General Information
Version
3.2/GHS/EN
Revision date
2022-10-13
Product name
PHENYLETHYLACETAT
Substance name
E PHENYL ETHYL
CAS No.
103-45-7
Emergency telephone
(+44) 1865 407333, (+34) 91114 2520, (+1) 202 464 2554
Icons in SDS
Company Information
company name
Madar Corporation limited
e-mail address of the competent person responsible for the Safety Data Sheet
technical@madarcorporation.co.uk
GHS Information
Signal word
Danger
Hazard Codes
Hazard statements (CLP)
H303, H318, H402
Hazard statements
Code
Statements
H303
May be harmful if swallowed
Section 2
SECTION 2: Hazards identification
Classification of the substance or mixture Acute lox. 5 (oral) - H303 Eye Dam. 1 - H318 Aquatic Acute 3 - H402
2.2 Label elements
m s ,
Signal word
Danger
Hazard statements
H303 - May be harmful if swallowed. H318 - Causes serious eye damage. H402 - Harmful to aquatic life.
Precautionary statements
P273 -Avoid release to the environment. P280 - Wear protective gloves/protective clothing/eye protection/face protection. P305+P351+P338+P310 - IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Imme- diately call a POISON CENTER or doctor/physician. P312 - Call a POISON CENTER or doctor/physician if you feel unwell. P501 - Dispose of contents/container according to local legislation.
2.1 Classification of the substance or mixture
mixture Acute lox. 5 (oral) - H303 Eye Dam. 1 - H318 Aquatic Acute 3 - H402 2.2. Label Elements m s , Signal Word: Danger Hazard statements: H303 - May be harmful if swallowed. H318 - Causes serious eye damage. H402 - Harmful to aquatic life. Precautionary statements: P273 -Avoid release to the environment. P280 - Wear protective gloves/protective clothing/eye protection/face protection. P305+P351+P338+P310 - IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Imme- diately call a POISON CENTER or doctor/physician. P312 - Call a POISON CENTER or doctor/physician if you feel unwell. P501 - Dispose of contents/container according to local legislation. 2.3. Other hazards 3. COMPOSITION/INFORMATION ON INGREDIENTS 3.1. Substances Chemical name: CAS number: 203-113-5 EC number: Hazardous constituents: CASNo. Chemical Name %{w/w) Classification according to GHS EC No. Acute Toxicity- Category 5 (oral) - H303 103-45-7 2-PHENYL ETHYL ACETATE 50 Serious eye damage- Category 1 - H318 203-113-5 Hazardous to the aquatic environment, short-term (acute) - Category 3 - H402 See the full text of the hazard statements in section 16. 3.2. Mixtures Not applicable. 4. FIRST-AID MEASURES 4.1. Description of necessary first aid measures Ingestion: Rinse mouth with water. Obtain medical advice. Keep at rest. Do not induce vomiting. Eye contact: In case of contact with eyes, rinse immediately with plenty of water for at least 15 minutes and seek medical advice. Inhalation: Remove person to fresh air and keep at rest. Seek immediate medical advice. Skin contact: Take off immediately all contaminated clothing. Thoroughly wash affected skin with soap and water. Seek medical attention if symptoms persist. 4.2. Most important symptoms and effects, both acute and delayed No information available. 4.3. Indication of any immediate medical attention and special treatment needed No information available. 5. FIRE-FIGHTING MEASURES 5.1. Extinguishing Media Water spray, carbon dioxide, dry chemical powder or appropriate foam. For safety reasons do not use full water jet. 5.2. Special hazards arising from the substance or mixture Known or Anticipated Hazardous Products of Combustion: Emits toxic fumes under fire conditions. 5.3. Advice for firefighters High temperatures can lead to high pressures inside closed containers. Avoid inhalation ofvapors that are created. Use appropriate respiratory protection. Do not allow spillage of fire to be poured into drains or watercourses. Wear self-contained breathing apparatus and protective clothing. 6. ACCIDENTAL RELEASE MEASURES 6.1. Personal precautions, protective equipment and emergency procedures Evacuate surronding areas. Ensure adequate ventilation. Keep unnecessary and,unprotected personnel from entering. Do not breathe vapor/spray. Avoid contact with skin and eyes. Information regarding personal protective measures: see section 8. 6.2. Environmental precautions To avoid possible contamination of the environment, do not discharge into any drains, surface waters or groundwaters. 