LEMON, ESSENTIAL OIL ORGANIC

Hazard statements (CLP)

H226, H304, H315, H317, H361, H410, H411

Code

Statements

H226

Flammable liquid and vapour

SECTION 2: Hazards identification

Regulation (EC) No. 1272/2008 CLASSIFICATION OF THE SUBSTANCE OR MIXTURE THE FULL TEXT FOR ALL HAZARD STATEMENTS IS DISPLAYED IN SECTION 16 CLASSIFICATION (67/548/EEC) NO ADDITIONAL DATA AVAILABLE FLAMMABLE LIQUID, HAZARD CATEGORY 3 SKIN CORROSION / IRRITATION CATEGORY 2 SENSITIZATION - SKIN CATEGORY 1 TOXIC TO REPRODUCTION CATEGORY 2 ASPIRATION HAZARD CATEGORY 1 HAZARDOUS TO THE AQUATIC ENVIRONMENT - ACUTE HAZARD CATEGORY 1 HAZARDOUS TO THE AQUATIC ENVIRONMENT - LONG-TERM HAZARD CATEGORY 1 CLASSIFICATION (EU1272/2008) HAZARDOUS TO THE AQUATIC ENVIRONMENT - LONG-TERM HAZARD CATEGORY 2 H226, FLAMMABLE LIQUID AND VAPOUR H304, MAY BE FATAL IF SWALLOWED AND ENTERS AIRWAYS H315, CAUSES SKIN IRRITATION H317, MAY CAUSE AN ALLERGIC SKIN REACTION H361, SUSPECTED OF DAMAGING FERTILITY OR THE UNBORN CHILD (EXPOSURE ROUTE) H410, VERY TOXIC TO AQUATIC LIFE WITH LONG LASTING EFFECTS H411, TOXIC TO AQUATIC LIFE WITH LONG LASTING EFFECTS

2.2 Label elements

GHS02 GHS07 GHS08 GHS09

Signal word

DANGER.

Contains

D-LIMONENE, BETA-PINENE, GAMMA-TERPINENE, PINENE ALPHA, LAEVO H226, FLAMMABLE LIQUID AND VAPOUR. H304, MAY BE FATAL IF SWALLOWED AND ENTERS AIRWAYS. H315, CAUSES SKIN IRRITATION.

Hazard statements

H317, MAY CAUSE AN ALLERGIC SKIN REACTION. H361, SUSPECTED OF DAMAGING FERTILITY OR THE UNBORN CHILD (EXPOSURE ROUTE). H410, VERY TOXIC TO AQUATIC LIFE WITH LONG LASTING EFFECTS. H411, TOXIC TO AQUATIC LIFE WITH LONG LASTING EFFECTS. P202, DO NOT HANDLE UNTIL ALL SAFETY PRECAUTIONS HAVE BEEN READ AND UNDERSTOOD. P210, KEEP AWAY FROM HEAT, SPARKS, OPEN FLAMES AND HOT SURFACES. - NO SMOKING. P233, KEEP CONTAINER TIGHTLY CLOSED. P240, GROUND/BOND CONTAINER AND RECEIVING EQUIPMENT. P241, USE EXPLOSION-PROOF ELECTRICAL, VENTILATING AND LIGHTING EQUIPMENT. P242, USE ONLY NON-SPARKING TOOLS. P243, TAKE PRECAUTIONARY MEASURES AGAINST STATIC DISCHARGE. P261, AVOID BREATHING VAPOUR OR DUST. P264, WASH HANDS AND OTHER CONTACTED SKIN THOROUGHLY AFTER HANDLING. P272, CONTAMINATED WORK CLOTHING SHOULD NOT BE ALLOWED OUT OF THE WORKPLACE. P273, AVOID RELEASE TO THE ENVIRONMENT. P280, WEAR PROTECTIVE GLOVES/EYE PROTECTION/FACE PROTECTION.

