Pina Colada

MADAR Corporation Limited

Revision date : 2025-04-13

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GHS09 GHS07
Health risk rating 4
Safety risk rating 1
Environmental risk rating 4

Note: Ingredients listed on restricted chemical lists

EC/CAS

202-086-7/91-64-5

Name of the chemical

2H-1-Benzopyran-2-one

Concentration

5-<10%

EC/CAS

204-642-4/123-68-2

Name of the chemical

Allyl hexanoate

Concentration

1-<5% 1-

EC/CAS

259-174-3/54464-57-2

Name of the chemical

1-(1,2,3,4,5,6,7,8-octahydro-2,3,8,8-tetramethyl-2-naphthyl)ethan-1-one; 1-(1,2,3,4,5,6,7,8-octahydro-2,3,5,5-tetramethyl-2-naphthyl)ethan-1-one; 1-(1,2,3,5,6,7,8,8a-octahydro-2,3,8,8-tetramethyl-2-naphthyl)ethan-1-one; 1-(1,2,3,4,6,7,8,8a-octahydro-2,3,8,8-tetramethyl-2-naphthyl)ethan-1-one (40)

Concentration

1-<5%

EC/CAS

259-174-3/2705-87-5

Name of the chemical

Allyl cyclohexylpropionate; 2-Propenyl 3-Cyclohexanepropanoate

Concentration

1-<5%

EC/CAS

214-946-9/5989-27-5

Name of the chemical

(R)-p-mentha-1,8-diene

Concentration

0.1-<1%

EC/CAS

220-292-5

Name of the chemical

Allyl cyclohexylpropionate; 2-Propenyl 3-Cyclohexanepropanoate

Concentration

1-<5%

EC/CAS

227-813-5

Name of the chemical

(R)-p-mentha-1,8-diene; (d-limonene)

Concentration

0.1-<1%

General Information

Revision date

2025-04-13

Product name

Pina Colada

Product Synonyms

None

1.2.1 Relevant identified uses

Fragrances

Icons in SDS

GHS07 GHS09 M004 M009 M013 M017

Company Information

company name

MADAR Corporation Limited

e-mail address of the competent person responsible for the Safety Data Sheet

technical@madarcorporation.co.uk

GHS Information

Signal word

Warning

Hazard Codes

Hazard statements (CLP)

H317, H411

Hazard statements

Code

Statements

H317

May cause an allergic skin reaction

Section 2

SECTION 2: Hazards identification

Classification under Regulation (EC) No 1272/2008 Classification of the substance or mixture

Signal word

Warning

Hazard statements

H317, May cause an allergic skin reaction. H411, Toxic to aquatic life with long lasting effects. EUH208, Contains d-Limonene. May produce an allergic reaction.

Additional information

1

Precautionary statements

P261, Avoid breathing vapour or dust. P272, Contaminated work clothing should not be allowed out of the workplace. P273, Avoid release to the environment. P280, Wear protective gloves/eye protection/face protection. P303/361/353, IF ON SKIN (or hair): Remove/take off immediately all contaminated clothing. Rinse skin with water/shower. P333/313, If skin irritation or rash occurs: Get medical advice/attention. P363, Wash contaminated clothing before reuse. P391, Collect spillage. P501, Dispose of contents/container to approved disposal site, in accordance with local regulations.

