Organic Peppermint Oil (Arvensis)

Hazard statements (CLP)

H302, H304, H315, H317, H319, H411

Code

Statements

H302

Harmful if swallowed

SECTION 2: Hazards identification

(EC) No 1272/2008 Classification of the substance or mixture No additional data Classification (EC 1272/2008)

Health hazards

Acute Tox. 4 - H302 Asp. Tox. 1 - H304 Skin Irrit. 2 - H315 Skin Sens. 1 - H317 Eye Irrit. 2 - H319

Environmental hazards

Aquatic Chronic 2 - H411

Signal word

Danger

Contains

- Alpha-Pinene - Beta-Limonene - D-Limonene

Hazard statements

H302 - Harmful if swallowed. H304 - May be fatal if swallowed and enters airways. H315 - Causes skin irritation. H317 - May cause an allergic skin reaction. H319 - Causes serious eye irritation. H411 - Toxic to aquatic life with long lasting effects.

Precautionary statements

P261 - Avoid breathing fume/ mist/vapours/spray. P273 - Avoid release to the environment. P280 - Wear protective gloves/protective clothing/eye protection/face protection. P301/P310 - IF SWALLOWED - Immediately call a POISON CENTRE/doctor. P302/P352 - IF ON SKIN - Wash with plenty of water. P305/P351/P338 - IF IN EYES - Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P331 - Do NOT induce vomiting. P333/P313 - If skin irritation or rash occurs: Get medical advice/attention. P337/P313 - If eye irritation persists: Get medical advice/attention. P391 - Collect spillage. P501 - Dispose of contents in accordance with local, state or national legislation.

Supplemental label elements

P264 - Wash hands and exposed skin thoroughly after handling.

2.3 Other hazards

PBT or vPvB according to Annex XIII Not PBT or vPvB. Adverse physio-chemical properties No additional data

