210 CLEANER

SECTION 2: Hazards identification

OSHA IDENTIFICATION EMERGENCY OVERVIEW

HMIS® ratings

SYSTEM

NFPA Ratings

SYSTEM Health: 2 Health: 2 Flammability: 2 Reactivity: 0 Protection: B POTENTIAL HEALTH CONSIDERATIONS LIKELY ROUTES OF ENTRY: Contact; Inhalation; Absorption TARGET ORGANS: Eyes; Skin; Respiratory Tract; POTENTIAL IMMEDIATE EFFECTS FROM OVEREXPOSURE Page 3. 3. HAZARDS IDENTIFICATION (Cont.) (Cont.) EYE CONTACT Can cause minor eye irritation, tearing or reddening. SKIN CONTACT Can cause minor skin irritation, defatting or dermatitis. SKIN ABSORBTION Toxic if absorbed through the skin causing systemic damage. INHALATION Can cause respiratory irritation, dizziness, weakness, fatigue, nausea, headache and possible unconsciousness. High concentrations in immediate area can displace oxygen and can cause dizziness, unconsciousness and even death with longer exposure. INGESTION Toxic. If swallowed, may cause abdominal discomfort, nausea, vomiting, diarrhea and systemic poisoning. POTENTIAL LONG-TERM EFFECTS FROM OVEREXPOSURE:

Cancer information

None of the substances in this product have been shown to cause cancer. Not a carcinogen according to NTP, IARC or OSHA. No IARC cancer hazard information available. No ACGIH cancer hazard information available. No NTP cancer hazard information available. No OSHA cancer hazard information available. REPRODUCTIVE SYSTEM INFORMATION None of the substances in this product have been shown to cause reproductive system disorders. ADDITIONAL HEALTH HAZARD INFORMATION Propylene glycol methyl ether: Skin absorption may contribute to exposure. 1-Methyl-2-pyrrolidinone: Skin absorption may contribute to exposure. MEDICAL CONDITIONS POTENTIALLY AGGRAVATED BY OVEREXPOSURE ____________________________________________________________________ 4. 4. FIRST FIRST AID AID MEASURES MEASURES EYE CONTACT Immediately flush eyes with plenty of water for at least 20 minutes retracting eyelids often. Get immediate medical attention. SKIN CONTACT Wash skin with soap and water. Get medical attention if irritation develops and persists. INHALATION Remove to fresh air. If not breathing, perform rescue breathing and, if Page 4. 4. FIRST FIRST AID AID MEASURES MEASURES (Cont.) (Cont.) available, have a trained person administer oxygen. Get medical attention immediately. INGESTION Emergency personnel should be contacted immediately and be provided with this MSDS. For ingestion of small quantities of chemicals, the risk associated with inducing vomiting usually exceeds the poisoning risk. ____________________________________________________________________ 5. 5. FIRE FIRE FIGHTING FIGHTING MEASURES MEASURES FLAMMABILITY DATA FLASH POINT: 115 F, 46 C EXPLOSIVE/FLAMMABILITY LIMITS ESTIMATED FROM INGREDIENTS: LOWER LIMIT: 1.3 % UPPER LIMIT: 12.0 % AUTOIGNITION TEMPERATURE ESTIMATED FROM INGREDIENTS: 518 F, ND C GENERAL HAZARDS Material may ignite if heated to temperatures above the flash point in the presence of a source of ignition. EXTINGUISHING MEDIA Use alcohol foam, carbon dioxide, dry chemical powder or water spray to extinguish fire. FIRE FIGHTING INSTRUCTIONS Do not enter fire area without proper protection including self-contained breathing apparatus and full protective equipment. Fight fire from a safe distance and a protected location. Heat may build pressure and rupture closed containers, spreading fire and increasing risk of burns or injuries. Use water spray/fog for cooling. Even if material is water soluble, it may not be practical to extinguish fire by water dilution. Notify authorities if liquid enters sewers or other public waters. HAZARDOUS COMBUSTION PRODUCTS carbon dioxide; carbon monoxide; nitrogen containing gases ____________________________________________________________________ 6. 6. ACCIDENTAL ACCIDENTAL RELEASE RELEASE MEASURES MEASURES SPILL CLEAN-UP PROCEDURES Prevent the spread of any spill to minimize harm to human health and the environment. Dike with suitable absorbent material. Wear complete and proper personal protective equipment and ventilate the area. HEALTH CONSIDERATIONS AND PROTECTIVE EQUIPMENT Information on the selection and use of personal protective equipment is found in Section 8 of this MSDS. Personal protective equipment needs must be evaluated based on information provided on this sheet and the special circumstances created by the spill including; material spilled, quantity, the area in which it occurred and the expertise of employees in the area Page 6. 6. ACCIDENTAL ACCIDENTAL RELEASE RELEASE MEASURES MEASURES (Cont.) (Cont.) responding to the spill. Never exceed any occupational exposure limits and consider that the evaporation of volatile solvents can lead to the displacement of air creating an environment that can cause asphxyiation. ____________________________________________________________________ 7. 7. HANDLING HANDLING AND AND STORAGE