Precautionary statements

P301/310, IF SWALLOWED: IMMEDIATELY CALL A POISON CENTER OR DOCTOR/PHYSICIAN. P303/361/353, IF ON SKIN (OR HAIR): REMOVE/TAKE OFF IMMEDIATELY ALL CONTAMINATED CLOTHING. RINSE SKIN WITH WATER/SHOWER. P308/313, IF EXPOSED OR CONCERNED: GET MEDICAL ADVICE/ATTENTION. P331, DO NOT INDUCE VOMITING. P333/313, IF SKIN IRRITATION OR RASH OCCURS: GET MEDICAL ADVICE/ATTENTION. P362, TAKE OFF CONTAMINATED CLOTHING AND WASH BEFORE REUSE. P370/378, IN CASE OF FIRE: USE CARBON DIOXIDE, DRY CHEMICAL, FOAM FOR EXTINCTION. P391, COLLECT SPILLAGE. P403/235, STORE IN A WELL-VENTILATED PLACE. KEEP COOL. P405, STORE LOCKED UP. P501, DISPOSE OF CONTENTS/CONTAINER TO APPROVED DISPOSAL SITE, IN ACCORDANCE WITH LOCAL REGULATIONS. NO DATA

Further information

RISK & SAFETY PHRASES IN FULL

2.3 Other hazards

ADVERSE PHYSIO-CHEMICAL PROPERTIES HYDROCARBON CONCENTRATION %: 96.0000 ADVERSE EFFECTS ON HUMAN HEALTH PBT OR VPVB ACCORDING TO ANNEX XIII OF NO DATA

