ULTRABOND ECO VS90 PLUS

MAPEI U.K. Ltd

Revision date : 2022-06-01

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Health risk rating 4
Safety risk rating 1
Environmental risk rating 1

Note: Ingredients listed on restricted chemical lists

EC/CAS

220-120-9/2634-33-5

Name of the chemical

1,2-Benzisothiazol-3(2H)-one

Concentration

≥0.01- <0.016% 00-6

EC/CAS

611-341-5/55965-84-9

Name of the chemical

Mixture of 5-chloro-2-methyl-2H- isothiazol-3-one (EINECS 247-500-7) and 2-methyl-2H-isothiazol-3-one (EINECS 220-239-6)

Concentration

<0.0015 %

EC/CAS

247-500-7

Name of the chemical

Mixture of 5-Chloro-2-methyl-isothiazol-3(2H)-one and 2-methylisothiazol-3(2H)-one

Concentration

00-5 0,06%≤C<0,6 0,06%≤C<0,6

General Information

Revision date

2022-06-01

Product name

ULTRABOND ECO VS90 PLUS

1.2.1 Relevant identified uses

Water-borne synthetic polymer based adhesive

1.2.2. Uses advised against

Data not available

Emergency telephone

+44(0)333 333 9962

Icons in SDS

M010

Company Information

company name

MAPEI U.K. Ltd

e-mail address of the competent person responsible for the Safety Data Sheet

sicurezza@mapei.it

Section 2

SECTION 2: Hazards identification

Regulation EC 1272/2008 (CLP) Classification of the substance or mixture

Adverse physicochemical, human health and environmental effects

No other hazards

Special Provisions

EUH208

Contains

1,2-benzisothiazol-3(2H)-one; 1,2-benzisothiazolin-3-one. May produce an allergic reaction EUH208 Contains reaction mass of: 5-chloro-2-methyl-4-isothiazolin-3-one [EC no. 247-500-7] and 2-methyl-2H - isothiazol-3-one [EC no. 220-239-6] (3:1). May produce an allergic reaction. EUH210 Safety data sheet available on request.

Annex XVII - Restrictions on the manufacture, placing on the market and use of certain dangerous substances, mixtures and articles

None.

2.3 Other hazards

No PBT, vPvB or endocrine disruptor substances present in concentration >= 0.1%. No other hazards This product contains crystalline silica (quartz sand). IARC has classified crystalline silica as a Group 1 carcinogen. Both IARC and NTP consider silica as a known human carcinogen. Evidence is based on the chronic and long-term exposure workers have had to respirable sized crystalline silica dust particles. Because this product is in liquid or paste form, it does not pose a dust hazard; therefore, this classification is not relevant. (Note: sanding of the hardened product may create a silica dust hazard)

