHA. REPRODUCTIVE SYSTEM INFORMATION Contains a substance that is a possible reproductive hazard based on tests with laboratory animals. ADDITIONAL HEALTH HAZARD INFORMATION Paraffin Wax: This product contains paraffin wax. If heated to decomposition (>390F) fumes generated may result in respiratory irritation. ACGIH exposure limit for Paraffin Wax fume is a TLV-TWA of 2 mg/m3. Octylphenoxypolyethoxyethanol: Rabbit studies indicate that contact with undiluted material may result in lung inflamation. Developmental effects Page 3. 3. HAZARDS IDENTIFICATION (Cont.) (Cont.) including extra ribs and other skeletal variations were observed in the fetuses of rats treated with high levels of this material both in diet or by skin contact. Human studies did not show any association of congenital effects in children and maternal exposure to octoxynol-containing spermicide. 1-Methyl-2-pyrrolidinone: Skin absorption may contribute to exposure. MEDICAL CONDITIONS POTENTIALLY AGGRAVATED BY OVEREXPOSURE Kidney disease, Respiratory disease including asthma and bronchitis, Skin disease including eczema and sensitization, Liver disease, Eye disease, No information found. ____________________________________________________________________ 4. 4. FIRST FIRST AID AID MEASURES MEASURES EYE CONTACT Immediately flush eyes with plenty of water for at least 20 minutes retracting eyelids often. Get immediate medical attention. SKIN CONTACT Wash skin with soap and water. Remove contaminated clothing and launder. Get medical attention if irritation develops or persists. For hot material, immediately immerse in or flush the affected area with large amounts of cold water. Get prompt medical attention. Mineral oil may be used to soften material. INHALATION Remove to fresh air. If not breathing, perform rescue breathing and, if available, have a trained person administer oxygen. Get medical attention immediately. INGESTION Emergency personnel should be contacted immediately and be provided with this MSDS. For ingestion of small quantities of chemicals, the risk associated with inducing vomiting usually exceeds the poisoning risk. Get medical attention immediately. Contact a poison information service. Do not induce vomiting. Never give anything by mouth to an unconscious person. ____________________________________________________________________ 5. 5. FIRE FIRE FIGHTING FIGHTING MEASURES MEASURES FLAMMABILITY DATA FLASH POINT: 53 F, 11 C EXPLOSIVE/FLAMMABILITY LIMITS ESTIMATED FROM INGREDIENTS: LOWER LIMIT: 0.8 % UPPER LIMIT: 12.0 % AUTOIGNITION TEMPERATURE ESTIMATED FROM INGREDIENTS: 338 F, 201 C GENERAL HAZARDS Vapors may be ignited by heat, sparks, flames or other sources of ignition giving rise to a Class B fire. Vapors are heavier than air and may travel to a source of ignition and flash back. Container may explode in heat of fire. Empty container may still contain residual material that can ignite and/or result in an explosion. Do not pressurize, cut, weld, braze, solder, drill, Page 5. 5. FIRE FIRE FIGHTING FIGHTING MEASURES MEASURES (Cont.) (Cont.) grind, or expose empty container to heat, flame, sparks, static electricity, or other sources of ignition. EXTINGUISHING MEDIA Small Fires: Dry chemical, CO2, water spray or alcohol-resistant foam. Large Fires: Water spray, fog or alcohol-resistant foam. Move containers from fire area if it can be done without risk. Apply cooling water to containers that are exposed to flames until well after fire is out. FIRE FIGHTING INSTRUCTIONS Do not enter fire area without proper protection including self-contained breathing apparatus and full protective equipment. Fight fire from a safe distance and a protected location. Heat may build pressure and rupture closed containers, spreading fire and increasing risk of burns or injuries. Water may be ineffective in