6.3. Methods and materials for containment and cleaning up Cover with an inert, inorganic, non-combustible absorbent material (e.g. dry-lime, sand, soda ash). Place in covered containers using non-sparking tools and transport outdoors. Avoid open flames or sources of ignition (e.g. pilot lights on gas hot water heater). Ventilate area and wash spill site after material pickup is complete. 6.4. Reference to other sections Information regarding exposure controls, personal protection and disposal considerations can be found in sections 8 and 13. 7. HANDLING AND STORAGE 7.1. Precautions for safe handling Do not store or handle this material near food or drinking water. Do not smoke. Avoid contact with the eyes, skin and clothing. Wear protective clothing and use glasses. Observe the rules of safety and hygiene at work. Keep in the original container or an alternative made from a compatible material. 7.2. Conditions for safe storage, including any incompatibilities Store in tightly closed and preferably full containers in a cool, dry and ventilated area, protected from light. Keep away from sources of ignition (e.g. hot surfaces, sparks, flame and static discharges). Keep away from incompatible materials (see section 10). 7.3. Specific end use(s) No information available. 8. EXPOSURE CONTROLS AND PERSONAL PROTECTION 8.1. Control parameters Components with occupational exposure limits: None known. 8.2. Exposure controls Measures should be taken to prevent materials from being splashed into the body. Provide adequate ventilation, according to the conditions of use. Use a mechanical exhaust if required. 8.3. Individual protection measures, such as personal protective equipment Eye/Face protection: Chemical safety goggles are recommended. Wash contaminated goggles before reuse. Hand Protection: Chemical-resistant gloves are recommended. Wash contaminated gloves before reuse. Body protection: Personal protective equipment for the body should be selected based on the task being performed and the risks involved. Respiratory Protection: In case of insufficient ventilation, use suitable respiratory equipment. Environmental exposure controls: Emissions from ventilation or process equipment should be checked to ensure they comply with environmental protection legislation. In some cases, filters or engineering modifications to the process equipment will be necessary to reduce emissions to acceptable levels. 9. PHYSICAL AND CHEMICAL PROPERTIES Appearance: Liquid Colour: Conforms to Odour: standard Conforms to Odour theshold: standard Not pH: determined Not Melting point/freezing point: Boling determined -10 point/boiling range (0C): Flash point: 232 Evaporation rate: 1os•c Flammability: Not determined Lower flammability/Explosive limit: Not determined Upper flammability/Explosive limit: Not determined Vapour pressure: Not determined Vapour Density: Not determined Density: Not determined Relative density: 1,031-1,035 g/mL (20°C) Water solubility: 1,031-1,035 (20°cJ Not Solubility in other solvents: Partition determined coefficient n-octanolfwater: Auto- Not determined ignition temperature: Decomposition Not determined temperature: Viscosity, dynamic: Not determined Viscosity, kinematic: Not determined Explosive properties: Not determined Oxidising properties: Not determined 10. STABILITY AND REACTIVITY 10.1. Reactivity No hazardous reactions if stored and handled as prescribed/indicated. 10.2. Chemical stability The product is stable if stored and handled as prescribed/indicated. 10.3. Possibility of hazardous reactions No hazardous reactions if stored and handled as prescribed/indicated. 10.4. Conditions to Avoid Conditions to Avoid: Excessive heat, flame or other ignition sources. 10.5. Incompatible materials Avoid contact with strong acids and bases and oxidizing agents. 10.6. Hazardous decomposition products During combustion may form carbon monoxide and unidentified organic compounds. 