215 CLEANER

SECTION 2: Hazards identification

OSHA IDENTIFICATION EMERGENCY OVERVIEW

HMIS® ratings

SYSTEM

NFPA Ratings

SYSTEM Health: 2 Health: 2 Flammability: 3 Reactivity: 0 Protection: B POTENTIAL HEALTH CONSIDERATIONS LIKELY ROUTES OF ENTRY: Inhalation; Contact; Absorption; Ingestion TARGET ORGANS: Heart; Lungs; Blood; Respiratory Tract; Liver; Kidneys; Eyes; Skin; Nervous System; POTENTIAL IMMEDIATE EFFECTS FROM OVEREXPOSURE Page 3. 3. HAZARDS IDENTIFICATION (Cont.) (Cont.) EYE CONTACT Can cause minor eye irritation, tearing or reddening. SKIN CONTACT Can cause minor skin irritation, defatting or dermatitis. SKIN ABSORBTION Toxic if absorbed through the skin causing systemic damage. Can be absorbed through the skin which can lead to permanent vision changes, loss of vision or total blindness. INHALATION Can cause respiratory irritation, dizziness, weakness, fatigue, nausea, headache and possible unconsciousness. INGESTION Irritating to mouth, throat, and stomach. Can cause abdominal discomfort, nausea, vomiting and diarrhea. Upon ingestion of a large quantity of this material, visual disturbances may occur. Onset of the response may be delayed. POTENTIAL LONG-TERM EFFECTS FROM OVEREXPOSURE:

Cancer information

None of the substances in this product have been shown to cause cancer. Not a carcinogen according to NTP, IARC or OSHA. No IARC cancer hazard information available. Contains a substance which is cassified by ACGIH as A4: Not classifiable as a human carcinogen. No NTP cancer hazard information available. No OSHA cancer hazard information available. REPRODUCTIVE SYSTEM INFORMATION Contains a substance that is a possible reproductive hazard based on human studies. ADDITIONAL HEALTH HAZARD INFORMATION Ethyl alcohol: Repeated ingestion by pregnant mothers can cause fetal alcohol syndrome, a nervous system disorder. Effects include mental and physical retardation, learning disturbances, motor and language deficiencies, behavioral disorders, and small head size. MEDICAL CONDITIONS POTENTIALLY AGGRAVATED BY OVEREXPOSURE Liver disease, Ethyl alcohol: Repeated exposure to ethyl alcohol may worsen liver injury produced from other causes. Page 4. 4. FIRST FIRST AID AID MEASURES MEASURES EYE CONTACT Immediately flush eyes with plenty of water for at least 20 minutes retracting eyelids often. Get immediate medical attention. SKIN CONTACT Wash with soap and water. Remove contaminated clothing and launder. Get medical attention if irritation develops or persists. INHALATION Remove to fresh air. If not breathing, perform rescue breathing and, if available, have a trained person administer oxygen. Get medical attention immediately. INGESTION Emergency personnel should be contacted immediately and be provided with this MSDS. For ingestion of small quantities of chemicals, the risk associated with inducing vomiting usually exceeds the poisoning risk. ____________________________________________________________________ 5. 5. FIRE FIRE FIGHTING FIGHTING MEASURES MEASURES FLAMMABILITY DATA FLASH POINT: 48 F, 8 C EXPLOSIVE/FLAMMABILITY LIMITS ESTIMATED FROM INGREDIENTS: LOWER LIMIT: 1.2 % UPPER LIMIT: 36.5 % AUTOIGNITION TEMPERATURE ESTIMATED FROM INGREDIENTS: 793 F, 422 C GENERAL HAZARDS Vapors may be ignited by heat, sparks, flames or other sources of ignition giving rise to a Class B fire. Vapors are heavier than air and may travel to a source of ignition and flash back. Container may explode in heat of fire. Empty container may still contain residual material that can ignite and/or result in an explosion. Do not pressurize, cut, weld, braze, solder, drill, grind, or expose empty container to heat, flame, sparks, static electricity, or other sources of ignition. EXTINGUISHING MEDIA Use alcohol foam, carbon dioxide (CO2) or dry chemical. Water may not be effective to extinguish fire. Use water spray to cool fire-exposed containers and to protect personnel. FIRE FIGHTING INSTRUCTIONS Do not enter fire area without proper protection including self-contained breathing apparatus and full protective equipment. Fight fire from a safe distance and a protected location. Heat may build pressure and rupture closed containers, spreading fire and increasing risk of burns or injuries. Use water spray/fog for cooling. Even if material is water soluble, it may not be practical to extinguish fire by water dilution. Notify authorities if liquid enters sewers or other public waters. Page 5. 5. FIRE FIRE FIGHTING FIGHTING MEASURES MEASURES (Cont.) (Cont.) HAZARDOUS COMBUSTION PRODUCTS carbon dioxide; carbon monoxide; formaldehyde ____________________________________________________________________ 6. 6. ACCIDENTAL ACCIDENTAL RELEASE RELEASE MEASURES MEASURES SPILL CLEAN-UP PROCEDURES Shut off ignition sources; smoking, flames or other sources of ignition must not be permitted in the area. Small Spills: Take up with sand or other noncombustible absorbent material and put into properly labeled containers for disposal. Large Spills: Dike ahead of liquid spill area to minimize migration and vapor generation. Ventilate the area. Get professional help from outside contractors, the fire department or your trained spill brigade. HEALTH CONSIDERATIONS AND PROTECTIVE EQUIPMENT Information on the selection and use of personal protective equipment is found in Section 8 of this MSDS. Personal protective equipment needs must be evaluated based on information provided on this sheet and the special circumstances created by the spill including; material spilled, quantity, the area in which it occurred and the expertise of employees in the area responding to the spill. Never exceed any occupational exposure limits and consider that the evaporation of volatile solvents can lead to the displacement of air creating an environment that can cause asphxyiation. ____________________________________________________________________ 7. 7. HANDLING HANDLING AND AND STORAGE

