METHYL CINNAMATE

Hazard statements (CLP)

H317

Code

Statements

H317

May cause an allergic skin reaction

SECTION 2: Hazards identification

Classification of the substance or mixture Skin sensitizer -Category 1B - H317

Signal word

Warning

Hazard statements

H317 -May cause an allergic skin reaction.

Precautionary statements

P261 -Avoid breathing dust/fume/gas/mist/vapours/spray. P272 -Contaminated work clothing should not be allowed out of the workplace. P280 -Wear protective gloves/protective clothing/eye protection/face protection. P302+P352+P333+P3l3 - IF ON SKIN Wash with plenty of soap and water. If skin Irritation or rash occurs Get medical advice/attention P362+P364 -Take off contaminated clothing and wash it before reuse. P501 - Dispose of contents/container according to local legislation.

Supplemental label elements

Contains METHYL CINNAMATE. May produce an allergic reaction.

2.3 Other hazards

Product not containing any component that meets the criteria for PBT or vPvB according to Regulation (EC) 1907 /2006, Annex XIII. Product not containing any component identified as having endocrine disrupting properties according to Regulation (EU) 2017/2100.

2.1 Classification of the substance or mixture

Skin sensitizer -Category 1B - H317 2.2. Label Elements Hazard pictograms: Signal Word: Warning Hazard statements: H317 -May cause an allergic skin reaction. Precautionary statements: P261 -Avoid breathing dust/fume/gas/mist/vapours/spray. P272 -Contaminated work clothing should not be allowed out of the workplace. P280 -Wear protective gloves/protective clothing/eye protection/face protection. P302+P352+P333+P3l3 - IF ON SKIN: Wash with plenty of soap and water. If skin Irritation or rash occurs: Get medical advice/attention. P362+P364 -Take off contaminated clothing and wash it before reuse. P501 - Dispose of contents/container according to local legislation. Suplemental Hazard Information: Contains METHYL CINNAMATE. May produce an allergic reaction. 2.3. Other hazards Product not containing any component that meets the criteria for PBT or vPvB according to Regulation (EC) 1907 /2006, Annex XIII. Product not containing any component identified as having endocrine disrupting properties according to Regulation (EU) 2017/2100. SECTION 3. COMPOSITION/INFORMATION ON INGREDIENTS 3.1. Substances Chemical name: METHYL CINNAMATE CASnumber. 103-26-4 EC number: 203-093-8 BRAZIL • CHINA • COLOMBIA • INDIA • MEXICO • SIN.G • SPAIN • USA • hitp://www.ventos.com Hazardous constituents: CASNo. Classification according to Chemical Name Specific Concentration Limit, o/o(w/w) EC No. Regulation 1272/2008 M-factor, ATE, SVHC Index No. METHYL CINNAMATE 103-26-4 Skin Sens. 1B- H317 ATE (oral): 2610 mg/kg 50 203-093-8 See the full text of the hazard statements in section 16. 3.2. Mixtures Not applicable. SECTION 4. FIRST-AID MEASURES 4.1. Description of necessary first aid measures Ingestion: Rinse mouth with water. Obtain medical advice. Keep at rest. Do not induce vomiting. Eye contact: In case of contact with eyes, rinse immediately with plenty of water for at least 15 minutes and seek medical advice. Inhalation: Remove person to fresh air and keep at rest. Seek immediate medical advice. Skin contact: Take off immediately all contaminated clothing. Thoroughly wash affected skin with soap and water. Seek medical attention if symptoms persist 4.2. Most important symptoms and effects, both acute and dela.yed No information available. 4.3. Indication of any immediate medical attention and special treatment needed No information available. SECTION 5. FIRE-FIGHTING MEASURES S.1. Extinguishing Media Water spray, carbon dioxide, dry chemical powder or appropriate foam. For safety reasons do not use full water jet. 5.2. Special hazards arising from the substance or mixture Known or Anticipated Hazardous Products of Combustion: Emits toxic fumes under fire conditions. S.3. Advice for firefighters High temperatures can lead to high pressures inside closed containers. Avoid inhalation of vapors that are created. Use appropriate respiratory protection. Do not allow spillage of fire to be poured into drains or watercourses. Wear self-contained breathing apparatus and protective clothing. SECTION 6. ACCIDENTAL RELEASE MEASURES 6.1. Personal precautions, protective equipment and emergency procedures Evacuate surronding areas. Ensure adequate ventilation. Keep unnecessary and unprotected personnel from entering. Do not breathe vapor/spray. Avoid contact with skin and eyes. Information regarding personal protective measures: see section 8. 6.2. Environmental precautions To avoid possible contamination of the environment, do not discharge into any drains, surface waters or groundwaters. 6.3. Methods and materials for containment and cleaning up Cover with an inert, inorganic, non-combustible absorbent material (e.g. dry-lime, sand, soda ash). Place in covered containers using non-sparking tools and transport outdoors. Avoid open flames or sources of ignition (e.g. pilot lights on gas hot water heater). Ventilate area and wash spill site after material p.ickup is complete. 