11. TOXICOLOGICAL INFORMATION Acute toxicity May be harmful if swallowed. Skin corrosion/irritation Based on the data available, the criteria for classification are not met. Serious eye damage/irritation Causes serious eye damage. Respiratory or skin sensitisation Based on the data available, the criteria for classification are not met. Germ cell mutagenicity Based on the data available, the criteria for classification are not met. Carcinogenicity Based on the data available, the criteria for classification are not met. Reproductive toxicity Based on the data available, the criteria for classification are not met. STOT-single exposure Based on the data available, the criteria for classification are not met. STOT-repeated exposure Based on the data available, the criteria for classification are not met. Aspiration hazard Based on the data available, the criteria for classification are not met. 12. ECOLOGICAL INFORMATION 12.1. Toxicity Assessment: Harmful to aquatic life. Experimental/calculated data: No information available. 12.2. Persistence and degradability No information available. 12.3. Bioaccumulative potential No information available. 12.4. Soil mobility No information available. 12.5. Other adverse effects See also sections 6, 7, 13 and 15 Do not allow to get into waste water or waterways. 13. DISPOSAL CONSIDERATIONS 13.1. Waste treatment methods Dispose of in accordance with national and local environmental regulations. 14. TRANSPORT INFORMATION ADR/RID/ADN IMDG IATA-ICAO 14.1. UN Number Not classified as hazardous goods 14.2. UN Proper Shipping Name Not applicable 14.3. Transport Hazard Class(es) Not applicable 14.4. Packing Group Not applicable 14.5. Environmental hazards No Additional information 14.6 Special precautions for user None known 14.7. Maritime transport in bulk according to IMO instruments No information available 15. REGULATORY INFORMATION 15.1. Safety, health and environmental regulations/legislation specific for the substance or mixture No information available 16. OTHER INFORMATION Full text of the R-phrases, hazard statements and precautionary statements mentioned in section 3: H303 - May be harmful if swallowed. H318 - Causes serious eye damage. H402 - Harmful to aquatic life. The information included in this safety data sheet is based on the available data at the moment this document is issued. It is meant to be a description of safety requirements for our product and does not stand for a guarantee of its properties. The user is responsible for taking all necfssary steps leading to compliance with local rules and legislation. PRINT DATE 05/02/25 SPECIFICATION SHEET PRODUCT PHENYL ETHYL ACETATE IUPAC NAME PH EN ETHYL ACETATE SYNONYMS BENZVL CARBINYL ACETATE, 2-PHENETHYL ACETATE CAS 103-45-7 EINECS 203-113-5 FEMA 2857 TARIFF NUMBER 2915390090 SPECIFICATIONS VERSION VERSION DATE ODOUR FLORAL, ROSY, FRESH, HONEY-LIKE TASTE SWEET, FRUITY DENSITY AT 20°C (g / ml) DENSITY 25/25 REFRACTIVE INDEX nD20 REFRACTIVE INDEX nD25 OPTICAL ROTATION (0) I FLASH POINT (0C) 105 STABILITY AND STORAGE KEEP IN TIGHTLY CLOSED CONTAINER IN A COOL AND DRY PLACE, PROTECTED FROM LIGHT. WHEN STORED FOR MORE THAN 24 MONTHS, QUALITY SHOULD BE CHECKED BEFORE USE. WE BELIEVE THE ABOVE INFORMATION TO BE CORRECT BUT WE DO NOT PRESENT JT AS All INCLUSIVE AND AS SUCH SHOULD BE USED AS A GUIDE. IT IS THE SOLE RESPONSIBILITY OF THE RECEIVER OF OUR PRODUCT TO COMPLY WITH EXISTING GULATIONS Af-lD INSTRUCTIONS. THIS PRODUCT HAS NOT BEEN FILTERED DUE TO TECHNICAL REASONS. WERECOMMEND NOT TO USE IT UNLESS FILTERED WHEN USED AS A W MATERIAL IN FOOD INTENDED FOR FINAL CONSUMERS. VEGAN 05 February 2025 Product: PHENYL ETHYL ACETATE This is to certify that, to the best of our knowledge, the above-mentioned material is suitable for the following diets: 0 Vegan Does not contain any ingredient of animal origin (mammalian, poultry, fish, crustacean, mollusc) or animal derivatives (dairy, egg and bee products) including additives and processing aids. In addition, we confirm that it complies with the requirements listed on the Criteria of the V-label: Regulations, that can be found in Annex1: Criteria for the V-Label 0 Vegetarian Does not contain any ingredient of animal origin (mammalian, poultry, fish, crustacean, mollusc) or dairy and egg products, including additives and processing aids. Bee products (e.g. honey, bees wax) are acceptable. 0 Ovo-Lacto Vegetarian Does not contain any ingredient of animal origin (mammalian, poultry, fish, crustacean, mollusc), including additives and processing aids. Dairy, egg and bee products (e.g. honey, bees wax) are acceptable. 'Animal' refers to the entire animal kingdom, i.e. vertebrates and multicellular invertebrates. The informabon indicated above corresponds to our knowledge at the date of issue. This document 1s electronically generated and therefore it 1s oot signed