Storage

HANDLING Avoid contact with material, avoid breathing vapors, use only in a well ventilated area, use bonding and grounding when transferring this material. Store in a cool dry ventilated location, away from oxidizers, heat, flame or other incompatible conditions. Keep container(s) closed if possible. ____________________________________________________________________ 8. 8. EXPOSURE EXPOSURE CONTROLS CONTROLS AND AND PERSONAL PERSONAL PROTECTION PROTECTION ENGINEERING CONTROLS Local exhaust ventilation or other engineering controls are normally required when handling or using this product to keep exposure to airborne contaminants below the TLV, PEL, or other recommended exposure limit and/or maintain operator comfort. Facilities storing or using this material should be equipped with an eyewash and safety shower. RESPIRATORY PROTECTION If air monitoring indicates airborne concentrations at or above the limits, or symptoms of inhalation over-exposure occur, a respiratory protection program may be required. Engineering controls to reduce the exposure below acceptable limits are usually preferable to a respirator program. EYE PROTECTION Page 8. 8. EXPOSURE EXPOSURE CONTROLS CONTROLS AND AND PERSONAL PERSONAL PROTECTION PROTECTION (Cont.) (Cont.) Chemical splash goggles and a face shield must be worn when handling this product. Contact lenses should not be worn. An eye wash station should be available. SKIN PROTECTION Depending upon conditions of use, wear protective gloves and other protective equipment. Inspect gloves for chemical break-through and replace as needed. Clean equipment thoroughly after each use. Appropriate gloves to be used for MARKEM products that are mixtures have not been determined. Glove type(s) for ingredients present at 10% or more (if known) are: Neoprene ____________________________________________________________________ 9. 9. PHYSICAL PHYSICAL AND AND CHEMICAL CHEMICAL PROPERTIES PROPERTIES - - PRODUCT PRODUCT APPEARANCE: Liquid COLOR: Colorless to slightly pale ODOR: Mild solvent odor SPECIFIC GRAVITY(g/ml): 0.78 PERCENT VOLATILE: 100 VOC CONTENT(lb/gl): 6.50 VAPOR PRESSURE (Pa): 1329 - 13289 BOILING PT OR RANGE(F): ND pH: NA VISCOSITY: ND VAPOR DENSITY: Heavier than air FREEZING POINT(F): ND EVAPORATION RATE: 2-10 (n-Butyl acetate = 1) ____________________________________________________________________ 9.1 9.1 EXPOSURE, EXPOSURE, PHYSICAL PHYSICAL AND AND CHEMICAL CHEMICAL PROPERTIES PROPERTIES FOR FOR COMPONENTS COMPONENTS COMPONENT ACGIH OSHA TWA\CEIL STEL TWA CEIL 64-17-5 1000 ppm NE 67-56-1 200 ppm s 250 ppm s 200 ppm NE 108-10-1 50 ppm 75 ppm 50 ppm NE SPECIFIC EVAP RATE WATER VAPOR GRAVITY N-BUTYL SOLUBILITY PRESSURE COMPONENT CAS NUMBER ACETATE=1 Weight % mmHg at F 64-17-5 0.786 0.5-2 Complete; 143 @ 68 67-56-1 0.789 2-10 Complete; 192 @ 68 108-10-1 0.799 0.5-2 Minimal; 1-16 @ 68 ____________________________________________________________________ 10. 