SOLBREAK

Marichem Marigases Hellas SA

Revision date : 2014-12-23

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GHS02 GHS05 GHS07 GHS08 GHS09
Health risk rating 4
Safety risk rating 2
Environmental risk rating 4

Note: Ingredients listed on restricted chemical lists

EC/CAS

64742-82-1

Name of the chemical

Naphtha (petroleum), hydrodesulfurized heavy

Concentration

30% - 50%

EC/CAS

64742-95-6

Name of the chemical

Solvent naphtha (petroleum), light arom

Concentration

50% - 70%

General Information

Revision date

2014-12-23

Product name

SOLBREAK

1.2.1 Relevant identified uses

Industrial applications; Cleaning agent for vessel’s bilges, cargo holds and tanks

1.2.2. Uses advised against

This product is not recommended for any industrial, professional or consumer use

Emergency telephone

++30 210 4148800 (including working hours

Icons in SDS

GHS02 GHS07 GHS08 GHS09 M004 M009 M010 M017

Company Information

company name

Marichem Marigases Hellas SA

e-mail address of the competent person responsible for the Safety Data Sheet

mail@marichem-marigases.com

GHS Information

Signal word

Danger

Hazard Codes

Hazard statements (CLP)

H226, H304, H318, H335, H336, H372, H411

Hazard statements

Code

Statements

H226

Flammable liquid and vapour

Section 2

2.1 Classification of the substance or mixture

Classification under EC 1272/2008 regulation - GHS classification. Flammable liquids - Category 3; H226

Aspiration hazard

Category 1; H304 Serious eye damage - Category 1; H318 Specific target organ toxicity - single exposure - Category 3; Narcotic effects. Respiratory tract irritation; H335, H336 Specific target organ toxicity - repeated exposure - Category 1; H372 Hazardous to the aquatic environment; Long-term Hazard - Category 2; H411

Supplemental label elements

EUH066

Signal word

DANGER GHS02 GHS07 GHS08 GHS09

Hazard statements

H226: Flammable liquid and vapour. H304: May be fatal if swallowed and enters airways. H318: Causes serious eye damage. H335: May cause respiratory irritation. H336: May cause drowsiness or dizziness. H372: Causes damage to organs through prolonged or repeated exposure. H411: Toxic to aquatic life with long lasting effects. EUH066: Repeated exposure may cause skin dryness or cracking. H226: Flammable liquid and vapour. H304: May be fatal if swallowed and enters airways. H318: Causes serious eye damage. 2 H335: May cause respiratory irritation. H336: May cause drowsiness or dizziness. H372: Causes damage to organs through prolonged or repeated exposure. H411: Toxic to aquatic life with long lasting effects. EUH066: Repeated exposure may cause skin dryness or cracking.

2.2 Label elements

Labelling according to Regulation (EC) No. 1272/2008. The substance is classified and labelled according to the CLP Regulation.

Hazard pictograms

GHS02 GHS07 GHS08 GHS09 Xn, N Harmful (Xn) Dangerous for the environment (N)

Prevention

P102: Keep out of reach of children. P210: Keep away from heat/sparks/open flames/hot surfaces. - No smoking. P233: Keep container tightly closed. P240: Ground/bond container and receiving equipment. P241: Use explosion-proof electrical/ventilating/lighting/equipment. P242: Use only non-sparking tools. P243: Take precautionary measures against static discharge. P260: Do not breathe fume/mist/vapours/spray. P261: Avoid breathing dust/fume/gas/mist/vapours/spray. P262: Do not get in eyes, on skin, or on clothing. P271: Use only outdoors or in a well-ventilated area. P273: Avoid release to the environment. P280: Wear protective gloves/protective clothing/eye protection/face protection.

Response

P301+P310 IF SWALLOWED Immediately call a POISON CENTER or doctor/physician P303+361+353 IF ON SKIN (or hair) Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower. P304 + P340 IF INHALED Remove victim to fresh air and keep at rest in a position comfortable for breathing. P305 + P351 + P338 IF IN EYES Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P310: Immediately call a POISON CENTER or doctor/physician. P331: Do NOT induce vomiting. P370 + P378 In case of fire Use foam, dry chemicals, CO2 for extinction

Storage

P403 + P233: Store in a well ventilated place. Keep container tightly closed. P403 + P235: Store in a well ventilated place. Keep cool.

Disposal

P501: Dispose of contents and container to appropriate waste site or reclaimer in accordance with local and national regulations.

Health hazards

Repeated exposure may cause skin dryness or cracking. Possibility of organ or organ system damage from prolonged exposure; see Chapter 11 for details. Target organ(s): Auditory system. Safety Hazards: In use, may form flammable/explosive vapour-air mixture. This material is a static accumulator. Even with proper grounding and bonding, this material can still accumulate an electrostatic charge. If sufficient charge is allowed to accumulate, electrostatic discharge and ignition of flammable air- vapour mixtures can occur. 3

Further information

For Industry guidance and tools on REACH please visit the CEFIC website at http://cefic.org/Industry-support. Product classification and labelling according to Directive 67/548/EEC, European Dangerous Preparations Directive (1999/45/EC), European Regulation 648/2004 and their amendments.

R-phrase(s)

R10: Flammable R65: Harmful: may cause lung damage if swallowed R66: Repeated exposure may cause skin dryness or cracking R67: Vapours may cause drowsiness and dizziness R51-53:Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment.

S-phrase(s)

S2: Keep out of the reach of children. S9: Keep container in a well-ventilated place S23: Do not breathe gas/vapour S24: Avoid contact with skin S61: Avoid release to the environment. Refer to special instructions/Material Safety Data Sheets (MSDS). S62: If swallowed, do not induce vomiting: seek medical advice immediately and show this container or label S38: In case of insufficient ventilation, wear suitable respiratory equipment.

SDS Library

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Safety – One-click access to first aid information.
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Labels – Generate Secondary Container Labels with just one click.