Morning Glory Madar Corp

MADAR Corporation Limited

Revision date : 2018-11-23

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GHS07 GHS02 GHS08 GHS09
Health risk rating 4
Safety risk rating 2
Environmental risk rating 4

Note: Ingredients listed on restricted chemical lists

EC/CAS

218-080-2

Name of the chemical

Pentyl-2-hydroxy-benzoate (40)

Concentration

0.1-<1

General Information

Version

1 (23/02/2021

Revision date

2018-11-23

Product name

Morning Glory Madar Corp

1.2.1 Relevant identified uses

Fragrances

Icons in SDS

GHS02 GHS07 GHS08 GHS09 M004 M009 M013 M017

Company Information

company name

MADAR Corporation Limited

e-mail address of the competent person responsible for the Safety Data Sheet

technical@madarcorporation.co.uk, technical@madarcorporation.co.uk

GHS Information

Signal word

Danger

Hazard Codes

Hazard statements (CLP)

H226, H304, H315, H317, H319, H400, H411

Hazard statements

Code

Statements

H226

Flammable liquid and vapour

Section 2

SECTION 2: Hazards identification

Signal word

Danger

Hazard statements

H226, Flammable liquid and vapour. H304, May be fatal if swallowed and enters airways. H315, Causes skin irritation. H317, May cause an allergic skin reaction. H319, Causes serious eye irritation. H400, Very toxic to aquatic life. H411, Toxic to aquatic life with long lasting effects.

Additional information

EUH208, Contains 1-(1,2,3,4,5,6,7,8-Octahydro-2,3,8,8-tetramethyl-2-naphthalenyl)ethanone, 2,4-Dimethyl-3-cyclohexen-1-carboxaldehyde, 2-Methyl-3-(p-isopropylphenyl)propionaldehyde, 4-tert-Butylcyclohexyl acetate, Citral, Citronellal, Coumarin, Ethyl methylphenylglycidate, Eucalyptol, Geranial, Linalyl acetate, Neral, Nerol, alpha-Hexylcinnamaldehyde, alpha-Pinene, alpha-iso-Methylionone, beta-Caryophyllene, beta-Pinene, dl-Citronellol, dl-Limonene (racemic), l-Limonene, l-Menthone, p-t-Butyl-alpha-methylhydrocinnamic aldehyde. May produce an allergic reaction.

Precautionary statements

P210, Keep away from heat, sparks, open flames and hot surfaces. - No smoking. P240, Ground/bond container and receiving equipment. P233, Keep container tightly closed. P241, Use explosion-proof electrical, ventilating and lighting equipment. P242, Use only non-sparking tools. P243, Take precautionary measures against static discharge. P261, Avoid breathing vapour or dust. P272, Contaminated work clothing should not be allowed out of the workplace. P264, Wash hands and other contacted skin thoroughly after handling. P273, Avoid release to the environment. P280, Wear protective gloves/eye protection/face protection. P301/310, IF SWALLOWED: Immediately call a POISON CENTER or doctor/physician. P303/361/353, IF ON SKIN (or hair): Remove/take off immediately all contaminated clothing. Rinse skin with water/shower. P305/351/338, IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P331, Do not induce vomiting. P333/313, If skin irritation or rash occurs: Get medical advice/attention. P337/313, If eye irritation persists: Get medical advice/attention. P362, Take off contaminated clothing and wash before reuse. P370/378, In case of fire: Use carbon dioxide, dry chemical, foam for extinction. P391, Collect spillage. P403/235, Store in a well-ventilated place. Keep cool. P405, Store locked up. 3 ( 11 ) Version: 1 P501, Dispose of contents/container to approved disposal site, in accordance with local regulations.