2.1 Classification of the substance or mixture

Regulation (EC) n. 1272/2008 (CLP) The product is not classified as dangerous according to Regulation EC 1272/2008 (CLP). Adverse physicochemical, human health and environmental effects: No other hazards 2.2. Label elements The product is not classified as dangerous according to Regulation EC 1272/2008 (CLP). Special Provisions: EUH208 Contains 1,2-benzisothiazol-3(2H)-one; 1,2-benzisothiazolin-3-one. May produce an allergic reaction. EUH208 Contains reaction mass of: 5-chloro-2-methyl-4-isothiazolin-3-one [EC no. 247-500-7] and 2-methyl-2H - isothiazol-3-one [EC no. 220-239-6] (3:1). May produce an allergic reaction. EUH210 Safety data sheet available on request. Special provisions according to Annex XVII of REACH and subsequent amendments: None. 2.3. Other hazards No PBT, vPvB or endocrine disruptor substances present in concentration >= 0.1%. Other Hazards: No other hazards This product contains crystalline silica (quartz sand). IARC has classified crystalline silica as a Group 1 carcinogen. Both IARC and NTP consider silica as a known human carcinogen. Evidence is based on the chronic and long-term exposure workers have had to respirable sized crystalline silica dust particles. Because this product is in liquid or paste form, it does not pose a dust hazard; therefore, this classification is not relevant. (Note: sanding of the hardened product may create a silica dust hazard) SECTION 3: Composition/information on ingredients 3.1. Substances Not Relevant 3.2. Mixtures Mixture identification: ULTRABOND ECO VS90 PLUS Hazardous components within the meaning of the CLP regulation and related classification: Concentra Name Ident. Numb. Classification Registration Number tion (% w/w) Print date 09/06/2022 Production Name ULTRABOND ECO VS90 PLUS Page n. 1 of ≥0.01 - 1,2-benzisothiazol-3(2H)-one; 1,2- CAS:2634-33-5 Skin Irrit. 2, H315 Eye Dam. 1, <0.016 % benzisothiazolin-3-one EC:220-120-9 H318 Aquatic Acute 1, H400 Acute Index:613-088- Tox. 4, H302 Skin Sens. 1, H317 00-6 Aquatic Chronic 2, H411 Specific Concentration Limits: C ≥ 0,05%: Skin Sens. 1 H317 <0.0015 % reaction mass of: 5-chloro-2- CAS:55965-84-9 Aquatic Acute 1, H400 Aquatic methyl-4-isothiazolin-3-one [EC EC:611-341-5 Chronic 1, H410 Acute Tox. 3, no. 247-500-7] and 2-methyl-2H - Index:613-167- H301 Skin Corr. 1C, H314 Skin isothiazol-3-one [EC no. 220-239- 00-5 Sens. 1A, H317 Acute Tox. 2, 6] (3:1) H310 Acute Tox. 2, H330 Eye Dam. 1, H318, M-Chronic:100, M- Acute:100 Specific Concentration Limits: C ≥ 0,6%: Skin Corr. 1C H314 0,06% ≤ C < 0,6%: Skin Irrit. 2 H315 C ≥ 0,6%: Eye Dam. 1 H318 0,06% ≤ C < 0,6%: Eye Irrit. 2 H319 C ≥ 0,0015%: Skin Sens. 1A H317 SECTION 4: First aid measures 4.1. Description of first aid measures In case of skin contact: Wash with plenty of water and soap. In case of eyes contact: Wash immediately with water. In case of Ingestion: Do not induce vomiting, get medical attention showing the SDS and the hazard label. In case of Inhalation: Remove casualty to fresh air and keep warm and at rest. 4.2. Most important symptoms and effects, both acute and delayed Not available 4.3. Indication of any immediate medical attention and special treatment needed Treatment: Not available (see paragraph 4.1) SECTION 5: Firefighting measures 5.1. Extinguishing media Suitable extinguishing media: Water. Carbon dioxide (CO2). Extinguishing media which must not be used for safety reasons: None in particular. 5.2. Special hazards arising from the substance or mixture Do not inhale explosion and combustion gases. 5.3. Advice for firefighters Use suitable breathing apparatus. SECTION 6: Accidental release measures 6.1. Personal precautions, protective equipment and emergency procedures Wear personal protection equipment. Remove persons to safety. 6.2. Environmental precautions Do not allow to enter into soil/subsoil. Do not allow to enter into surface water or drains. Limit leakages with earth or sand. 6.3. Methods and material for containment and cleaning up Suitable material for taking up: absorbing material, organic, sand Retain contaminated washing water and dispose it. 6.4. Reference to other sections Print date 09/06/2022 Production Name ULTRABOND ECO VS90 PLUS Page n. 2 of 6.4. Reference to other sections See also section 8 and 13 SECTION 7: Handling and storage 7.1. Precautions for safe handling Avoid contact with skin and eyes, inhalation of vapours and mists. Do not eat or drink while working. See also section 8 for recommended protective equipment. 