firefighting due to low flash point and limited miscibility with water. Flammable/combustible components of this material may be lighter than water and burn while floating on the surface. Use water spray/fog for cooling. Even if material is water soluble, it may not be practical to extinguish fire by water dilution. Notify authorities if liquid enters sewers or other public waters. HAZARDOUS COMBUSTION PRODUCTS carbon dioxide; carbon monoxide; sulfur containing gases; nitrogen containing gases; hydrogen cyanide; other toxic gases ____________________________________________________________________ 6. 6. ACCIDENTAL ACCIDENTAL RELEASE RELEASE MEASURES MEASURES SPILL CLEAN-UP PROCEDURES Shut off ignition sources; smoking, flames or other sources of ignition must not be permitted in the area. Small Spills: Take up with sand or other noncombustible absorbent material and put into properly labeled containers for disposal. Large Spills: Dike ahead of liquid spill area to minimize migration and vapor generation. Ventilate the area. Get professional help from outside contractors, the fire department or your trained spill brigade. HEALTH CONSIDERATIONS AND PROTECTIVE EQUIPMENT Information on the selection and use of personal protective equipment is found in Section 8 of this msds. Personal protective equipment needs must be evaluated based on information provided on this sheet and the special circumstances created by the spill including; material spilled, quantity, the area in which it occurred and the expertise of employees in the area responding to the spill. Never exceed any occupational exposure limits and consider that the evaporation of volatile solvents can lead to the displacement of air creating an environment that can cause asphxyiation. Page 7. 7. HANDLING HANDLING AND AND STORAGE

Storage

HANDLING Avoid contact with material, avoid breathing vapors, use only in a well ventilated area, use bonding and grounding when transferring this material. Store in a cool dry ventilated location, away from oxidizers, heat, flame or other incompatible conditions. Keep container(s) closed if possible. Do not let nitrocellulose become dry. Keep moist with liquid at all times. Store in a cool, dry, well ventilated area away from ignition sources. ____________________________________________________________________ 8. 8. EXPOSURE EXPOSURE CONTROLS CONTROLS AND AND PERSONAL PERSONAL PROTECTION PROTECTION ENGINEERING CONTROLS Local exhaust ventilation or other engineering controls are normally required when handling or using this product to keep exposure to airborne contaminants below the TLV, PEL, or other recommended exposure limit and/or maintain operator comfort. These controls should be explosion-proof when exhausting flammable vapors. Facilities storing or using this material should be equipped with an eyewash and safety shower. RESPIRATORY PROTECTION If air monitoring indicates airborne concentrations at or above the limits, or symptoms of inhalation over-exposure occur, a respiratory protection program may be required. Engineering controls to reduce the exposure below acceptable limits are usually preferable to a respirator program. Use of a respirator may be required when using this product at elevated temperatures and engineering controls are not adequate to avoid overexposure. A respiratory protection program that meets OSHAs 29 CFR 1910.134 and ANSI Z88.2 requirements must be followed whenever workplace conditions warrant the use of a respirator. EYE PROTECTION Chemical splash goggles and a face shield must be worn when handling this product. Contact lenses should not be worn. An eye wash station should be available. SKIN PROTECTION Prevent skin contact by wearing gloves and other protective equipment. Inspect gloves for chemical break-through and replace if detected. Clean protective equipment thoroughly after each use. Do not remove from workplace. an emergency shower in the area is recommended. Appropriate gloves to be used for MARKEM products that are mixtures have not been determined. Glove type(s) for ingredients present at 10% or more (if known) are: Neoprene; Natural rubber; Nitrile Page 9. 