2.1 Classification of the substance or mixture

CLASSIFICATION OF THE SUBSTANCE OR MIXTURE THE FULL TEXT FOR ALL HAZARD STATEMENTS IS DISPLAYED IN SECTION 16. CLASSIFICATION (67/548/EEC) NO ADDITIONAL DATA AVAILABLE. FLAMMABLE LIQUID, HAZARD CATEGORY 3 SKIN CORROSION / IRRITATION CATEGORY 2 SENSITIZATION - SKIN CATEGORY 1 TOXIC TO REPRODUCTION CATEGORY 2 ASPIRATION HAZARD CATEGORY 1 HAZARDOUS TO THE AQUATIC ENVIRONMENT - ACUTE HAZARD CATEGORY 1 HAZARDOUS TO THE AQUATIC ENVIRONMENT - LONG-TERM HAZARD CATEGORY 1 CLASSIFICATION (EU1272/2008) HAZARDOUS TO THE AQUATIC ENVIRONMENT - LONG-TERM HAZARD CATEGORY 2 H226, FLAMMABLE LIQUID AND VAPOUR. H304, MAY BE FATAL IF SWALLOWED AND ENTERS AIRWAYS. H315, CAUSES SKIN IRRITATION. H317, MAY CAUSE AN ALLERGIC SKIN REACTION. H361, SUSPECTED OF DAMAGING FERTILITY OR THE UNBORN CHILD (EXPOSURE ROUTE). H410, VERY TOXIC TO AQUATIC LIFE WITH LONG LASTING EFFECTS. H411, TOXIC TO AQUATIC LIFE WITH LONG LASTING EFFECTS 2.2 LABEL ELEMENTS LABEL IN ACCORDANCE WITH REGULATION (EC) NO 1272/2008. GHS LABEL GHS02 GHS07 GHS08 GHS09 SIGNAL WORD DANGER. CONTAINS D-LIMONENE, BETA-PINENE, GAMMA-TERPINENE, PINENE ALPHA, LAEVO H226, FLAMMABLE LIQUID AND VAPOUR. H304, MAY BE FATAL IF SWALLOWED AND ENTERS AIRWAYS. H315, CAUSES SKIN IRRITATION. HAZARDS STATEMENT H317, MAY CAUSE AN ALLERGIC SKIN REACTION. H361, SUSPECTED OF DAMAGING FERTILITY OR THE UNBORN CHILD (EXPOSURE ROUTE). H410, VERY TOXIC TO AQUATIC LIFE WITH LONG LASTING EFFECTS. H411, TOXIC TO AQUATIC LIFE WITH LONG LASTING EFFECTS. P202, DO NOT HANDLE UNTIL ALL SAFETY PRECAUTIONS HAVE BEEN READ AND UNDERSTOOD. P210, KEEP AWAY FROM HEAT, SPARKS, OPEN FLAMES AND HOT SURFACES. - NO SMOKING. P233, KEEP CONTAINER TIGHTLY CLOSED. P240, GROUND/BOND CONTAINER AND RECEIVING EQUIPMENT. P241, USE EXPLOSION-PROOF ELECTRICAL, VENTILATING AND LIGHTING EQUIPMENT. P242, USE ONLY NON-SPARKING TOOLS. P243, TAKE PRECAUTIONARY MEASURES AGAINST STATIC DISCHARGE. P261, AVOID BREATHING VAPOUR OR DUST. P264, WASH HANDS AND OTHER CONTACTED SKIN THOROUGHLY AFTER HANDLING. P272, CONTAMINATED WORK CLOTHING SHOULD NOT BE ALLOWED OUT OF THE WORKPLACE. P273, AVOID RELEASE TO THE ENVIRONMENT. P280, WEAR PROTECTIVE GLOVES/EYE PROTECTION/FACE PROTECTION. PRECAUTIONARY STATEMENTS P301/310, IF SWALLOWED: IMMEDIATELY CALL A POISON CENTER OR DOCTOR/PHYSICIAN. P303/361/353, IF ON SKIN (OR HAIR): REMOVE/TAKE OFF IMMEDIATELY ALL CONTAMINATED CLOTHING. RINSE SKIN WITH WATER/SHOWER. P308/313, IF EXPOSED OR CONCERNED: GET MEDICAL ADVICE/ATTENTION. P331, DO NOT INDUCE VOMITING. P333/313, IF SKIN IRRITATION OR RASH OCCURS: GET MEDICAL ADVICE/ATTENTION. P362, TAKE OFF CONTAMINATED CLOTHING AND WASH BEFORE REUSE. P370/378, IN CASE OF FIRE: USE CARBON DIOXIDE, DRY CHEMICAL, FOAM FOR EXTINCTION. P391, COLLECT SPILLAGE. P403/235, STORE IN A WELL-VENTILATED PLACE. KEEP COOL. P405, STORE LOCKED UP. P501, DISPOSE OF CONTENTS/CONTAINER TO APPROVED DISPOSAL SITE, IN