6.4. Reference to other sections Information regarding exposure controls, personal protection and disposal considerations can be found in sections 8 and 13. SECTION 7. HANDLING AND STORAGE 7.1. Precautions for safe handling Do not store or handle this material near food or drinking water. Do not smoke. Avoid contact with the eyes, skin and clothing. Wear protective clothing and use glasses. Observe the rules of safety and hygiene at work. Keep in the original container or an alternative made from a compatible material. 7.2. Conditions for safe storage, including any incompatibilities Store in tightly closed and preferably full containers in a cool, dry and ventilated area, protected from light. Keep away from sources of ignition (e.g. hot surfaces, sparks, flame and static discharges). Keep away from incompatible materials (see section 10). 7.3. Specific end use(s) No information available. SECTION 8. EXPOSURE CONTROLS AND PERSONAL PROTECTION 8.1. Control parameters Components with occupational exposure limits: None known. 8.2. Exposure controls Appropriate engineering controls: Measures should be taken to prevent materials from being splashed into the body. Provide adequate ventilation, according to the conditions of use. Use a mechanical exhaust if required. Eye/Face protection: Chemical safety goggles are recommended. Wash contaminated goggles before reuse .. Hand Protection: Chemical-resistant gloves are recommended. Wash contaminated gloves before reuse. Body protection: Personal protective equipment for the body should be selected based on the task beiAg performed and the risks involved. Respiratory Protection: In case of insufficient ventilation, use suitable respiratory equipment. Environmental exposure controls: Emissions from ventilation or process equipment should be checked to ensure they comply with environntal protection legislation. In some cases, filters or engineering modifications to the process equipment will be necessary to reduce emissions to acceptable levels. SECTION 9. PHYSICAL AND CHEMICAL PROPERTIES 9.1. Information on basic physical and chemical properties Physical sate: Liquid/solid Colour: Conforms to standard Odour: Conforms to standard Melting point/freezing point 33 .. 37 Boiling point or initial boiling point and range (0C): 262°C (1013 mbar) Flammability: Not determined Lower and upper explosion limit Not determined Flash point: 123 °c Auto-ignition temperature: Not determined Decomposition temperature: Not determined pH: Not determined Kinematic viscosity: Not determined Solubility: SOLUBILITY IN WATER: 299 mg/I (20"C)/SOLUBt.E 1:1 W/V IN ETHANOL 80% Partition coefficient n-octanol/water (log value): LOGPOW2,6 Vapour pressure: < 0,1 mbar (20°C) Density and/or relative density: I Relative vapour density: 5,5(AIR= l) Particle characteristics: Not determined 9.2. Other information 9.2.1. Information with regard to phyical hazard classes: No information avaliable. 9.2.2. Other safety characteristics: No information avaliable SECTION 10. STA BILITY A ND REA CTIVITY 10.1. Reactivity No hazardous reactions if stored and handled as prescribed/indicated. 10.2. Chemical stability The product is stable if stored and handled as prescribed/indicated. 10.3. Possibility of hazardous reactions No hazardous reactions if stored and handled as prescribed/indicated. 10.4. Conditions to A void Conditions to Avoid: Excessive heat, flame or other ignition sources. 10.s. Incompatible materials Avoid contact with strong acids and bases and oxidizing agents. 10.6. Hazardous decomposition products During combustion may form carbon monoxide and unidentified organic compounds. SECTION 11. T OXICOLOGICAL INFORMATION 11.1. Information on hazard classes as defined in Regulation (EC) No 1272/2008 Based on the data available, the criteria for classification are not met. Acute toxicity Based on the data available, the criteria for classification are not met. Skin corrosion/Irritation Based on the data available, the criteria for classification are not met. Serious eye damage/irritation May cause an allergic skin reaction. Respiratory or skin sensitisation Germ cell mutagenicity Based on the data available, the criteria for classification are not met. Carcinogenicity Based on the data available, the criteria for classification are not met. Reproductive toxicity Based on the data available, the criteria for classification are not met. STOT-single exposure Based on the data available, the criteria for classification are not met. STOT-repeated exposure Aspiration hazard Based on the data available, the criteria for classification are not met. 11.2. Information on other hazards 11.2.1. Endocrine disrupting properties: Product not containing any component identified as having endocrine disrupting properties according to Regulation (EU) 2017 /2100. 