Storage

HANDLING Avoid contact with material, avoid breathing vapors, use only in a well ventilated area, use bonding and grounding when transferring this material. Store in a cool dry ventilated location, away from oxidizers, heat, flame or other incompatible conditions. Keep container(s) closed if possible. ____________________________________________________________________ 8. 8. EXPOSURE EXPOSURE CONTROLS CONTROLS AND AND PERSONAL PERSONAL PROTECTION PROTECTION ENGINEERING CONTROLS Local exhaust ventilation or other engineering controls are normally required when handling or using this product to keep exposure to airborne contaminants below the TLV, PEL, or other recommended exposure limit and/or maintain operator comfort. RESPIRATORY PROTECTION If air monitoring indicates airborne concentrations at or above the limits, or symptoms of inhalation over-exposure occur, a respiratory protection program may be required. Engineering controls to reduce the exposure below acceptable limits are usually preferable to a respirator program. Follow a respiratory protection program that meets OSHA 29 CFR 1910.134 requirements whenever workplace conditions warrant the use of a respirator. EYE PROTECTION Chemically resistant safety glasses with side shields must be worn when handling this product. Further eye protection such as chemical splash goggles and/or face shield must be worn when the possibility exists for eye contact due to splashing or spraying liquid or airborne particles. Contact lenses should not be worn. An eye wash station should be available. SKIN PROTECTION Wear protective gloves and apron. Depending upon conditions of use other equipment may be required. Inspect gloves for chemical break-through and replace as required. Clean equipment after each use. An emergency eye wash in the area is recommended. Appropriate gloves to be used for MARKEM products that are mixtures have not been determined. Glove type(s) for ingredients present at 10% or more (if known) are: Nitrile; Butyl rubber, Neoprene Page 9. 9. PHYSICAL PHYSICAL AND AND CHEMICAL CHEMICAL PROPERTIES PROPERTIES - - PRODUCT PRODUCT APPEARANCE: Liquid COLOR: Colorless to pale amber ODOR: Mild solvent odor SPECIFIC GRAVITY(g/ml): 0.99 PERCENT VOLATILE: 100 VOC CONTENT(lb/gl): 8.25 lb/gal VAPOR PRESSURE (Pa): 13.3 - 133 BOILING PT OR RANGE(F): 204 pH: NA VISCOSITY: ND VAPOR DENSITY: Heavier than air FREEZING POINT(F): ND EVAPORATION RATE: 0.5-2 (n-Butyl acetate = 1) ____________________________________________________________________ 9.1 9.1 EXPOSURE, EXPOSURE, PHYSICAL PHYSICAL AND AND CHEMICAL CHEMICAL PROPERTIES PROPERTIES FOR FOR COMPONENTS COMPONENTS COMPONENT ACGIH OSHA TWA\CEIL STEL TWA CEIL 34590-94-8 100 150 100 NE 107-98-2 100 150 100 NE TS0000-00-7 NE NE 872-50-4 19 (MAK) NE NE SPECIFIC EVAP RATE WATER VAPOR GRAVITY N-BUTYL SOLUBILITY PRESSURE COMPONENT CAS NUMBER ACETATE=1 Weight % mmHg at F 34590-94-8 0.950 <0.01 Complete; 10.4 107-98-2 0.919 0.5-2 ND 10.9 TS0000-00-7 1.000 ND 872-50-4 1.028 0.01-0.1 Complete; 10.29 ____________________________________________________________________ 10. 10. STABILITY STABILITY AND AND REACTIVITY REACTIVITY STABILITY Stable under normal conditions. CONDITIONS TO AVOID Elevated temperatures in combination with sparks, open flames, or other sources of ignition. INCOMPATIBILITY strong oxidizing agents; HAZARDOUS DECOMPOSITION PRODUCTS carbon dioxide; carbon monoxide; nitrogen containing gases Page 11. 11. TOXICOLOGICAL TOXICOLOGICAL INFORMATION INFORMATION Dipropylene glycol methyl ether: Oral LD50 rat: 5135 mg/kg Propylene glycol monomethyl ether: Inhalation human 3000 ppm, Effect Behavioral (General anesthetic); Gastrointestinal (Nausea or vomiting) Oral LD50 rat: 5660 mg/kg Inhalation LCLo rat 7000 ppm/6H, Effect Behavioral (Sleep); Nutritional and gross metabolic (Weight loss or decreased weight gain) Propylene glycol monomethyl ether: Inhalation human 3000 ppm, Effect Behavioral (General anesthetic); Gastrointestinal (Nausea or vomiting) Oral LD50 rat: 5660 mg/kg Inhalation LCLo rat 7000 ppm/6H, Effect Behavioral (Sleep); Nutritional and gross metabolic (Weight loss or decreased weight gain) Oral LD50 mouse: 11700 mg/kg 1-Methyl-2-pyrrolidinone: LD50 (oral, rat): 3914 mg/kg LD50 (oral, mouse): 5320 mg/kg LD50 (oral, rabbit): 3500 mg/kg LD50 (oral, guinea pig): 4400 mg/kg LD50 (skin, rabbit): 8000 mg/kg ____________________________________________________________________ 12. 