ACCORDANCE WITH LOCAL REGULATIONS. NO DATA SUPPLEMENTARY PRECAUTIONARY STATEMENTS SECTION 16 (OTHER INFORMATION): RISK & SAFETY PHRASES IN FULL. 2.3 OTHER HAZARDS ADVERSE PHYSIO-CHEMICAL PROPERTIES HYDROCARBON CONCENTRATION %: 96.0000 ADVERSE EFFECTS ON HUMAN HEALTH NO DATA PBT OR VPVB ACCORDING TO ANNEX XIII NO DATA SECTION 3: COMPOSITION OF INGREDIENTS 50 - 100 % D-LIMONENE CAS-NO: 5989-27-5; EC NO.: 227-813-5 3.2 MIXTURES CLASSIFICATION (EC 1272/2008) FLAM. LIQ. 3-SKIN IRRIT. 2-SKIN SENS. 1B-ASP. TOX 1-AQUATIC ACUTE 1- AQUATIC CHRONIC 1; H226-H304-H315- H317-H410,-, M FACTOR (ACUTE) = 1. M FACTOR (CHRONIC) = 1 5 - <10 % BETA-PINENE CAS NO: 127-91-3 EC NO: - CLASSIFICATION (EC 1272/2008) FLAM. LIQ. 3-SKIN IRRIT. 2-SKIN SENS. 1B-ASP. TOX 1-AQUATIC ACUTE 1- AQUATIC CHRONIC 1; H226-H304-H315- H317-H410,-, M=1 5-<10 % GAMMA-TERPINENE CAS NO: 99-85-4 EC NO: - CLASSIFICATION (EC 1272/2008) FLAM. LIQ. 3-REPR. 2- ASP. TOX 1;H226-H304- H361,-, ORAL: ATE = 3850 MG/KG BW 1 - <5% MYRCENE CAS NO: 123-35-3 EC NO: - CLASSIFICATION (EC 1272/2008) FLAM. LIQ. 3-SKIN IRRIT. 2-EYE IRRIT. 2-ASP. TOX 1-AQUATIC ACUTE 1- AQUATIC CHRONIC 2; H226-H304-H315- H319-H400-H411,-, M=1 0.1 – <1% NERYL ACETATE CAS NO: 141-12-8 EC NO: - CLASSIFICATION (EC 1272/2008) SKIN SENS. 1B (H317) 1 -<5% ALPHA-PINENE CAS NO: 80-56-8 EC NO: - CLASSIFICATION (EC 1272/2008) FLAM. LIQ. 3-ACUTE TOX. 4-SKIN IRRIT. 2-SKIN SENS. 1B-ASP. TOX 1- AQUATIC ACUTE 1- AQUATIC CHRONIC 1; H226-H302-H304- H315-H317-H410,-, M = 1-ORAL: ATE = 500 MG/KG BW 0.1 - <1% GERANYL ACETATE CAS NO: 105-87-3 EC NO: - CLASSIFICATION (EC 1272/2008) SKIN IRRIT. 2-SKIN SENS. 1B-AQUATIC CHRONIC 3; H315-H317-H412,- 0.1 -<1% LINALOOL CAS NO: 78-70-6 EC NO: - CLASSIFICATION (EC 1272/2008) SKIN IRRIT. 2-EYE IRRIT. 2- SKIN SENS. 1B;H315- H317-H319,-, ORAL: ATE = 2790 MG/KG BW 0.1-<1% TERPINOLENE CAS NO: 586-62-9 EC NO: - CLASSIFICATION (EC 1272/2008) FLAM. LIQ. 3-SKIN SENS. 1B-ASP. TOX 1-AQUATIC ACUTE 1-AQUATIC CHRONIC 1;H226-H304- H317-H410,-, M = 1-ORAL: ATE = 3775 MG/KG BW 0.1 -<1% BETA-CARYOPHYLLENE CAS NO: 87-44-5 EC NO: - CLASSIFICATION (EC 1272/2008) SKIN SENS. 1B-ASP. TOX 1-AQUATIC CHRONIC 4;H304-H317-H413,- 0.1 -<1% PARA-CYMENE CAS NO: 99-87-6 EC NO: - CLASSIFICATION (EC 1272/2008) FLAM. LIQ. 3-REPR. 2- ASP. TOX 1-AQUATIC CHRONIC 2;H226-H304- H361-H411,-, ORAL: ATE = 4750 MG/KG BW 0.1 - <1% GERANIOL CAS NO: 106-24-1 EC NO: - CLASSIFICATION (EC 1272/2008) SKIN IRRIT. 2-EYE IRRIT. 2- SKIN SENS. 1B;H315- H317-H319,-, DERMAL: ATE = 2250 MG/KG BW 0.1 -<1% CIS-ALPHA-BISABOLENE CAS NO : 29837-07-8 EC NO : - CLASSIFICATION (EC 1272/2008) SKIN IRRIT. 2-SKIN SENS. 1B-ASP. TOX 1;H304- H315-H317,- 0.1 - <1% NERAL CAS NO : 106-26-3 EC NO : 203-379-2 CLASSIFICATION (EC 1272/2008) SKIN IRRIT. 2-EYE IRRIT. 