7.2. Conditions for safe storage, including any incompatibilities Keep away from food, drink and feed. Incompatible materials: None in particular. Instructions as regards storage premises: Adequately ventilated premises. 7.3. Specific end use(s) Recommendation(s) None in particular Industrial sector specific solutions: None in particular SECTION 8: Exposure controls/personal protection 8.1. Control parameters No data available 8.2. Exposure controls Eye protection: Not needed for normal use. Anyway, operate according good working practices. Protection for skin: No special precaution must be adopted for normal use. Protection for hands: Suitable materials for safety gloves; EN ISO 374: Polychloroprene - CR: thickness >=0,5mm; breakthrough time >=480min. Nitrile rubber - NBR: thickness >=0,35mm; breakthrough time >=480min. Butyl rubber - IIR: thickness >=0,5mm; breakthrough time >=480min. Fluorinated rubber - FKM: thickness >=0,4mm; breakthrough time >=480min. Respiratory protection: Personal Protective Equipment should comply with relevant CE standards (as EN ISO 374 for gloves and EN ISO 166 for goggles), correctly maintained and stored. Consult the supplier to check the suitability of equipment against specific chemicals and for user information. Not needed for normal use. Anyway, operate according good working practices. Hygienic and Technical measures Not available Appropriate engineering controls: Not available SECTION 9: Physical and chemical properties 9.1. Information on basic physical and chemical properties Physical state: Liquid Appearance: paste Color: various Odour: Characteristic Odour threshold: Not available Melting point / freezing point: Not available Initial boiling point and boiling range: 100 °C (212 °F) Flammability: N.A. Upper/lower flammability or explosive limits: Not available Flash point: Not available Auto-ignition temperature: Not available Decomposition temperature: Not available pH: Not available Viscosity: 110,000.00 cPs Kinematic viscosity: Not available Print date 09/06/2022 Production Name ULTRABOND ECO VS90 PLUS Page n. 3 of Kinematic viscosity: Not available Solubility in water: dispersible Solubility in oil: insoluble Partition coefficient (n-octanol/water): Not available Vapour pressure: Not available Relative density: Not available Vapour density: Not available Particle characteristics: Particle size: Not available 9.2. Other information Miscibility: Not available Conductivity: Not available Explosive properties: == No other relevant information SECTION 10: Stability and reactivity 10.1. Reactivity Stable under normal conditions 10.2. Chemical stability Stable under normal conditions 10.3. Possibility of hazardous reactions None. 10.4. Conditions to avoid Stable under normal conditions. 10.5. Incompatible materials None in particular. 10.6. Hazardous decomposition products None. SECTION 11: Toxicological information 11.1. Information on hazard classes as defined in Regulation (EC) No 1272/2008 Toxicological information of the mixture: a) acute toxicity Not classified Based on available data, the classification criteria are not met b) skin corrosion/irritation Not classified Based on available data, the classification criteria are not met c) serious eye damage/irritation Not classified Based on available data, the classification criteria are not met d) respiratory or skin sensitisation Not classified Based on available data, the classification criteria are not met e) germ cell mutagenicity Not classified Based on available data, the classification criteria are not met f) carcinogenicity Not classified Based on available data, the classification criteria are not met g) reproductive toxicity Not classified Based on available data, the classification criteria are not met h) STOT-single exposure Not classified Based on available data, the classification criteria are not met i) STOT-repeated exposure Not classified Based on available data, the classification criteria are not met j) aspiration hazard Not classified Based on available data, the classification criteria are not met Toxicological information on main components of the mixture: 1,2-benzisothiazol-3(2H)- a) acute toxicity LD50 Oral Rat = 670, mg/kg one; 1,2-benzisothiazolin- 3-one Print date 09/06/2022 Production Name ULTRABOND ECO VS90 PLUS Page n. 4 of reaction mass of: 5- a) acute toxicity LC50 Inhalation Rat = 2,36 mg/l 4h chloro-2-methyl-4- isothiazolin-3-one [EC no. 247-500-7] and 2- methyl-2H -isothiazol-3- one [EC no. 220-239-6] (3:1) LD50 Skin Rabbit = 660, mg/kg

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