Potential Acute Health Effects

No additional data

2.1 Classification of the substance or mixture

No additional data Classification (EC 1272/2008) Health hazards: - Acute Tox. 4 - H302 - Asp. Tox. 1 - H304 - Skin Irrit. 2 - H315 - Skin Sens. 1 - H317 - Eye Irrit. 2 - H319 Environmental hazards: - Aquatic Chronic 2 - H411 2.2 Label Elements Label in accordance with (EC) No 1272/2008 Signal Word Danger Contains - Alpha-Pinene - Beta-Limonene - D-Limonene Hazard Statements H302 - Harmful if swallowed. H304 - May be fatal if swallowed and enters airways. H315 - Causes skin irritation. H317 - May cause an allergic skin reaction. H319 - Causes serious eye irritation. H411 - Toxic to aquatic life with long lasting effects. Precautionary Statements P261 - Avoid breathing fume/ mist/vapours/spray. P273 - Avoid release to the environment. P280 - Wear protective gloves/protective clothing/eye protection/face protection. P301/P310 - IF SWALLOWED - Immediately call a POISON CENTRE/doctor. P302/P352 - IF ON SKIN - Wash with plenty of water. P305/P351/P338 - IF IN EYES - Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P331 - Do NOT induce vomiting. P333/P313 - If skin irritation or rash occurs: Get medical advice/attention. P337/P313 - If eye irritation persists: Get medical advice/attention. P391 - Collect spillage. P501 - Dispose of contents in accordance with local, state or national legislation. Supplementary Statements P264 - Wash hands and exposed skin thoroughly after handling. 2.3 Other Hazards PBT or vPvB according to Annex XIII Not PBT or vPvB. Adverse physio-chemical properties No additional data Adverse effects on human health No additional data 03. COMPOSITION/INFORMATION ON INGREDIENTS 3.1 Composition 30.0 – 50.0% L-Menthol CAS: 2216-51-5 Classification (EC 1272/2008) Skin Irrit. 2 - H315, Eye Irrit. 2 - H319 15.0 – 35.0% trans-Menthone CAS: 89-80-5 Classification (EC 1272/2008) Acute Tox. 4- H302, Aquatic Chronic 3 - H412 < 10.0% d-Limonene CAS: 5989-27-5 Classification (EC 1272/2008) - Flam. Liq. 3 - H226 - Asp. Tox. 1 - H304 - Skin Irrit. 2 - H315 - Skin Sens. 1 - H317 - Aquatic Acute 1 - H400 - Aquatic Chronic 1 - H410 5.0 – 15.0% dl-Isomenthone CAS: 491-07-6 Classification (EC 1272/2008) - Skin Irrit. 2 - H315 - Skin Sens. 1 - H317 <4.0% alpha-Pinene CAS: 80-56-8 Classification (EC 1272/2008) - Flam. Liq. 3 - H226 - Acute Tox. 4 - H302 - Asp. Tox. 1 - H304 - Skin Irrit. 2 - H315 - Skin Sens. 1 - H317 - Aquatic Acute 1 - H400 - Aquatic Chronic 1 - H410 < 4.0% beta-Pinene CAS: 127-91-3 Classification (EC 1272/2008) - Flam. Liq. 3 - H226 - Asp. Tox. 1 - H304 - Skin Irrit. 2 - H315 - Skin Sens. 1 - H317 - Aquatic Acute 1 - H400 - Aquatic Chronic 1 - H410 1.0 – 3.0% Isopulegol CAS: 89-79-2 Classification (EC 1272/2008) - Acute Tox. 4 - H302 - Skin Irrit. 2 - H315 - Eye Irrit. 2 - H319 <3.0% Pulegone CAS: 89-82-7 Classification (EC 1272/2008) - Acute Tox. 4 - H302 <2.0% Carvone CAS: 99-49-0 Classification (EC 1272/2008) - Skin Sens. 1 - H317 <2.0% Pipertone CAS: 4573-50-6 Classification (EC 1272/2008) - Skin Irrit. 2 - H315 - Skin Sens. 1B - H317 - Eye Irrit. 2 - H319 04. FIRST AID MEASURES 4.1 Description of first aid measures Inhalation Remove to fresh air and remain in a position which is comfortable for breathing. Seek medical attention. Ingestion Do NOT induce vomiting. Ingestion may cause nausea and vomiting. Immediately rinse mouth and provide fresh air. Seek medical attention. Skin Contact Remove contaminated clothing and wash before reuse. Wash skin thoroughly with soap and water. If discomfort occurs/continues, seek medical attention. Eye Contact Rinse eyes with clean water for a minimum of fifteen minutes. If safe to do so, remove to contact lenses and continue to rinse. Seek medical attention. 4.2 Most important symptoms and effects, both acute and delayed No additional data 4.3 Indication of any immediate medical attention and special treatment needed Treat symptomatically. 05. FIRE-FIGHTING MEASURES 5.1 Extinguishing Media Carbon Dioxide, Foam, Dry Chemical Powder. Do NOT use water. 5.2 Special hazards arising from the product When heated to decomposition, it emits acrid smoke as well as carbon monoxide and carbon dioxide. 5.3 Advice for firefighters Wear self-contained respiratory equipment and chemical protective clothing at all times. 06. ACCIDENTAL RELEASE MEASURES 6.1 Personal precautions, protective equipment and emergency procedures Wear appropriate protective clothing at all times. 6.2 Environmental Precautions Do not discharge into drains, water courses or onto the ground. 6.3 Methods and material for containment and cleaning up. Absorb with inert, absorbent material. Transfer to suitable, labelled containers for disposal. Clean spillage area thoroughly with plenty of water. 6.4 Reference to other sections Section 13 07. HANDLING AND STORAGE 7.1 Precautions for safe handling Adhere to all good health, safety and hygiene practices. If handling large/heavy packages or drums, ensure the use of suitable mechanical equipment at all times. Do not eat, drink or smoke whilst handling this product. Avoid spilling, skin and eye contact. 