9. PHYSICAL PHYSICAL AND AND CHEMICAL CHEMICAL PROPERTIES PROPERTIES - - PRODUCT PRODUCT MIXTURE MIXTURE APPEARANCE: Liquid COLOR: Black ODOR: Mild solvent odor SPECIFIC GRAVITY(g/ml): 1.21 PERCENT VOLATILE: 30 VOC CONTENT: Not Determined VAPOR PRESSURE(mmHg): <0.01 BOILING PT OR RANGE: ND pH: ND VISCOSITY: ND VAPOR DENSITY: Heavier than air FREEZING POINT: ND EVAPORATION RATE: 0.5-2 (n-Butyl acetate = 1) ____________________________________________________________________ 9.1 9.1 EXPOSURE, EXPOSURE, PHYSICAL PHYSICAL AND AND CHEMICAL CHEMICAL PROPERTIES PROPERTIES FOR FOR INGREDIENTS INGREDIENTS COMPONENT ACGIH OSHA TWA\CEIL STEL TWA CEIL 1333-86-4 3.5 mg/m3 NE 3.5 mg/m3 NE 124-17-4 NE 67-63-0 400 ppm 500 ppm 400 ppm NE 71-36-3 50 ppm C sk NE 100 ppm NE 9004-70-0 NE 9036-19-5 NE 8002-74-2 2 mg/m3 NE fume 872-50-4 19 (MAK) NE NE SPECIFIC EVAP RATE WATER VAPOR GRAVITY N-BUTYL SOLUBILITY PRESSURE COMPONENT CAS NUMBER ACETATE=1 % mmHg 1333-86-4 1.800 ND Insoluble ND 124-17-4 0.981 0.01 6.5% .04 mmHg @ 20°C 67-63-0 0.783 1.44 100 33 71-36-3 0.808 .46 7.7% 4.4 mmHg 9004-70-0 1.660 ND No data ND 9036-19-5 1.067 ND No data ND 8002-74-2 0.900 ND No data ND 872-50-4 1.028 .03 100 0.29 ____________________________________________________________________ 10. 10. STABILITY STABILITY AND AND REACTIVITY REACTIVITY STABILITY Stable under normal conditions. CONDITIONS TO AVOID Heat, sparks, open flame, other ignition sources, oxidizing conditions, and elevated temperatures. Page 10. 10. STABILITY STABILITY AND AND REACTIVITY REACTIVITY (Cont.) (Cont.) INCOMPATIBILITY strong oxidizing agents; caustics (bases); acids; chlorine; ethylene oxide; isocyanates; acetaldehyde HAZARDOUS DECOMPOSITION PRODUCTS carbon dioxide; carbon monoxide; sulfur containing gases; nitrogen containing gases; hydrogen cyanide; other toxic gases ____________________________________________________________________ 11. 11. TOXICOLOGICAL TOXICOLOGICAL INFORMATION INFORMATION Carbon black: NTP: Not classified OSHA: Not classified ACGIH: Not classifiable as a human carcinogen (A4) IARC: Carbon black is possibly carcinogenic to humans (Group 2B) Evaluation: There is inadequate evidence in humans for the carcinogenicity of carbon black. There is sufficient evidence in experimental animals for the carcinogenicity of carbon black. There is sufficient evidence in experimental animals for the carcinogenicity of carbon black extracts. Overall evaluation: Carbon black is possibly carcinogenic to humans (Group 2B) [IARC. Monographs on the Evaluation of the Carcinogenic Risk of Chemicals to Man. Geneva: World Health Organization, International Agency for Research on Cancer,1972-PRESENT. (Multivolume work).,p. 65 247 (1996)]. LC50 (inhalation, rat): 27000 mg/m3 (27 mg/L) (1-hour exposure). CHRONIC INHALATION: Hamsters, mice, guinea pigs, rabbits and monkeys exposed to carbon blacks (channel black or furnace black) at concentrations of 85 mg/m3 (channel black) and 56 mg/m3 (furnace black) intermittently for periods up to 3000 hours (13,000 hours for monkeys) showed no significant effects other than accumulation of dusts in the lungs. The channel black contained extremely low levels of benzene-extractable material and the furnace black contained 0.28% extractable material. Diethylene glycol monobutyl ether acetate: Oral LD50 rat: 6500 mg/kg Isopropyl alcohol: LD50 (rat, oral): 4.42 - 5.84 g/kg LD50 (mouse, oral): 4.8 g/kg LD50 (rabbit, oral): 7.9 g/kg LD50 (rabbit, dermal): 13 g/kg n-Butyl alcohol: LC50 (rat): Greater than 8000 ppm (4-hr exposure). LD50 (oral, rat): 800-4400 mg/kg. LD50 (oral, rabbit): 1600-3500 mg/kg. LD50 (dermal, rabbit): 4200-5300 mg/kg. Octylphenoxypolyethoxyethanol: Oral LD50 rat: 4190 mg/kg Eye rabbit 1%, Effect Severe Paraffin wax: TDlo imp (rat) 120 mg/kg ETA 1-Methyl-2-pyrrolidinone: Page 11. 