DIHYDROMYRCENOL

Hazard statements (CLP)

H227, H303, H315, H319, H336, H402

Code

Statements

H227

Combustible liquid

SECTION 2: Hazards identification

Classification of the substance or mixture Flam. Liq. 4 - H227 Acute Tox. 5 (oral) - H303 Skin lrrit. 2 - H315 Eye lrrit. 2A - H319 STOT SE 3 (narc.) - H336 Aquatic Acute 3 - H402

Signal word

Warning

Hazard statements

H227 - Combustible liquid. H303 - May be harmful if swallowed. H315 - Causes skin irritation. H319 -Causes serious eye irritation. H336 - May cause drowsiness or dizziness. H402 - Harmful to aquatic life.

Precautionary statements

P210 - Keep away from heat/sparks/open flames/hot surfaces. - No smoking. P261 -Avoid breathing dust/fume/gas/mist/vapours/spray. P280 - Wear protective gloves/protective clothing/eye protection/face protection. P302+P352+P332+P313 - IF ON SKIN Wash with plenty of soap and water. If skin irritation occurs Get medical advice/attention P305+P351+P338+P337+P313 - IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. If eye irritation persists: Get medical advice/attention. P312 - Call a POISON CENTER or doctor/physician if you feel unwell. P403+P233 - Store in a well-ventilated place. Keep container tightly closed. 19-20 Sandleheath Industrial Estate, Fordingbridge, Hampshire, SP6 1PA, UK Tel 01425 655555 Email technical@madarcorporation.co.uk Page 10 of 16