11.2.2. Other information: No information available SECTION 12. ECOLOGICAL INFORMATION 12.1. Toxicity Assessment: Based on the data available, the criteria for classification are not met. ExperimentaVcalculated data: No information available. 12.2. Persistence and degradability The product is readily biodegradable 12.3. Bioaccumulative potential No information available. 12.4. Soil mobility No information available. 12.s. Results of PBT and vPvB assessment Product not containing any component that meets the criteria for PBT or vPvB according to Regulation [EC) 1907 /2006, Annex XIII. 12.6. Endocrine disrupting properties Product not containing any component identified as having endocrine disrupting properties according to Regulation (EU) 2017 /2100. 12.7. Other adverse effects See also sections 6, 7, 13 and 15 Do not allow to get into waste water or waterways. SECTION 13. DISPOSAL CONSIDERATIONS 13.1. Waste treatment methods Dispose of in accordance with national and local environmental regulations. SECTION 14: TRANSPORT INFORMATION ADR/RID/ADN IMDG IATA-ICAO 14.1. UN Number Not classified as hazardous goods Not classified as-hazardous goods Not classified as hazardous goods 14.2. UN Proper Shipping Name Not applicable 14.3. Transport Hazard Class(es) Not applicable 14.4. Packing Group Not applicable 14.5. Environmental hazards No Additional information 14.6 Special precautions for user None known 14. 7. Maritime transport in bulk according to IMO instruments No information available SECTION 15: REGULATORY INFORMATION 15.1. Safety, health and environmental regulations/legislation specific for the substance or mixture WGK:WGKI 15.2. Chemical safety assessment No chemical safety assessment has been carried out for the substance or mixture by the supplier SECTION 16: OTHER INFORMATION Full text of the R-phrases, hazard statements and precautionary statements mentioned in sectiot1 3: H317 - May cause an allergic skin reaction. SPECIFICATION SHEET PRODUCT METHYL CINNAMATE IUPAC NAME SYNONYMS METHYL CINNAMATE METHYL 3-PHENYLPROPENOATE FORMULA MOLECULAR WEIGHT C10 Hm 02 CAS 162 ,19 CAS 2 103-26-4 EINECS 1754-62-7 FEMA 203-093-8 TARIFF NUMBER 2698 2916399090 SPECIFICATIONS VERSION 5 VERSION DATE 19/09/22 ASPECT AT 20°C LIQUID/ SOLID COLOUR WHITE OR SLIGHTLY YELLOW ODOUR SWEET, BALSAMIC WITH FRUITY NUANCES TASTE FRUITY, STRAWBERRY-LIKE DENSITY AT 20°C (g / ml) DENSITY 25/25 REFRACTIVE INDEX nD20 REFRACTIVE INDEX nD25 OPTICAL ROTATION (0) I BOILING POINT (0C) 262 °C (1013 mbar) MELTING POINT (0C) 33 - 37 FLASH POINT (0C) 123 ASSAY(o/oGC) >98 ACID VALUE (mg KOH/g) <1 SOLUBILITY SOLUBILITY IN WATER: 299 mg/I (20 °() VAPOUR PRESSURE <0,1 mbar(20°C} OTHER SOLUBILITIES SOLUBLE 1:1 W/V IN ETHANOL 80% OTHER TECHNICAL DATA THIS SUBSTANCE CAN POLYMERIZE, PROCESS WHICH IS FAVOURED BY REPEATED MELTING. IT IS WISE TO DO A SOLUBILITY TEST 1:10 IN ETHANOL 96 BEFORE USING. AND STOCKING IT IN ° THE HOT CHAMBER AFTER BEING MELTED. STABILITY AND STORAGE KEEP IN TIGHTLY CLOSED CONTAINER IN A COO L AND DRY PLACE, PROTECTED FROM LIGHT. WHEN STORED FOR MORE THAN 9 MONTHS, QUAL­ ITY SHOULD BE CHECKED BEFORE USE. DO SOLUBILITY TEST ETHANOL 96 BEFORE USING. IT MAY CONTAIN 0,05% OF ALPHA-TOCOPHEROL. ° WE BELIEVE THE ABOVE INFORMATION TO BE CORRECT BUT WE DO NOT PR ESENT IT AS ALL INCLUSIVE AND AS SUCH SHOULD BE.USED AS A GUIDE. IT IS THE SOLE RESPONSIBILITY OF THE RECEIV-ER OF OUR PRODUCT TO COMPLY WITH-EXISTING REGULATIONS ANO INSTRUCTIONS. THIS PRODUCT HAS NOT BEEN FILTERED DUE TO TECHNICAL REASONS. WE RECOMMEND NOTTO USE IT UNLESS FILTERED WHEN USED ASA RAW MATERIAL IN FOOD INTENDED FOR FINAL CONSUMERS. VEGAN 05 February 2025 Product: METHYL CINNAMATE This is to certify that, to the best of our knowledge, the above-mentioned material is suitable for the following diets: [Z] Vegan Does not contain any ingredient of animal origin (mammalian, poultry, fish, crustacean, mollusc) or animal derivatives (dairy, egg and bee products) including additives and processing aids. In addition, we confirm that it complies with the requirements listed on the Criteria of the V-label: Regulations, that can be found in Annex1: Criteria for the V-Label [Z] Vegetarian Does not contain any ingredient of animal origin (mammalian, poultry, fish, crustacean, mollusc) or dairy and egg products, including additives and processing aids. Bee products (e.g. honey, bees wax) are acceptable. [Z] Ovo-Lacto Vegetarian Does not contain any ingredient of animal origin (mammalian, poultry, fish, crustacean, mollusc), including additives and processing aids. Dairy, egg and bee products (e.g. honey, bees wax) are acceptable. 'Animal' refers to the entire animal kingdom, i.e. vertebrates and multicellular invertebrates. The informabon indicated above corresponds to our knowledge at the date of issue. This document is electronically generated and therefore 11 is not signed