Note: Ingredients listed on restricted chemical lists
EC/CAS
64742-82-1
Name of the chemical
Naphtha (petroleum), hydrodesulfurized heavy
Concentration
30% - 50%
EC/CAS
64742-95-6
Name of the chemical
Solvent naphtha (petroleum), light arom
Concentration
50% - 70%
General Information
Revision date
2014-12-23
Product name
SOLBREAK
1.2.1 Relevant identified uses
Industrial applications; Cleaning agent for vessel’s bilges, cargo holds and tanks
1.2.2. Uses advised against
This product is not recommended for any industrial, professional or consumer use
Emergency telephone
++30 210 4148800 (including working hours
Icons in SDS
Company Information
company name
Marichem Marigases Hellas SA
e-mail address of the competent person responsible for the Safety Data Sheet
mail@marichem-marigases.com
GHS Information
Signal word
Danger
Hazard Codes
Hazard statements (CLP)
H226, H304, H318, H335, H336, H372, H411
Hazard statements
Code
Statements
H226
Flammable liquid and vapour
Section 2
2.1 Classification of the substance or mixture
Classification under EC 1272/2008 regulation - GHS classification. Flammable liquids - Category 3; H226
Aspiration hazard
Category 1; H304 Serious eye damage - Category 1; H318 Specific target organ toxicity - single exposure - Category 3; Narcotic effects. Respiratory tract irritation; H335, H336 Specific target organ toxicity - repeated exposure - Category 1; H372 Hazardous to the aquatic environment; Long-term Hazard - Category 2; H411
Supplemental label elements
EUH066
Signal word
DANGER GHS02 GHS07 GHS08 GHS09
Hazard statements
H226: Flammable liquid and vapour. H304: May be fatal if swallowed and enters airways. H318: Causes serious eye damage. H335: May cause respiratory irritation. H336: May cause drowsiness or dizziness. H372: Causes damage to organs through prolonged or repeated exposure. H411: Toxic to aquatic life with long lasting effects. EUH066: Repeated exposure may cause skin dryness or cracking. H226: Flammable liquid and vapour. H304: May be fatal if swallowed and enters airways. H318: Causes serious eye damage. 2 H335: May cause respiratory irritation. H336: May cause drowsiness or dizziness. H372: Causes damage to organs through prolonged or repeated exposure. H411: Toxic to aquatic life with long lasting effects. EUH066: Repeated exposure may cause skin dryness or cracking.
2.2 Label elements
Labelling according to Regulation (EC) No. 1272/2008. The substance is classified and labelled according to the CLP Regulation.
Hazard pictograms
GHS02 GHS07 GHS08 GHS09 Xn, N Harmful (Xn) Dangerous for the environment (N)
Prevention
P102: Keep out of reach of children. P210: Keep away from heat/sparks/open flames/hot surfaces. - No smoking. P233: Keep container tightly closed. P240: Ground/bond container and receiving equipment. P241: Use explosion-proof electrical/ventilating/lighting/equipment. P242: Use only non-sparking tools. P243: Take precautionary measures against static discharge. P260: Do not breathe fume/mist/vapours/spray. P261: Avoid breathing dust/fume/gas/mist/vapours/spray. P262: Do not get in eyes, on skin, or on clothing. P271: Use only outdoors or in a well-ventilated area. P273: Avoid release to the environment. P280: Wear protective gloves/protective clothing/eye protection/face protection.
Response
P301+P310 IF SWALLOWED Immediately call a POISON CENTER or doctor/physician P303+361+353 IF ON SKIN (or hair) Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower. P304 + P340 IF INHALED Remove victim to fresh air and keep at rest in a position comfortable for breathing. P305 + P351 + P338 IF IN EYES Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P310: Immediately call a POISON CENTER or doctor/physician. P331: Do NOT induce vomiting. P370 + P378 In case of fire Use foam, dry chemicals, CO2 for extinction
Storage
P403 + P233: Store in a well ventilated place. Keep container tightly closed. P403 + P235: Store in a well ventilated place. Keep cool.
Disposal
P501: Dispose of contents and container to appropriate waste site or reclaimer in accordance with local and national regulations.
Health hazards
Repeated exposure may cause skin dryness or cracking. Possibility of organ or organ system damage from prolonged exposure; see Chapter 11 for details. Target organ(s): Auditory system. Safety Hazards: In use, may form flammable/explosive vapour-air mixture. This material is a static accumulator. Even with proper grounding and bonding, this material can still accumulate an electrostatic charge. If sufficient charge is allowed to accumulate, electrostatic discharge and ignition of flammable air- vapour mixtures can occur. 3
Further information
For Industry guidance and tools on REACH please visit the CEFIC website at http://cefic.org/Industry-support. Product classification and labelling according to Directive 67/548/EEC, European Dangerous Preparations Directive (1999/45/EC), European Regulation 648/2004 and their amendments.
R-phrase(s)
R10: Flammable R65: Harmful: may cause lung damage if swallowed R66: Repeated exposure may cause skin dryness or cracking R67: Vapours may cause drowsiness and dizziness R51-53:Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment.
S-phrase(s)
S2: Keep out of the reach of children. S9: Keep container in a well-ventilated place S23: Do not breathe gas/vapour S24: Avoid contact with skin S61: Avoid release to the environment. Refer to special instructions/Material Safety Data Sheets (MSDS). S62: If swallowed, do not induce vomiting: seek medical advice immediately and show this container or label S38: In case of insufficient ventilation, wear suitable respiratory equipment.