2.1 Classification of the substance or mixture

Flam. Liq. 4 - H227 Acute Tox. 5 (oral) - H303 Skin lrrit. 2 - H315 Eye lrrit. 2A - H319 STOT SE 3 (narc.) - H336 Aquatic Acute 3 - H402 2.2. Label Elements Hazard pictograms: Signal Word: Warning Hazard statements: H227 - Combustible liquid. H303 - May be harmful if swallowed. H315 - Causes skin irritation. H319 -Causes serious eye irritation. H336 - May cause drowsiness or dizziness. H402 - Harmful to aquatic life. Precautionary statements: P210 - Keep away from heat/sparks/open flames/hot surfaces. - No smoking. P261 -Avoid breathing dust/fume/gas/mist/vapours/spray. P280 - Wear protective gloves/protective clothing/eye protection/face protection. P302+P352+P332+P313 - IF ON SKIN: Wash with plenty of soap and water. If skin irritation occurs: Get medical advice/attention. P305+P351+P338+P337+P313 - IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. If eye irritation persists: Get medical advice/attention. P312 - Call a POISON CENTER or doctor/physician if you feel unwell. P403+P233 - Store in a well-ventilated place. Keep container tightly closed. 19-20 Sandleheath Industrial Estate, Fordingbridge, Hampshire, SP6 1PA, UK Tel: 01425 655555 Email: technical@madarcorporation.co.uk Page 10 of 16 2.3. Other hazards 3. COMPOSITION/INFORMATION ON INGREDIENTS 3.1. Substances Chemical name: DIHYDROMYRCENOL CAS number: EC number: 242-362-4 Hazardous constituents: 0/o(w/w} CAS No. Chemical Name EC No. Classification according to GHS Flammable Liquids - Category 4 - H227 Acute Toxicity - Category S (oral) - H303 18479-58-8 Skin Irritant - Category 2 - H315 DIHYDROMYRCENOL so 242-362-4 Eye Irritant - Category 2A- H319 Specific target organ toxicity following single exposure - Category 3 (narcotic effects} - H336 Hazardous to the aquatic environment, short-term (acute) - Category 3 - H402 See the full text of the hazard statements in section 16. 3.2. Mixtures Not applicable. 4. FIRST-AID MEASURES 4.1. Description of necessary first aid measures Ingestion: Rinse mouth with water. Obtain medical advice. Keep at rest. Do not induce vomiting. Eye contact: In case of contact with eyes, rinse immediately with plenty of water for at least 15 minutes and seek medical advice. Inhalation: Remove person to fresh air and keep at rest. Seek immediate medical advice. Skin contact: Take off immediately all contaminated clothing. Thoroughly wash affected skin with soap and water. Seek medical attention if symptoms persist. 4.2. Most important symptoms and effects, both acute and delayed No information available. 4.3. Indication of any immediate medical attention and special treatment needed No information available. 5. FIRE-FIGHTING MEASURES 5.1. Extinguishing Media Water spray, carbon dioxide, dry chemical powder or appropriate foam. For safety reasons do not use full water jet. 5.2. Special hazards arising from the substance or mixture Known or Anticipated Hazardous Products of Combustion: Emits toxic fumes under fire conditions. 5.3. Advice for firefighters High temperatures can lead to high pressures inside closed containers. Avoid inhalation of vapors that are created. Use appropriate respiratory protection. Do not allow spillage of fire to be poured into drains or watercourses. Wear self-contained breathing apparatus and protective clothing. 6. ACCIDENTAL ' · .c_,.,. RELEASE ' s . - -, MEASURES .• . 6.1. Personal precautions, protective equipment and emergency procedures Evacuate surronding areas. Ensure adequate ventilation. Keep unnecessary and unprotected personnel from entering. Do not breathe vapor/spray. Avoid contact with skin and eyes. lnformatipA regarding personal protective measures: see section 8. 6.2. Environmental precautions To avoid possible contamination of the environment, do not discharge into any drains, surface waters or groundw_aters. .· 19-20 Sandleheath Industrial Estate, Fordingbridge, Hampshire, SP6 1PA, UK Tel: 01425 655555 Email: technical@madarcorporation.co.uk Page 11 of 16 6.3. Methods and materials for containment and cleaning up Cover with an inert, inorganic, non-combustible absorbent material (e.g. dry-lime, sand, soda ash). Place in covered containers using non-sparking tools and transport outdoors. Avoid open flames or sources of ignition (e.g. pilot lights on gas hot water heater). Ventilate area and wash spill site after material pickup is complete. 6.4. Reference to other sections Information regarding exposure controls, personal protection and disposal considerations can be found in sections 8 and 13. 