2- SKIN SENS. 1B;H315- H317-H319,-, DERMAL: ATE = 2250 MG/KG BW SECTION 4: FIRST AID MEASURES 4.1 DESCRIPTION OF FIRST AID MEASURES GENERAL INFORMATION ALWAYS REMOVE CONTAMINATED CLOTHING IMMEDIATELY. IMMEDIATE MEDICAL ATTENTION IS NOT REQUIRED. IF SYMPTOMS PERSIST, CALL A PHYSICIAN. MOVE TO INHALATION FRESH AIR IN CASE OF ACCIDENTAL INHALATION OF VAPORS OR DECOMPOSITION PRODUCTS. CLEAN MOUTH WITH WATER AND DRINK AFTERWARDS PLENTY OF WATER. NEVER GIVE ANYTHING BY MOUTH INGESTION TO AN UNCONSCIOUS PERSON. CALL A PHYSICIAN. DO NOT INDUCE VOMITING. SKIN CONTACT REMOVE CONTAMINATED CLOTHES. WASH THOROUGHLY WITH SOAP AND WATER. CONTACT PHYSICIAN IF IRRITATION PERSISTS. EYE CONTACT FLUSH IMMEDIATELY WITH WATER FOR AT LEAST 15 MINUTES. CONTACT PHYSICIAN IF SYMPTOMS PERSIST. 4.2 MAY BE FATAL IF SWALLOWED AND ENTERS AIRWAYS. CAUSES SKIN IRRITATION. MOST IMPORTANT SYMPTOMS & EFFECTS (ACUTE & MAY CAUSE AN ALLERGIC SKIN REACTION. DELAYED) SUSPECTED OF DAMAGING FERTILITY OR THE UNBORN CHILD (EXPOSURE ROUTE). 4.3 INDICATION OF ANY IMMEDIATE MEDICAL ATTENTION OR TREAT SYMPTOMATICALLY. SPECIAL TREATMENT REQUIRED SECTION 5: FIRE FIGHTING MEASURES 5.1 FOAM, CO2, DRY CHEMICAL POWDER. EXTINGUISHING MATERIAL 5.2 SPECIAL HAZARDS ARISING FROM THE SUBSTANCE OR BURNING PRODUCES IRRITATING, TOXIC AND OBNOXIOUS FUMES MIXTURE 5.3 SPECIAL PROTECTIVE EQUIPMENT FOR FIRE-FIGHTERS: ADVICE FOR FIRE-FIGHTERS WEAR POSITIVE-PRESSURE SELF-CONTAINED BREATHING APPARATUS (SCBA) AND APPROPRIATE PROTECTIVE CLOTHING. SECTION 6: ACCIDENTAL RELEASE MEASURES 6.1 ENSURE ADEQUATE VENTILATION OF THE WORKING AREA, EVACUATE PERSONNEL TO SAFE AREA, WEAR SUITABLE PROTECTIVE PERSONAL PRECAUTIONS EQUIPMENT. NO SMOKING, SPARKS, FLAMES OR OTHER SOURCES OF IGNITION NEAR SPILLAGE. AVOID CONTACT WITH SKIN, EYES AND CLOTHING. 6.2 DO NOT DISCHARGE INTO DRAINS, WATER COURSES OR ONTO THE GROUND. DISPOSE OF IN LINE WITH LOCAL AUTHORITY ENVIRONMENTAL PRECAUTIONS GUIDELINES. 6.3 METHODS & MATERIAL FOR CONTAINMENT AND CLEANING REMOVE IGNITION SOURCES. PROVIDE ADEQUATE VENTILATION. AVOID EXCESSIVE INHALATION OF VAPOURS. CONTAIN UP SPILLAGE IMMEDIATELY BY USE OF SAND OR INERT POWDER. DISPOSE OF ACCORDING TO LOCAL REGULATIONS. 6.4 REFER & CONSIDER SECTION 8. REFERENCES TO OTHER SECTIONS REFER & CONSIDER SECTION 13. SECTION 7: HANDLING & STORAGE HANDLE IN ACCORDANCE WITH GOOD HYGIENE AND SAFETY PRACTICE. KEEP AWAY FROM HEAT, SPARKS, OPEN FLAMES AND 7.1 HOT SURFACES. - NO SMOKING. USE PERSONAL PROTECTIVE EQUIPMENT AS REQUIRED. USE IN ACCORDANCE WITH GOOD PRECAUTIONS FOR SAFE-HANDLING MANUFACTURING AND INDUSTRIAL HYGIENE PRACTICES. USE IN AREAS WITH ADEQUATE VENTILATION DO NOT EAT, DRINK OR SMOKE WHEN USING THIS PRODUCT. 7.2 KEEP THE PRODUCT CONTAINER TIGHTLY CLOSED, IN A DRY, VENTILATED AREA. KEEP AWAY FROM POTENTIAL SOURCES OF CONDITIONS FOR SAFE STORAGE, INCLUDING ANY INCOMPATIBILITIES IGNITION AND PROTECTED FROM LIGHT. MAINTAIN LIMITED CONTACT WITH OXYGEN. 