11. TOXICOLOGICAL TOXICOLOGICAL INFORMATION INFORMATION (Cont.) (Cont.) LD50 (oral, rat): 3914 mg/kg LD50 (oral, mouse): 5320 mg/kg LD50 (oral, rabbit): 3500 mg/kg LD50 (oral, guinea pig): 4400 mg/kg LD50 (skin, rabbit): 8000 mg/kg ____________________________________________________________________ 12. 12. ECOLOGICAL ECOLOGICAL INFORMATION INFORMATION Isopropyl alcohol: LC50 Pimephales promelas (fathead minnows) 11,830 mg/l/1 hr, 11,160 mg/l/24 hr 11,130 mg/l/48 hr, 72 hr, 96 hr, When released into water, isopropyl alcohol will volatilize and biodegrade. In the atmosphere it will photodegrade primarily by reaction with hydroxyl radicals with a half-life of one to several days. N-butyl alcohol: LC50 Pimephales promelas (fathead minnow) 1730 mg/l/96 hr. Release of n-butanol to soil will result in volatilization from the soil surface and biodegradation. n-Butanol should not bind strongly to soil and so is expected to leach into groundwater. Release of n-butanol to water is expected to result in biodegradation and in volatilization from the water surface. Vapor phase n-butanol in the atmosphere is expected to react with photochemically generated hydroxyl radicals with a half-life of 1.2 (experimental)-2.3 (estimated) days. 1-Methyl-2-pyrrolidinone(NMP) If released to soil, NMP has the potential to biodegrade under aerobic conditions. It is expected to display high mobility in soil. If released to water, it will biodegrade under aerobic conditions and is not expected to significantly bioconcentrate in fish. NMP will not volatilize from water to air. If released to the atmosphere, 1-methyl-2-pyrrolidinone is expected to undergo a gas-phase reaction with photochemically produced hydroxyl radicals with an estimated half-life of 5.2 hrs. ____________________________________________________________________ 13. 13. DISPOSAL DISPOSAL CONSIDERATIONS CONSIDERATIONS Dispose of by incineration or waste water treatment following Federal, State, Local or Provincial regulations. ____________________________________________________________________ 14. 14. TRANSPORT TRANSPORT INFORMATION, INFORMATION, DOT DOT and and IATA: IATA: DOT: PRINTING INK, 3, UN1210, PG II IATA: PRINTING INK RELATED MATERIAL, 3, UN1210, PG II LABEL REQUIRED: FLAMMABLE LIQUID Page 15. 15. REGULATORY REGULATORY INFORMATION INFORMATION Those ingredients appearing on the following list that do not appear in Section 2 are present at <0.1% for carcinogens, <1% for other hazardous substances, or are not considered hazardous in this product. UNITED STATES OF AMERICA FEDERAL REGULATIONS CERCLA: The following components have CERCLA reportable quantities: CASRN DESCRIPTION 7440-50-8 COPPER final RQ = 5000 pounds (2270 kg) (no reporting of releases of this hazardous substance is required if the diameter of the pieces of the solid metal released is equal to or exceeds 0.004 inches) 100-41-4 ETHYL BENZENE final RQ = 1000 pounds (454 kg) 75-21-8 ETHYLENE OXIDE final RQ = 10 pounds (4.54 kg) 78-83-1 ISOBUTYL ALCOHOL final RQ = 5000 pounds (2270 kg) 123-86-4 BUTYL ACETATE final RQ = 5000 pounds (2270 kg) 71-36-3 N-BUTYL ALCOHOL final RQ = 5000 pounds (2270 kg) 1330-20-7 BENZENE, DIMETHYL- final RQ = 100 pounds (45.4 kg) 123-91-1 1,4-DIOXANE final RQ = 100 pounds (45.4 kg) RCRA: The following components are subject to RCRA land disposal restrictions: CASRN DESCRIPTION 100-41-4 ETHYL BENZENE 75-21-8 ETHYLENE OXIDE 78-83-1 ISOBUTYL ALCOHOL 71-36-3 N-BUTYL ALCOHOL 1330-20-7 XYLENES (O-, M-, P- ISOMERS) 123-91-1 1,4-DIOXANE SARA TITLE III