7. HANDLING AND STORAGE 7.1. Precautions for safe handling Do not store or handle this material near food or drinking water. Do not smoke. Avoid contact with the eyes, skin and clothing. Wear protective clothing and use glasses. Observe the rules of safety and hygiene at work. Keep in the original container or an alternative made from a compatible material. 7.2. Conditions for safe storage, including any incompatibilities Store in tightly closed and preferably full containers in a cool, dry and ventilated area, protected from light. Keep away from sources of ignition (e.g. hot surfaces, sparks, flame and static discharges). Keep away from incompatible materials (see section 10). 7.3. Specific end use(s} No information available. 8. EXPOSURE CONTROLS AND PERSONAL PROTECTION 8.1. Control parameters Components with occupational exposure limits: None known. 8.2. Exposure controls Measures should be taken to prevent materials from being splashed into the body. Provide adequate ventilation, according to the conditions of use. Use a mechanical exhaust if required. 8.3. Individual protection measures, such as personal protective equipment Eye/Face protection: Chemical safety goggles are recommended. Wash contaminated goggles before reuse. Hand Protection: Chemical-resistant gloves are recommended. Wash contaminated gloves before reuse. Body protection: Personal protective equipment for the body should be selected based on the task being performed and the risks involved. Respiratory Protection: In case of insufficient ventilation, use suitable respiratory equipment. Environmental exposure Emissions from ventilation or process equipment should be checked to ensure they comply with environmental controls: protection legislation. In some cases, filters or engineering modifications to the process equipment will be necessary to reduce emissions to acceptable levels. 9. PHYSICAL AND CHEMICAL PROPERTIES Appea ranee: Liquid Colour: Conforms to standard Odour: Conforms to Odour theshold: standard Not pH: determined Not Melting point/freezing point: determined Boling point/boiling range ('C): Not Flash point: determined 76 •c Evaporation rate: Not determined Flammability: Not determined Lower flammability/Explosive limit: Not determined Upper flammability/Explosive limit: Not determined Vapour pressure: Not determined Vapour Density: Not determined Density: o,83-0,84 g/mL (20°c) Relative density: o,83-0,84 (20°c) Water solubility: 1-5 ml/ml ETHANOL 70° I Solubility in other solvents: SOLUBLE IN ETHANOL 19-20 Sandleheath Industrial Estate, Fordingbridge, Hampshire, SP6 1PA, UK Tel: 01425 655555 Email: technical@madarcorporation.co.uk Page 12 of 16 Partition coefficient n-octanol/water: Not determined Auto-ignition temperature: Not determined Decomposition temperature: Not determined Viscosity. dynamic: Not determined Viscosity, kinematic: Not determined Explosive properties: Not determined Oxidising properties: NONE EXPECTED 10. STABILITY AND REACTIVITY 1 o .1. Reactivity No hazardous reactions if stored and handled as prescribed/indicated. 10.2. Chemical stability The product is stable if stored and handled as prescribed/indicated. 10.3. Possibility of hazardous reactions No hazardous reactions if stored and handled as prescribed/indicated. 10.4. Conditions to Avoid Conditions to Avoid: Excessive heat, flame or other ignition sources. 10.5. Incompatible materials Avoid contact with strong acids and bases and oxidizing agents. 10.6. Hazardous decomposition products During combustion may form carbon monoxide and unidentified organic compounds. 11. TOXICOLOGICAL INFORMATION Acute toxicity May be harmful if swallowed. Skin corrosion/irritation Causes skin irritation. Serious eye damage/irritation Causes serious eye irritation. Respirator y or skin sensitisation Based on the data available, he criteria for classification are not met. Germ cell mutagenicity Based on the data available, the criteria for classification are not met. Carcinogenicity Based on the data available, the criteria for classification are not met. Reproductive toxicity Based on the data available, the criteria for classification are not met. STOT-single exposure May cause drowsiness or dizziness. STOT-repeated exposure Based on the data available, the criteria for classification are not met. J Aspiration hazard i Based on the data available, the criteria for classification are not met. 12. ECOLOGICAL INFORMATION 12.1. Toxicity Assessment: Harmful to aquatic life. Experimental/calculated data: No information available. 12.2. Persistence and degradability Biodegradation: > 72%. (OECD 301 B). The product is readily biodegradable 12.3. Bioaccumulative potential No information available. 