10. STABILITY STABILITY AND AND REACTIVITY REACTIVITY STABILITY Stable under normal conditions. CONDITIONS TO AVOID Page 10. 10. STABILITY STABILITY AND AND REACTIVITY REACTIVITY (Cont.) (Cont.) Heat, sparks, open flame, other ignition sources, oxidizing conditions, and elevated temperatures. INCOMPATIBILITY strong oxidizing agents; HAZARDOUS DECOMPOSITION PRODUCTS carbon dioxide; carbon monoxide; formaldehyde ____________________________________________________________________ 11. 11. TOXICOLOGICAL TOXICOLOGICAL INFORMATION INFORMATION Ethyl alcohol: Oral LD50 rat: 7060 mg/kg Inhalation LC50 rat: 20000 ppm/10H (4-hour exposure). Methyl alcohol: Oral LD50 rat: 5628 mg/kg. Inhalation LC50 rat: 64000 ppm/4H Oral TDLo man 6422 mg/kg Effect Brain and Coverings (Changes in circulation) Lungs, Thorax or Respiration (Dyspnea), Gastrointestinal (Nausea or vomiting) Sense organs and special senses (Visual field changes) Inhalation TCLo human 86000 mg/m3, Effect Sense organs and special senses (Lacrimation); Lungs, Thorax or Respiration (Cough; Other changes) Methyl isobutyl ketone: LD50 (mouse, oral) 2850 mg/kg LD50 (rat, oral) 1600-3200 mg/kg LD50 (rat, oral) 5700 ml/kg LC50 (rat, inhalation) 2000-4000 ppm/4hrs LD50 (rabbit, dermal) >10 ml/kg ____________________________________________________________________ 12. 12. ECOLOGICAL ECOLOGICAL INFORMATION INFORMATION Ethyl alcohol: LC50 Pimephales promelas (fathead minnows) 15.3 g/l/96 hr. When released to the atmosphere it will photodegrade in hours (polluted urban atmosphere) to an estimated range of 4 to 6 days in less polluted areas. Rain out should be significant. Methyl Alcohol: LC50 Pimephales promelas (fathead minnows) 29.4 g/l/96 hr. If released to the atmosphere, methanol degrades via reaction with photochemically produced hydroxyl radicals with an approximate half-life of 17.8 days. Methyl Isobutyl Ketone, MIBK: LC50 Pimephales promelas (fathead minnow) 505 mg/l 96 hr. If released to soil, MIBK may be removed by direct photolysis on soil surfaces, volatilization, or aerobic biodegradation. This compound is also susceptible to extensive leaching and has been detected in landfill leachate If released to water, the primary removal mechanisms for MIBK are expected to be volatilization (t1/2 15-33 hours) and direct photolysis. In the atmosphere, methyl isobutyl ketone (MIBK) will be subject to direct photolysis (t1/2 15 hours in sunlight) and reaction with hydroxyl radical Page 12. 12. ECOLOGICAL ECOLOGICAL INFORMATION INFORMATION (Cont.) (Cont.) (t1/2, 16-17 hours). In photochemical smog, MIBK may also react with nitrogen oxides. Acetone is a major photooxidation product of MIBK, and in the presence of nitrogen oxides, peroxyacetylnitrate (PAN) and methyl nitrate will also be formed. ____________________________________________________________________ 13. 