SECTION 302 Extremely Hazardous Substances (EHS) CASRN DESCRIPTION 75-21-8 ETHYLENE OXIDE SECTION 311/312 Community Right to Know CASRN DESCRIPTION 7440-50-8 COPPER 100-41-4 ETHYL BENZENE 75-21-8 ETHYLENE OXIDE 67-63-0 ISOPROPYL ALCOHOL 7439-96-5 MANGANESE 71-36-3 N-BUTYL ALCOHOL 1330-20-7 XYLENE (MIXED ISOMERS) 872-50-4 N-METHYL-2-PYRROLIDINONE 123-91-1 1,4-DIOXANE SARA HAZARD CATEGORY INFORMATION FIRE: YES SUDDEN RELEASE OF PRESSURE: NO REACTIVE: NO IMMEDIATE (ACUTE) HEALTH HAZARD: YES DELAYED (CHRONIC) HEALTH HAZARD: YES SECTION 313 Toxic Chemical Release Inventory Reporting (TRI) CASRN DESCRIPTION 7440-50-8 COPPER 1 Page 15. 15. REGULATORY REGULATORY INFORMATION INFORMATION (Cont.) (Cont.) 100-41-4 ETHYL BENZENE 0 75-21-8 ETHYLENE OXIDE 0 67-63-0 ISOPROPYL ALCOHOL 3 7439-96-5 MANGANESE 2 71-36-3 N-BUTYL ALCOHOL 11 1330-20-7 XYLENE (MIXED ISOMERS) 1 872-50-4 N-METHYL-2-PYRROLIDINONE 7 123-91-1 1,4-DIOXANE 0 TSCA SECTION 8(b) Inventory: All chemicals in this product appear in the inventory or are exempt from the listing requirements. SECTION 12(b) Export: The following chemicals are subject to export reporting CASRN DESCRIPTION 124-17-4 2-(2-BUTOXYETHOXY)ETHYL ACETATE 78-83-1 ISOBUTYL ALCOHOL 67-63-0 ISOPROPYL ALCOHOL 123-86-4 N-BUTYL ACETATE 71-36-3 N-BUTYL ALCOHOL 872-50-4 1-METHYL-2-PYRROLIDONE STATE REGULATIONS CALIFORNIA SAFE DRINKING WATER AND TOXIC ENFORCEMENT ACT (PROPOSITION 65) The following chemical(s) in this product are known to the State of California to cause cancer: CASRN DESCRIPTION 75-21-8 ETHYLENE OXIDE 123-91-1 1,4-DIOXANE The following chemical(s) in this product are known to the State of California to be hazards to reproductive health: CASRN DESCRIPTION None MASSACHUSETTS Right to Know Law CASRN DESCRIPTION % 1333-86-4 CARBON BLACK 1-5 7440-50-8 COPPER 0.1-1 100-41-4 ETHYL BENZENE 0.1-1 75-21-8 ETHYLENE OXIDE <0.001 78-83-1 ISOBUTYL ALCOHOL 0.1-1 67-63-0 ISOPROPYL ALCOHOL 1-5 7439-96-5 MANGANESE 1-5 123-86-4 BUTYL ACETATE 0.1-1 71-36-3 N-BUTYL ALCOHOL 7-13 9004-70-0 COLLODION 1-5 8002-74-2 PARAFFIN WAX FUME 3-7 1330-20-7 XYLENE 0.1-1 872-50-4 1-METHYL-2-PYRROLIDONE 5-10 123-91-1 1,4-DIOXANE <0.001 NEW JERSEY Right to Know Law CASRN DESCRIPTION % 1333-86-4 CARBON BLACK 1-5 7440-50-8 COPPER 0.1-1 100-41-4 ETHYL BENZENE 0.1-1 75-21-8 ETHYLENE OXIDE <0.001 Page 15. 15. REGULATORY REGULATORY INFORMATION INFORMATION (Cont.) (Cont.) 78-83-1 ISOBUTYL ALCOHOL 0.1-1 67-63-0 ISOPROPYL ALCOHOL 1-5 7439-96-5 MANGANESE 1-5 123-86-4 N-BUTYL ACETATE 0.1-1 71-36-3 N-BUTYL ALCOHOL 7-13 9004-70-0 NITROCELLULOSE 1-5 1330-20-7 XYLENES (O-, M-, P- ISOMERS) 0.1-1 123-91-1 1,4-DIOXANE <0.001 PENNSYLVANIA Right to Know Law CASRN DESCRIPTION % 1333-86-4 CARBON BLACK 1-5 7440-50-8 COPPER 0.1-1 100-41-4 BENZENE, ETHYL- 0.1-1 75-21-8 OXIRANE <0.001 78-83-1 1-PROPANOL, 2-METHYL- 0.1-1 67-63-0 2-PROPANOL 1-5 7439-96-5 MANGANESE 1-5 123-86-4 ACETIC ACID, BUTYL ESTER 0.1-1 71-36-3 1-BUTANOL 7-13 9004-70-0 CELLULOSE, NITRATE 1-5 8002-74-2 PARAFFIN WAXES AND HYDROCARBON WAXES 3-7 1330-20-7 BENZENE, DIMETHYL- 0.1-1 872-50-4 2-PYRROLIDINONE, 1-METHYL- 5-10 123-91-1 1,4-DIOXANE <0.001 CANADA WHMIS: The following components are WHMIS Workplace Hazardous Materials: CASRN DESCRIPTION % 1333-86-4 CARBON BLACK 1-5 7440-50-8 COPPER, ELEMENTAL 0.1-1 100-41-4 ETHYL BENZENE 0.1-1 78-83-1 ISOBUTANOL 0.1-1 67-63-0 ISOPROPANOL 1-5 7439-96-5 MANGANESE, ELEMENTAL 1-5 123-86-4 N-BUTYL ACETATE 0.1-1 71-36-3 N-BUTYL ALCOHOL 7-13 9036-19-5 POLYETHYLENE GLYCOL OCTYLPHENYL ETHER 1-5 KOREA All chemicals appear on the Korean Existing and Evaluated Chemicals Inventory unless otherwise listed. Chemicals appearing on the Korean Harmful Substances List: None Chemicals appearing on the Korean Observational Chemicals List: None Chemicals appearing on the Korean Industrial Safety and Health List: None Page 16. 16. OTHER