12.4. Soil mobility No information available. 12.5. Other adverse effects See also sections 6, 7, 13 and 15 Do not allow to get into waste water or waterways. 19-20 Sandleheath Industrial Estate, Fordingbridge, Hampshire, SP6 1PA, UK Tel: 01425 655555 Email: technical@madarcorporation.co.uk Page 13 of 16 ,'\\ufffd . ./:;·.' ·,.,. 13. DISPOSAL CONSIDERATIONS 13.1. Waste treatment methods Dispose of in accordance with national and local environmental regulations. 14. TRANSPORT INFORMATION ADR/RID/ADN IMDG IATA-ICAO 14.1. UN Number Not classified as hazardous goods 14.2. UN Proper Shipping Name Not applicable 14.3. Transport Hazard Class(es) Not applicable 14.4. Packing Group Not applicable 14.S. Environmental hazards No Additional information 14.6 Special precautions for user None known 14.7. Maritime transport in bulk according to IMO instruments No information available 15. REGULATORY INFORMATION 15.1. Safety, health and environmental regulations/legislation specific for the substance or mixture No information available 16. OTHER INFORMATION Full text of the R-phrases, hazard statements and precautionary statements mentioned in section 3: H227 - Combustible liquid . H303 - May be harmful if swallowed. H315 - Causes skin irritation. H319 - Causes serious eye irritation. H336 - May cause drowsiness or dizziness. H402 - Harmful to aquatic life. 19-20 Sandleheath Industrial Estate, Fordingbridge, Hampshire, SP6 1PA, UK Tel: 01425 655555 Email: technical@madarcorporation.co.uk Page 14 of 16 .SPECIFICATION SHEET VERSION 4,00 VERSION DATE 19/09/22 PRINT DATE 22/02/24 PRODUCT DIHYDROMYRCENOL APPLICATIONS Industrial raw material not intended for direct IUPAC NAME use. 2,6-DIMETHYL-7-0CTEN-2-0L SYNONYMS 2,6-DIMETHYL-7-0CTEN-2-0L FORMULA ClO H20 0 MOLECULAR WEIGHT 156,00 CAS 184 79-58-8 EINECS 242-362-4 (1 TARIFF NUMBER 2905220090 +OH REACH REGISTRATION NO. 01-2119457274-37 SPECIFICATIONS ASPECT AT 20°C CLEAR MOBILE LIQUID COLOUR COLORLESS ODOUR FRESH,CITRIC,FLORAL,STRONG,SWEET TASTE DENSITY AT 20°c (g / ml) 0,830 - 0,840 DENSITY 25/25 REFRACTIVE INDEX nD20 1,4350 - 1,4450 REFRACTIVE INDEX nD25 OPTICAL ROTATION (0) -10,00 I 10,00 BOILING POINT (°C) MELTING POINT (°C) FLASH POINT (°C) 76,00 ASSAY(% GC) > 98 ACID VALUE (mg KOH/g) < 0.5 SOLUBILITY 1-5 ml/ml ETHANOL 70° VAPOUR PRESSURE NOT DETERMINED OTHER SOLUBILITIES SOLUBLE IN ETHANOL OTHER TECHNICAL DATA STABILITY AND STORAGE KEEP IN TIGHTLY CLOSED CONTAINER IN A COOL AND qRY PLACE, PROTECTED FROM LIGHT. WHEN STORED FOR MORE THAN 24 MONTHS, QUALITY SHOULD BE CHECKED BEFORE USE. IT TAKES COLOR IF HEATED REPETEADLY WE BELIEVE THE ABOVE INFORMATION TO BE CORRECT BUT WE DO NOT PRESENT IT AS ALL INCLUSIVE AND AS SUCH SHOULD BE USED AS A GUIDE. IT IS THE SOLE RESPONSIBILITY OF THE RECEIVER OF OUR PRODUCT TO COMPLY WITH EXISTING REGULATIONS AND INSTRUCTIONS. THIS PRODUCT HAS NOT BEEN FILTERED DUE TO TECHNICAL REASONS. WE RECOMMEND NOT TO USE IT UNLESS FILTERED WHEN USED AS A RAW MATEAL IN FOOD INTENDED FOR FINAL CONSUMERS. 19-20 Sandleheath Industrial Estate, Fordingbridge, Hampshire, SP6 1PA, UK Tel: 01425 655555 Email: technical@madarcorporation.co.uk Page 15 of 16 = VEGAN CERTIFIC l"E 22 February 2024 Product: DIHYOROMYRCl:NOL This is to certify that, to the best of our knowledge, the above-mentioned material is suitable for the following diets: 0 Vegan Does not contain any ingredient of animal origin (mammalian, poultry, fish, crustacean, mollusc) or animal derivatives (dairy, egg and bee products) including additives and processing aids. In addition, we confirm that it complies with the requirements listed on the Criteria of the V-label: Regulations, that can be found in https://www.v-label.eu/regulations_text 0 Vegetarian Does not contain any ingredient of animal origin (mammalian, poultry, fish, crustacean, mollusc) or dairy and egg products, including additives and processing aids. Bee products (e.g. honey, bees wax) are acceptable. [Zl Ovo-Lacto Vegetarian Does not contain any ingredient of animal origin (mammalian, poultry, fish, crustacean, mollusc), including additives and processing aids. Dairy, egg and bee products (e.g. honey, bees wax} are acceptable. 'Animal' refers to the entire anlmal kingdom, i.e. vertebrates and multicellular Invertebrates, 'rhe inforn1alion indicated above corresponds to our knowled9e at the date or issue. This dOcllment Is electronically generated and U1erefore It is not sl9ned, 19-20 Sandleheath Industrial Estate, Fordingbridge, Hampshire, SP6 1PA, UK Tel: 01425 655555 Email: technical@madarcorporation.co.uk Page 16 of 16 = --I