7.3 SPECIFIC END USE(S) FRAGRANCES: USE IN ACCORDANCE WITH GOOD MANUFACTURING AND INDUSTRIAL HYGIENE PRACTICES. SECTION 8: EXPOSURE CONTROLS & PERSONAL PROTECTION 8.1 WORKPLACE EXPOSURE LIMITS: NOT APPLICABLE. CONTROL PARAMETERS 8.2 EXPOSURE CONTROLS EYE PROTECTION WEAR PROTECTIVE GLOVES/EYE PROTECTION/FACE PROTECTION. HAND PROTECTION WEAR PROTECTIVE GLOVES/EYE PROTECTION/FACE PROTECTION. UNDER NORMAL CONDITIONS OF USE AND WHERE ADEQUATE VENTILATION IS AVAILABLE TO PREVENT BUILD UP OF EXCESSIVE VAPOUR, THIS MATERIAL SHOULD NOT REQUIRE SPECIAL ENGINEERING CONTROLS. HOWEVER, IN CONDITIONS OF HIGH OR PROLONGED USE, OR HIGH TEMPERATURE OR OTHER CONDITIONS WHICH INCREASE EXPOSURE, THE FOLLOWING ENGINEERING RESPIRATORY EQUIPMENT CONTROLS CAN BE USED TO MINIMISE EXPOSURE TO PERSONNEL: A) INCREASE VENTILATION OF THE AREA WITH LOCAL EXHAUST VENTILATION. B) PERSONNEL CAN USE AN APPROVED, APPROPRIATELY FITTED RESPIRATOR WITH ORGANIC VAPOUR CARTRIDGE OR CANISTERS AND PARTICULATE FILTERS. C) USE CLOSED SYSTEMS FOR TRANSFERRING AND PROCESSING THIS MATERIAL. ALSO REFER TO SECTIONS 2 AND 7. HYGIENE MEASURES GOOD PERSONAL HYGIENE PRACTICES ARE ALWAYS ADVISABLE, ESPECIALLY WHEN WORKING WITH CHEMICALS / OILS. ENGINEERING MEASURES PROVIDE ADEQUATE VENTILATION. SKIN PROTECTION WEAR PROTECTIVE CLOTHING TO REDUCE THE RISK OF SKIN AND EYE CONTACT. PERSONAL PROTECTION AVOID INHALATION OF THE PRODUCT. AVOID CONTACT WITH SKIN AND EYES. OTHER PROTECTION WEAR SUITABLE PROTECTION TO AVOID CONTACT WITH SKIN AND EYES. DO NOT INHALE VAPOURS. PROCESS CONDITIONS ENSURE AREA IS WELL VENTILATED. AVOID VAPOUR INHALATION. SAFETY SHOWER & EYE BATH. ENVIROMENTAL EXPOSURE CONTROLS AVOID DISCHARGING INTO DRAINAGE WATER. SECTION 9: PHYSICAL & CHEMICAL PROPERTIES 9.1 PHYSICAL & CHEMICAL PROPERTIES APPEARANCE LIQUID COLOUR GREENISH - YELLOW ODOUR CHARACTERISTIC - LEMON RELATIVE DENSITY 0.848 – 0.861 @ 25⁰C FLASH POINT (°C) 48⁰C REFRACTIVE INDEX @ 20 °C 1.4710 – 1.4760 @ 20⁰C SOLUBILITY IN WATER @ 20 °C NO DATA. BOILING POINT OR INITIAL BOILING POINT AND BOILING RANGE (°C) 210°C 9.2 OTHER INFORMATION NO DATA. 9.2.1 INFORMATION WITH REGARD TO PHYSICAL HAZARD CLASSES NO DATA. 9.2.2 OTHER SAFETY CHARACTERISTICS NO DATA. SECTION 10: STABILITY & REACTIVITY 10.1 PRESENTS NO SIGNIFICANT REACTIVITY HAZARDS, BY ITSELF OR IN CONTACT WITH WATER. STABLE UNDER NORMAL REACTIVITY TEMPERATURE AND STORAGE CONDITIONS AND RECOMMENDED USE. 10.2 CHEMICAL STABILITY STABLE UNDER SUGGESTED STORAGE CONDITIONS (<15°C). 10.3 POSSIBILITY OF HAZARDOUS REACTIONS NOT EXPECTED UNDER NORMAL CONDITIONS OF USE. 10.4 CONDITIONS TO AVOID HEAT, FLAMES AND SPARKS. 10.5 INCOMPATIBLE MATERIALS AVOID CONTACT WITH STRONG ACIDS, ALKALIS OR OXIDISING AGENTS 10.6 THIS PRODUCT DOES NOT DECOMPOSE UNDER NORMAL CONDITIONS. UNDER FIRE CONDITIONS THE PRODUCT WILL PRODUCE HAZARDOUS DECOMPOSITION PRODUCTS A MIXTURE OF IRRITATING FUMES & SMOKE & CARBON MONOXIDE. SECTION 11: TOXICOLOGICAL INFORMATION 11.1 TOXICOLOGICAL EFFECTS BASED ON AVAILABLE DATA THE CLASSIFICATION CRITERIA ARE NOT MET. ACUTE TOXICITY ORAL >5000 ACUTE TOXICITY ACUTE TOXICITY DERMAL NOT