12. ECOLOGICAL ECOLOGICAL INFORMATION INFORMATION Dipropylene glycol methyl ether: In moist soil, as in aquatic systems, biodegradation will probably be the primary removal mechanism. 1-Methyl-2-pyrrolidinone(NMP) If released to soil, NMP has the potential to biodegrade under aerobic conditions. It is expected to display high mobility in soil. If released to water, it will biodegrade under aerobic conditions and is not expected to significantly bioconcentrate in fish. NMP will not volatilize from water to air. If released to the atmosphere, 1-methyl-2-pyrrolidinone is expected to undergo a gas-phase reaction with photochemically produced hydroxyl radicals with an estimated half-life of 5.2 hrs. ____________________________________________________________________ 13. 13. DISPOSAL DISPOSAL CONSIDERATIONS CONSIDERATIONS Dispose of in accordance with all federal, state, local or provincial regulations. ____________________________________________________________________ 14. 14. TRANSPORT TRANSPORT INFORMATION, INFORMATION, DOT DOT and and IATA: IATA: DOT & IATA: FLAMMABLE LIQUID, N.O.S. (PROPYLENE GLYCOL MONOMETHYL ETHER) 3, UN1993, PGIII LABEL REQUIRED: FLAMMABLE LIQUID Page 15. 15. REGULATORY REGULATORY INFORMATION INFORMATION Those ingredients appearing on the following list that do not appear in Section 2 are present at <0.1% for carcinogens, <1% for other hazardous substances, or are not considered hazardous in this product. UNITED STATES OF AMERICA FEDERAL REGULATIONS CERCLA: The following components have CERCLA reportable quantities: CASRN DESCRIPTION CERCLA RQ WEIGHT% None RCRA: The following components are subject to RCRA land disposal restrictions: CASRN DESCRIPTION None SARA TITLE III SECTION 302 Extremely Hazardous Substances (EHS) CASRN DESCRIPTION None SECTION 311/312 Community Right to Know CASRN DESCRIPTION 872-50-4 N-METHYL-2-PYRROLIDINONE SARA HAZARD CATEGORY INFORMATION FIRE: YES SUDDEN RELEASE OF PRESSURE: NO REACTIVE: NO IMMEDIATE (ACUTE) HEALTH HAZARD: YES DELAYED (CHRONIC) HEALTH HAZARD: YES SECTION 313 Toxic Chemical Release Inventory Reporting (TRI) CASRN DESCRIPTION 872-50-4 N-METHYL-2-PYRROLIDINONE 30 TSCA SECTION 8(b) Inventory: All chemicals in this product appear in the inventory or are exempt from the listing requirements. SECTION 12(b) Export: The following chemicals are subject to export reporting CASRN DESCRIPTION 872-50-4 1-METHYL-2-PYRROLIDONE STATE REGULATIONS CALIFORNIA SAFE DRINKING WATER AND TOXIC ENFORCEMENT ACT (PROPOSITION 65) The following chemical(s) in this product are known to the State of California to cause cancer: CASRN DESCRIPTION WGT% None The following chemical(s) in this product are known to the State of California to be hazards to reproductive health: WGT% CASRN DESCRIPTION 10-30 872-50-4 N-METHYLPYRROLIDONE MASSACHUSETTS Right to Know Law CASRN DESCRIPTION % 34590-94-8 DIPROPYLENE GLYCOL, METHYL ETHER 10-30 107-98-2 PROPYLENE GLYCOL METHYL ETHER 20-40 872-50-4 1-METHYL-2-PYRROLIDONE 10-30 NEW JERSEY Right to Know Law CASRN DESCRIPTION % 34590-94-8 DIPROPYLENE GLYCOL MONOMETHYL ETHER 10-30 107-98-2 PROPYLENE GLYCOL MONOMETHYL ETHER 20-40 Page 15. 15. REGULATORY REGULATORY INFORMATION INFORMATION (Cont.) (Cont.) PENNSYLVANIA Right to Know Law CASRN DESCRIPTION % 34590-94-8 DIPROPYLENE GLYCOL MONOMETHYL ETHER 10-30 107-98-2 PROPYLENE GLYCOL MONOMETHYL ETHER 20-40 872-50-4 1-METHYL-2-PYRROLIDONE 10-30 ____________________________________________________________________ 16. 16. OTHER