13. DISPOSAL DISPOSAL CONSIDERATIONS CONSIDERATIONS Dispose of in accordance with all federal, state, local or provincial regulations. ____________________________________________________________________ 14. 14. TRANSPORT TRANSPORT INFORMATION, INFORMATION, DOT DOT and and IATA: IATA: DOT AND IATA: ALCOHOLS, N.O.S. (ETHANOL, METHANOL), ,3,UN1987,PGII LABEL REQUIRED: FLAMMABLE LIQUID ____________________________________________________________________ 15. 15. REGULATORY REGULATORY INFORMATION INFORMATION Those ingredients appearing on the following list that do not appear in Section 2 are present at <0.1% for carcinogens, <1% for other hazardous substances, or are not considered hazardous in this product. UNITED STATES OF AMERICA FEDERAL REGULATIONS CERCLA: The following components have CERCLA reportable quantities: CASRN DESCRIPTION CERCLA RQ WEIGHT% 67-56-1 METHANOL 5000 lb final RQ; 4 2270 kg final RQ 108-10-1 METHYLISOBUTYL KETONE 5000 lb final RQ; 2 2270 kg final RQ RCRA: The following components are subject to RCRA land disposal restrictions: CASRN DESCRIPTION 67-56-1 METHANOL 108-10-1 METHYL ISOBUTYL KETONE SARA TITLE III SECTION 302 Extremely Hazardous Substances (EHS) CASRN DESCRIPTION None SECTION 311/312 Community Right to Know CASRN DESCRIPTION 67-56-1 METHANOL 108-10-1 METHYL ISOBUTYL KETONE SARA HAZARD CATEGORY INFORMATION FIRE: YES SUDDEN RELEASE OF PRESSURE: NO REACTIVE: NO IMMEDIATE (ACUTE) HEALTH HAZARD: YES DELAYED (CHRONIC) HEALTH HAZARD: YES SECTION 313 Toxic Chemical Release Inventory Reporting (TRI) CASRN DESCRIPTION 67-56-1 METHANOL Page 15. 15. REGULATORY REGULATORY INFORMATION INFORMATION (Cont.) (Cont.) 108-10-1 METHYL ISOBUTYL KETONE 2 TSCA SECTION 8(b) Inventory: All chemicals in this product appear in the inventory or are exempt from the listing requirements. SECTION 12(b) Export: The following chemicals are subject to export reporting CASRN DESCRIPTION 108-10-1 METHYL ISOBUTYL KETONE STATE REGULATIONS CALIFORNIA SAFE DRINKING WATER AND TOXIC ENFORCEMENT ACT (PROPOSITION 65) The following chemical(s) in this product are known to the State of California to cause cancer: CASRN DESCRIPTION WGT% None The following chemical(s) in this product are known to the State of California to be hazards to reproductive health: WGT% CASRN DESCRIPTION 80-100 64-17-5 ETHYL ALCOHOL MASSACHUSETTS Right to Know Law CASRN DESCRIPTION % 64-17-5 ETHYL ALCOHOL 80-100 67-56-1 METHANOL 1-5 108-10-1 METHYLISOBUTYL KETONE 1-5 NEW JERSEY Right to Know Law CASRN DESCRIPTION % 64-17-5 ETHYL ALCOHOL 80-100 67-56-1 METHYL ALCOHOL 1-5 108-10-1 METHYL ISOBUTYL KETONE 1-5 PENNSYLVANIA Right to Know Law CASRN DESCRIPTION % 64-17-5 ETHANOL 80-100 67-56-1 METHANOL 1-5 108-10-1 2-PENTANONE, 4-METHYL- 1-5 ____________________________________________________________________ 16.