APPLICABLE ACUTE TOXICITY INHALATION NOT AVAILABLE SKIN IRRITATION SKIN CORROSION / IRRITATION CATEGORY 2 EYE DAMAGE OR IRRITATION BASED ON AVAILABLE DATA THE CLASSIFICATION CRITERIA ARE NOT MET. RESPIRATORY OR SKIN SENSITIVITY SENSITIZATION - SKIN CATEGORY 1 GERM CELL MUTAGENICITY BASED ON AVAILABLE DATA THE CLASSIFICATION CRITERIA ARE NOT MET. CARCINOGENICITY BASED ON AVAILABLE DATA THE CLASSIFICATION CRITERIA ARE NOT MET. REPRODUCTIVE TOXICITY TOXIC TO REPRODUCTION CATEGORY 2 STOT – SINGLE EXPOSURE BASED ON AVAILABLE DATA THE CLASSIFICATION CRITERIA ARE NOT MET. STOT – REPEATED EXPOSURE BASED ON AVAILABLE DATA THE CLASSIFICATION CRITERIA ARE NOT MET. ASPIRATION HAZARD ASPIRATION HAZARD CATEGORY 1 ALPHA-PINENE CAS NO: 80-56-8, EC NO: 201-291-9 11.2 LD50/ATE ORAL: 500 INFORMATION ON OTHER HAZARDS LD50/ATE DERMAL: NOT AVAILABLE LC50/ATE INHALATION: NOT AVAILABLE LC50 ROUTE: NOT AVAILABLE SECTION 12: ECOLOGICAL INFORMATION 12.1 VERY TOXIC TO AQUATIC LIFE WITH LONG LASTING EFFECTS. TOXICITY TOXIC TO AQUATIC LIFE WITH LONG LASTING EFFECTS. 12.2 PERSISTENCE & DEGRADABILITY NO ADDITIONAL INFORMATION AVAILABLE. 12.3 BIO- ACCUMULATIVE POTENTIAL NO ADDITIONAL INFORMATION AVAILABLE. 12.4 MOBILITY IN SOIL NO ADDITIONAL INFORMATION AVAILABLE. 12.5 RESULTS OF PBT & VPVB ASSESSMENT THIS SUBSTANCE DOES NOT MEET THE PBT/VPVB CRITERIA OF REACH, ANNEX XIII. 12.6 ENDOCRINE DISRUPTING PROPERTIES NO ADDITIONAL INFORMATION AVAILABLE. 12.7 OTHER ADVERSE EFFECTS NO ADDITIONAL INFORMATION AVAILABLE. SECTION 13: DISPOSAL INFORMATION 13.1 THE CONTAINERS USED FOR THIS PRODUCT MUST BE COMPLETELY EMPTY BEFORE DISPOSAL. DISPOSE WASTE TREATMENT METHODS PRODUCT AND / OR CONTAMINATED PACKAGING IN ACCORDANCE WITH LOCAL AND INTERNATIONAL REGULATIONS. DISPOSAL THROUGH THE WASTE WATER IS ILLEGAL. SECTION 14: TRANSPORT INFORMATION 14.1 TRANSPORT INFORMATION ROAD: 1197 UN NUMBER RAIL: 1197 AIR: 1197 IMDG : EXTRACTS, LIQUID (BETA-PINENE), MARINE POLLUTANT 14.2 UN SHIPPING NAME ADR, RID, ADN : EXTRACTS, LIQUID ICAO TI : EXTRACTS LIQUID IMDG : 3 ADR, RID, ADN : 3 ICAO TI : 3 TRANSPORT LABELS 14.3 TRANSPORT HAZARD CLASS(ES) ADR/RID/ADN PACKING GROUP III 14.4 IMDG PACKING GROUP III PACKING GROUP ICAO PACKING GROUP III 14.5 ENVIRONMENTALLY HAZARDOUS SUBSTANCE/MARINE POLLUTANT ENVIROMENTAL HAZARDS 14.6 CONTAINS CONSTITUENTS THAT ARE FLAMMABLE & DANGEROUS TO THE ENVIRONMENT. SPECIAL PRECAUTIONS FOR USER 14.7 TRANSPORT IN BULK ACCORDING TO ANNEX II OF MARPOL73/78 & THE IBC NOT APPLICABLE CODE. SECTION 15: REGULATORY INFORMATION 15.1 PRODUCT SPECIFIC SAFETY, HEALTH & ENVIRONMENTAL REGULATIONS & LEGISLATION REGULATION (EC) NO 2020/878 OF THE EUROPEAN PARLIAMENT AND OF THE COUNCIL OF 18TH DECEMBER 2006. CONCERNING THE REGISTRATION, EVALUATION, AUTHORIZATION & RESTRICTION OF CHEMICALS (REACH), ESTABLISHING A EUROPEAN CHEMICALS AGENCY, AMENDING DIRECTIVE 1999/45/EC AND REPEALING COUNCIL REGULATION (EEC) NO793/93 & COMMISSION EU DIRECTIVES