2.3 Other hazards

None

2.1 Classification of the substance or mixture

Classification under Regulation (EC) No 1272/2008 Class and category of Flammable Liquid, Hazard Category 3 danger: Skin Corrosion / Irritation Category 2 Eye Damage / Irritation Category 2 Sensitization - Skin Category 1 Aspiration Hazard Category 1 Hazardous to the Aquatic Environment - Acute Hazard Category 1 Hazardous to the Aquatic Environment - Long-term Hazard Category 2 H226, Flammable liquid and vapour. H304, May be fatal if swallowed and enters airways. H315, Causes skin irritation. H317, May cause an allergic skin reaction. H319, Causes serious eye irritation. H400, Very toxic to aquatic life. H411, Toxic to aquatic life with long lasting effects. 2 ( 11 ) Version: 1 2.2 Label elements Classification under Regulation (EC) No 1272/2008 Danger Signal word: Hazard statements: H226, Flammable liquid and vapour. H304, May be fatal if swallowed and enters airways. H315, Causes skin irritation. H317, May cause an allergic skin reaction. H319, Causes serious eye irritation. H400, Very toxic to aquatic life. H411, Toxic to aquatic life with long lasting effects. Supplemental EUH208, Contains 1-(1,2,3,4,5,6,7,8-Octahydro-2,3,8,8-tetramethyl-2-naphthalenyl)ethanone, Information: 2,4-Dimethyl-3-cyclohexen-1-carboxaldehyde, 2-Methyl-3-(p-isopropylphenyl)propionaldehyde, 4-tert-Butylcyclohexyl acetate, Citral, Citronellal, Coumarin, Ethyl methylphenylglycidate, Eucalyptol, Geranial, Linalyl acetate, Neral, Nerol, alpha-Hexylcinnamaldehyde, alpha-Pinene, alpha-iso-Methylionone, beta-Caryophyllene, beta-Pinene, dl-Citronellol, dl-Limonene (racemic), l-Limonene, l-Menthone, p-t-Butyl-alpha-methylhydrocinnamic aldehyde. May produce an allergic reaction. Precautionary P210, Keep away from heat, sparks, open flames and hot surfaces. - No smoking. statements: P240, Ground/bond container and receiving equipment. P233, Keep container tightly closed. P241, Use explosion-proof electrical, ventilating and lighting equipment. P242, Use only non-sparking tools. P243, Take precautionary measures against static discharge. P261, Avoid breathing vapour or dust. P272, Contaminated work clothing should not be allowed out of the workplace. P264, Wash hands and other contacted skin thoroughly after handling. P273, Avoid release to the environment. P280, Wear protective gloves/eye protection/face protection. P301/310, IF SWALLOWED: Immediately call a POISON CENTER or doctor/physician. P303/361/353, IF ON SKIN (or hair): Remove/take off immediately all contaminated clothing. Rinse skin with water/shower. P305/351/338, IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P331, Do not induce vomiting. P333/313, If skin irritation or rash occurs: Get medical advice/attention. P337/313, If eye irritation persists: Get medical advice/attention. P362, Take off contaminated clothing and wash before reuse. P370/378, In case of fire: Use carbon dioxide, dry chemical, foam for extinction. P391, Collect spillage. P403/235, Store in a well-ventilated place. Keep cool. P405, Store locked up. 3 ( 11 ) Version: 1 P501, Dispose of contents/container to approved disposal site, in accordance with local regulations. Pictograms: 2.3 Other hazards Other hazards: None Section 3. Composition / information on ingredients 3.2 Mixtures Contains: 4 ( 11 ) Version: 1 1 l-Menthone 14073-97-3 237-926-1 0.1-<1 % Skin Irrit. 2-Skin Sens. 1 B;H315-H317, - Skin Irrit. 2-Eye Dam. Nerol 106-25-2 203-378-7 0.1-<1 % 1- Eye Irrit. 2-Skin Sens. 1B;H315-H317- H318-H319,- Acute Tox. 4-Aquatic Amyl salicylate 2050-08-0 218-080-2 0.1-<1 % Acute 1-Aquatic Chronic 1;H302-H410,- Skin Irrit. 2-Skin Sens. alpha-iso-Methylionone 127-51-5 204-846-3 0.1-<1 % 1 B-Aquatic Chronic 2; H315-H317-H411,- Substances with Community workplace exposure limits: Not Applicable Substances that are persistent, bioaccumulative and toxic or very persistent and very bioaccumulative, greater than 0.1%: Not Applicable Section 4. First-aid measures 4.1 Description of first aid measures Inhalation: Remove from exposure site to fresh air, keep at rest, and obtain medical attention. Eye exposure: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Skin exposure: IF ON SKIN (or hair): Remove/take off immediately all contaminated clothing. Rinse skin with water/shower. Ingestion: IF SWALLOWED: Immediately call a POISON CENTER or doctor/physician. 4.2 Most important symptoms and effects, both acute and delayed May be fatal if swallowed and enters airways. Causes skin irritation. May cause an allergic skin reaction. Causes serious eye irritation. 4.3 Indication of any immediate medical attention and special treatment needed None expected, see Section 4.1 for further information. SECTION 5: Firefighting measures 5.1 Extinguishing media Suitable media: Carbon dioxide, Dry chemical, Foam. 5.2 Special hazards arising from the substance or mixture In case of fire, may be liberated: Carbon monoxide, Unidentified organic compounds. 1 5.3 Advice for fire fighters: In case of insufficient ventilation, wear suitable respiratory equipment. Section 6. Accidental release measures 6.1 Personal precautions, protective equipment and emergency procedures: Avoid inhalation. Avoid contact with skin and eyes. See protective measures under Section 7 and 8. 6.2 Environmental precautions: Keep away from drains, surface and ground water, and soil. 6.3 Methods and material for containment and cleaning up: Remove ignition sources. Provide adequate ventilation. Avoid excessive inhalation of vapours. Contain spillage immediately by use of sand or inert powder. Dispose of according to local regulations. 6.4 Reference to other sections: Also refer to sections 8 and 13. Section 7. Handling and storage 7.1 Precautions for safe handling: Keep away from heat, sparks, open flames and hot surfaces. - No smoking. 7.2 Conditions for safe storage, including any incompatibilities: Ground/bond container and receiving equipment. Use only non-sparking tools. Take precautionary measures against static discharge. 7.3 Specific end use(s): Fragrances: Use in accordance with good manufacturing and industrial hygiene practices. Section 8. Exposure controls/personal protection 8.1 Control parameters Workplace exposure limits: Not Applicable 8.2 Exposure Controls Eye / Skin Protection Wear protective gloves/eye protection/face protection Respiratory Protection 7 ( 11 ) Version: 1 Under normal conditions of use and where adequate ventilation is available to prevent build up of excessive vapour, this material should not require special engineering controls. However, in conditions of high or prolonged use, or high temperature or other conditions which increase exposure, the following engineering controls can be used to minimise exposure to personnel: a) Increase ventilation of the area with local exhaust ventilation. b) Personnel can use an approved, appropriately fitted respirator with organic vapour cartridge or canisters and particulate filters. c) Use closed systems for transferring and processing this material. Also refer to Sections 2 and 7. Section 9. Physical and chemical properties 9.1 Information on basic physical and chemical properties Appearance: Clear yellow Odour: Not determined Odour threshold: Not determined pH: Not determined Melting point / freezing point: Not determined Initial boiling point / range: Not determined Flash point: 44< °C Evaporation rate: Not determined Flammability (solid, gas): Not determined Upper/lower flammability or explosive limits: Product does not present an explosion

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