7.2 Conditions for safe storage, including any incompatibilities Store In a cool, dry, well-ventilated area. Protect from freezing, heat and light including sunlight. Protect from all potential sources of ignition. Keep all containers tightly sealed when not in use. Keep in original containers. Storage Class – Chemical Storage 7.3 Specific end use(s) No additional data 08. EXPOSURE CONTROLS/PERSONAL PROTECTION 8.1 Control parameters No additional data 8.2 Exposure controls Protective Equipment Process Conditions No additional data Engineering Measures Install sufficient ventilation across all areas, (general and local exhaust ventilation). Install readily available eyewash stations. Respiratory Equipment In the event of airborne contamination of ventilation failure ensure the use of suitable respiratory equipment/ protection. Hand Protection Wear appropriate protective, chemically resistant gloves at all times, which comply with EN374. Eye Protection Wear appropriate protective eyewear at all times which comply with EN166. Other Protection No additional data Hygiene Measures Good hygiene practices are always recommended, especially when handling oils, chemicals or any other similar type of material. Personal Protection Use personal protection according to Directive 89/686/EEC. Skin Protection Wear appropriate protective clothing at all times to prevent any potential skin contact with this product. Environmental Exposure Controls Avoid discharging into drainage water. 09. PHYSICAL AND CHEMICAL PROPERTIES 9.1 Information on basic physical and chemical properties Appearance Liquid Colour Colourless – Pale Yellow Odour Characteristic Relative Density ~0.899 @ 20°C Flash Point (°C) 68.0 Refractive Index ~1.460 @ 20°C Melting Point (°C) No additional data Boiling Point (°C) No additional data Vapour Pressure No additional data Solubility in Water @20°C Insoluble Auto-ignition temperature (°C) No additional data 9.2 Other information No additional data 10. STABILITY AND REACTIVITY 10.1 Reactivity No additional data 10.2 Chemical stability Expected to remain stable under recommended storage conditions. 10.3 Possible hazardous reactions No additional data 10.4 Conditions to Avoid Heat for prolonged periods. 10.5 Incompatible materials Acids, Alkalis, Oxidising Agents. 10.6 Hazardous Decomposition Products In the event of thermal decomposition, oxides of carbon will be gernerated. 11. TOXOLOGICAL INFORMATION 11.1 Information on toxicological effects Acute Toxicity Harmful if swallowed. Skin corrosion / irritation Causes skin irritation. Serious eye damage / irritation Causes serious eye irritation. Respiratory or skin May cause an allergic skin reaction. sensitisation Germ Cell Mutagenicity No additional data Carcinogenicity No additional data Reproductive toxicity No additional data STOT-single exposure No additional data STOT-repeated exposure No additional data Aspiration hazard May be fatal if swallowed and enters airways. Photo-toxicity No additional data Other Information No additional data 12. ECOLOGICAL INFORMATION 12.1 Toxicity Toxic to aquatic life with long lasting effects. 12.2 Persistence & degradability No additional data 12.3 Bioaccumulation Potential No additional data 12.4 Mobility in soil No additional data 12.5 Results of PBT and vPvB Assessment Not PBT or vPvB. 12.6 Other adverse effects No additional data 13. DISPOSAL CONSIDERATIONS 13.1 Waste treatment methods Always dispose of this product in accordance with local and national regulations. Whenever safely possible, always collect spilled material. Do not allow product to enter water ways, streams, drains or any part of the environment. When handling waste, consideration should be made to the safety precautions applying to handling of the product. 14. TRANSPORT INFORMATION 14.1 UN number UN No. Road 3082 UN No. SEA 3082 UN No. AIR 3082 14.2 UN proper shipping name ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S 14.3 Transport hazard class(es) ADR/RID/ADN Class 9: Miscellaneous dangerous substances and articles. IMDG Class 9 ICAO Class/Division 9 Transport Labels 14.4 Packing group III 14.5 Environmental hazards Environmentally Hazardous Substance/Marine Pollutant 14.6 Special precautions for user EMS F-A-S-F ADR transport category 3 Emergency Action Code •3Z Hazard Identification Number (ADR/RID) 90 Tunnel Restriction Code (E) 14.7 Transport in bulk according to Annex II of MARPOL73/78 and the IBC code No additional data 15. REGULATORY INFORMATION 15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture The Chemicals (Hazard Information and Packaging for Supply) Regulations 2009 (S.I 2009 No. 716). Workplace Exposure Limits EH40. CHIP for everyone HSG (108). Regulation (EC) No 1907/2006 of the European Parliament and of the Council of 18 December 2006 concerning the Registration, Evaluation, Authorisation and Restriction of Chemicals (REACH), establishing a European Chemicals Agency, amending Directive 1999/45/EC and repealing Council Regulation (EEC) No 793/93 and Commission Regulation (EC) No 1488/94 as well as Council Directive 76/769/EEC and Commission Directives 91/155/EEC, 93/67/EEC, 93/105/EC and 2000/21/EC, including amendments. 15.2 Chemical safety assessment No additional data 16. OTHER INFORMATION Hazard Statements in Full H226 - Flammable liquid and vapour. H302 - Harmful if swallowed. H304 - May be fatal if swallowed and enters airways. H315 - Causes skin irritation. H317 - May cause an allergic skin reaction. H319 - Causes serious eye irritation. H400 - Very toxic to aquatic life. H410 - Very toxic to aquatic life with long lasting effects. H411 - Toxic to aquatic life with long lasting effects. H412 - Harmful to aquatic life with long lasting effects. Revision Date 02/11/2021 Rev No 5 DISCLAIMER: This information relates only to the specific material designated and may not be valid for such material used in combination with any other materials or in any process. Such information is, to the best of the company's knowledge and belief, accurate and reliable as of the date indicated. However, no warranty guarantee or representation is made to its accuracy, reliability or completeness. It is the user's responsibility to satisfy himself as to the suitability of such information for his own particular use. Product Name Organic Peppermint Oil Arvensis Date 15/06/2017