REGULATION (EC) NO1488/94 AS WELL AS COUNCIL DIRECTIVE 76/769/EEC & COMMISSION DIRECTIVE 91/155/ECC, 93/67/ECC, 93/105/EEC & 2000/21/EC (INCLUDING AMENDMENTS). RIFM ID NUMBER: 136-G2.5 STATUTORY INSTRUMENTS THE CHEMICALS (HAZARD INFORMATION & PACKAGING FOR SUPPLY REGULATIONS 2009 (S.I.2009 NO 716). CLASSIFICATION & LABELLING OF SUBSTANCES & PREPARATIONS DANGEROUS FOR SUPPLY. SAFETY DATA APPROVED CODE OF PRACTICE SHEETS FOR SUBSTANCES & PREPARATIONS. GUIDANCE NOTES WORKPLACE EXPOSURE LIMITS EH40. CHIP FOR EVERYONE HSG 108. 15.2 CHEMICAL SAFETY ASSESSMENT - SECTION 16: OTHER INFORMATION ACUTE TOX. 4 ACUTE TOXICITY - ORAL CATEGORY 4 AQUATIC ACUTE 1 HAZARDOUS TO THE AQUATIC ENVIRONMENT - ACUTE HAZARD CATEGORY 1 AQUATIC CHRONIC 1 HAZARDOUS TO THE AQUATIC ENVIRONMENT - LONG-TERM HAZARD CATEGORY 1 AQUATIC CHRONIC 2 HAZARDOUS TO THE AQUATIC ENVIRONMENT - LONG-TERM HAZARD CATEGORY 2 AQUATIC CHRONIC 3 HAZARDOUS TO THE AQUATIC ENVIRONMENT - LONG-TERM HAZARD CATEGORY 3 AQUATIC CHRONIC 4 HAZARDOUS TO THE AQUATIC ENVIRONMENT - LONG-TERM HAZARD CATEGORY 4 HAZARD AND/ OR PRECAUTIONARY STATEMENTS IN FULL ASP. TOX 1 ASPIRATION HAZARD CATEGORY 1 EYE IRRIT. 2 EYE DAMAGE / IRRITATION CATEGORY 2 FLAM. LIQ. 3 FLAMMABLE LIQUID, HAZARD CATEGORY 3 H226 FLAMMABLE LIQUID AND VAPOUR. H302 HARMFUL IF SWALLOWED. H304 MAY BE FATAL IF SWALLOWED AND ENTERS AIRWAYS. H315 CAUSES SKIN IRRITATION. H317 MAY CAUSE AN ALLERGIC SKIN REACTION. H319 CAUSES SERIOUS EYE IRRITATION. H361 SUSPECTED OF DAMAGING FERTILITY OR THE UNBORN CHILD (EXPOSURE ROUTE). H400 VERY TOXIC TO AQUATIC LIFE. H410 VERY TOXIC TO AQUATIC LIFE WITH LONG LASTING EFFECTS. H411 TOXIC TO AQUATIC LIFE WITH LONG LASTING EFFECTS. H412 HARMFUL TO AQUATIC LIFE WITH LONG LASTING EFFECTS. H413 MAY CAUSE LONG LASTING HARMFUL EFFECTS TO AQUATIC LIFE. P202 DO NOT HANDLE UNTIL ALL SAFETY PRECAUTIONS HAVE BEEN READ AND UNDERSTOOD. P210 KEEP AWAY FROM HEAT, SPARKS, OPEN FLAMES AND HOT SURFACES. - NO SMOKING. P233 KEEP CONTAINER TIGHTLY CLOSED. P240 GROUND/BOND CONTAINER AND RECEIVING EQUIPMENT. P241 USE EXPLOSION-PROOF ELECTRICAL, VENTILATING AND LIGHTING EQUIPMENT. P242 USE ONLY NON-SPARKING TOOLS. P243 TAKE PRECAUTIONARY MEASURES AGAINST STATIC DISCHARGE. P261 AVOID BREATHING VAPOUR OR DUST. P264 WASH HANDS AND OTHER CONTACTED SKIN THOROUGHLY AFTER HANDLING. P270 DO NOT EAT, DRINK OR SMOKE WHEN USING THIS PRODUCT. P272 CONTAMINATED WORK CLOTHING SHOULD NOT BE ALLOWED OUT OF THE WORKPLACE. P273 AVOID RELEASE TO THE ENVIRONMENT. P280 WEAR PROTECTIVE GLOVES/EYE PROTECTION/FACE PROTECTION. P301/310 IF SWALLOWED: IMMEDIATELY CALL A POISON CENTER OR DOCTOR/PHYSICIAN. P302/352 IF ON SKIN: WASH WITH PLENTY OF SOAP AND WATER. P303/361/353 IF ON SKIN (OR HAIR): REMOVE/TAKE OFF IMMEDIATELY ALL CONTAMINATED CLOTHING. RINSE SKIN WITH WATER/SHOWER. P305/351/338 IF IN EYES: RINSE CAUTIOUSLY WITH WATER FOR SEVERAL MINUTES. REMOVE CONTACT LENSES, IF PRESENT AND EASY TO DO. CONTINUE RINSING.