2.3 Other hazards

None

2.1 Classification of the substance or mixture

Classification under Regulation (EC) No 1272/2008 Class and category of Sensitization - Skin Category 1 danger: Hazardous to the Aquatic Environment - Long-term Hazard Category 2 H317, May cause an allergic skin reaction. H411, Toxic to aquatic life with long lasting effects. 2.2 Label elements Signal word: Warning Hazard statements: H317, May cause an allergic skin reaction. H411, Toxic to aquatic life with long lasting effects. EUH208, Contains d-Limonene. May produce an allergic reaction. Supplemental Information: 1 Precautionary P261, Avoid breathing vapour or dust. statements: P272, Contaminated work clothing should not be allowed out of the workplace. P273, Avoid release to the environment. P280, Wear protective gloves/eye protection/face protection. P303/361/353, IF ON SKIN (or hair): Remove/take off immediately all contaminated clothing. Rinse skin with water/shower. P333/313, If skin irritation or rash occurs: Get medical advice/attention. P363, Wash contaminated clothing before reuse. P391, Collect spillage. P501, Dispose of contents/container to approved disposal site, in accordance with local regulations. Pictograms: Other hazards: None Section 3. Composition / information on ingredients 3.2 Mixtures Contains: REACH Registration Classification for Name CAS EC % No. (CLP) 1272/2008 Coumarin 91-64-5 202-086-7 5-<10% ATO 4-SS 1B;H302- H317,- ATO 3-ATD 3-ATI 3-EH Allyl hexanoate 123-68-2 204-642-4 1-<5% A1-EH C3;H301-H311- H331-H400-H412,- 1-(1,2,3,4,5,6,7,8- Octahydro-2,3,8,8- 54464-57-2 259-174-3 1-<5% SCI 2-SS 1B-EH C1; tetramethyl-2- H315-H317-H410,- naphthalenyl)ethanone 1 ATO 4-ATD 4-ATI 4-SS Allyl 2705-87-5 220-292-5 1-<5% 1-EH A1-EH C1;H302- cyclohexanepropionate H312-H317-H332- H410,- Ethyl maltol 4940-11-8 225-582-5 1-<5% ATO 4;H302,- alpha- 101-86-0 202-983-3 1-<5% SS 1B-EH A1-EH C2; Hexylcinnamaldehyde H317-H400-H411,- gamma-Undecalactone 104-67-6 203-225-4 1-<5% EH C3;H412,- 1,3,4,6,7,8-Hexahydro- 4,6,6,7,8,8- 1222-05-5 214-946-9 0.1-<1% EH A1-EH C1;H410,- hexamethylcyclopenta- gamma-2-benzopyran FL 3-SCI 2-SS 1B-AH d-Limonene 5989-27-5 227-813-5 0.1-<1% 1-EH A1-EH C1;H226- H304-H315-H317- H410,- Substances with Community workplace exposure limits: Not Applicable Substances that are persistent, bioaccumulative and toxic or very persistent and very bioaccumulative, greater than 0.1%: Not Applicable Section 4. First-aid measures 4.1 Description of first aid measures IF ON SKIN (or hair): Remove/take off immediately all contaminated clothing. Rinse skin with water/shower. 4.2 Most important symptoms and effects, both acute and delayed May cause an allergic skin reaction. 4.3 Indication of any immediate medical attention and special treatment needed None expected, see Section 4.1 for further information. SECTION 5: Firefighting measures 5.1 Extinguishing media Suitable media: Carbon dioxide, Dry chemical, Foam. 5.2 Special hazards arising from the substance or mixture Carbon monoxide, Unidentified organic compounds. 5.3 Advice for fire fighters: In case of insufficient ventilation, wear suitable respiratory equipment. 1 Section 6. Accidental release measures 6.1 Personal precautions, protective equipment and emergency procedures: Avoid inhalation. Avoid contact with skin and eyes. See protective measures under Section 7 and 8. 6.2 Environmental precautions: Keep away from drains, surface and ground water, and soil. 6.3 Methods and material for containment and cleaning up: Provide adequate ventilation. Avoid excessive inhalation of vapours. Contain spillage immediately by use of sand or inert powder. Dispose of according to local regulations. 6.4 Reference to other sections: Also refer to sections 8 and 13. Section 7. Handling and storage 7.1 Precautions for safe handling: Not Applicable 7.2 Conditions for safe storage, including any incompatibilities: Not Applicable 7.3 Specific end use(s): Fragrances: Use in accordance with good manufacturing and industrial hygiene practices. Section 8. Exposure controls/personal protection 8.1 Control parameters Workplace exposure limits: Not Applicable 8.2 Exposure Controls Eye / Skin Protection Wear protective gloves/eye protection/face protection Respiratory Protection Under normal conditions of use and where adequate ventilation is available to prevent build up of excessive vapour, this material should not require special engineering controls. However, in conditions of high or prolonged use, or high temperature or other conditions which increase exposure, the following engineering controls can be used to minimise exposure to personnel: a) Increase ventilation of the area with local exhaust ventilation. b) Personnel can use an approved, appropriately fitted respirator with organic vapour cartridge or canisters and particulate filters. c) Use closed systems for transferring and processing this material. 1 Also refer to Sections 2 and 7. Section 9. Physical and chemical properties 9.1 Information on basic physical and chemical properties Appearance: Clear to pale yellow Odour: Sweet Odour threshold: Not determined pH: Not determined Melting point / freezing point: Not determined Initial boiling point / range: Not determined Flash point: 96 °C Evaporation rate: Not determined Flammability (solid, gas): Not determined Upper/lower flammability or explosive limits: Product does not present an explosion hazard Vapour pressure: Not determined Vapour density: Not determined Relative density: 0.997625 - 1.007625 Solubility(ies): Not determined Partition coefficient: n-octanol/water: Not determined Auto-ignition temperature: Not determined Decomposition temperature: Not determined Viscosity: Not determined Explosive properties: Not expected Oxidising properties: Not expected Refractive Index: 1.45113 - 1.46061 Optical Rotation: 0.557° 9.2 Other information: None available Section 10. Stability and reactivity 10.1 Reactivity: Presents no significant reactivity hazard, by itself or in contact with water. 10.2 Chemical stability: Good stability under normal storage conditions. 10.3 Possibility of hazardous reactions: Not expected under normal conditions of use. 10.4 Conditions to avoid: Not Applicable 1 10.5 Incompatible materials: Avoid contact with strong acids, alkalis or oxidising agents. 10.6 Hazardous decomposition products: Not expected. Section 11. Toxicological information 11.1 Information on toxicological effects This mixture has not been tested as a whole for health effects. The health effects have been calculated using the methods outlined in Regulation (EC) No 1272/2008 (CLP).

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