ISO CYCLO CITRAL

Hazard statements (CLP)

H315, H317, H319, H412

Code

Statements

H315

Causes skin irritation

SECTION 2: Hazards identification

Regulation (EC) No. 1272/2008 Classification of the substance or mixture

Contains

Isocyclocitral

Signal word

Warning

Hazard statements

H315 - Causes skin irritation H317 - May cause an allergic skin reaction H319 - Causes serious eye irritation H412 - Harmful to aquatic life with long lasting effects

Precautionary statements

P280 - Wear protective gloves/protective clothing/eye protection/face protection P302 + P352 - IF ON SKIN: Wash with plenty of soap and water P333 + P313 - If skin irritation or rash occurs: Get medical advice/attention P305 + P351 + P338 - IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing P337 + P313 - If eye irritation persists: Get medical advice/attention P273 - Avoid release to the environment P501 - Dispose of contents/container in accordance with local, regional, national, and international regulations as applicable

2.3 Other hazards

H227 - Combustible liquid H303 - May be harmful if swallowed H401 - Toxic to aquatic life

2.1 Classification of the substance or mixture

Regulation (EC) No 1272/2008 Skin corrosion/irritation Category 2 - (H315) Serious eye damage/eye irritation Category 2 - (H319) Skin sensitization Category 1B - (H317) Chronic aquatic toxicity Category 3 - (H412) 2.2. Label Elements Product identifier Contains Isocyclocitral Signal word Warning Hazard statements H315 - Causes skin irritation H317 - May cause an allergic skin reaction H319 - Causes serious eye irritation H412 - Harmful to aquatic life with long lasting effects Precautionary Statements P280 - Wear protective gloves/protective clothing/eye protection/face protection P302 + P352 - IF ON SKIN: Wash with plenty of soap and water P333 + P313 - If skin irritation or rash occurs: Get medical advice/attention P305 + P351 + P338 - IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing P337 + P313 - If eye irritation persists: Get medical advice/attention P273 - Avoid release to the environment P501 - Dispose of contents/container in accordance with local, regional, national, and international regulations as applicable 2.3. Other Hazards H227 - Combustible liquid H303 - May be harmful if swallowed H401 - Toxic to aquatic life SECTION 3: Composition/information on ingredients 3.1 Substances Chemical nature Aliphatic aldehyde. Chemical Name EC No. CAS No. Weight-% Classification REACH according to registration Regulation (EC) number No. 1272/2008 [CLP] Isocyclocitral Present 1335-66-6 100 Aquatic Acute 2 No data available (H401) (EFFA) Skin Sens. 1 (H317) (EFFA) Eye Irrit. 2 (H319) (EFFA) Skin Irrit. 2 (H315) (EFFA) Aquatic Chronic 3 (H412) (EFFA) Acute Tox. 5 (H303)(EFFA) Flam. Liq. 4 (H227)(EFFA) Full text of H- and EUH-phrases: see section 16 SECTION 4: First aid measures 4.1. Description of first aid measures General advice If symptoms persist, call a physician. Inhalation Immediate medical attention is not required. If symptoms persist, call a physician. Move to fresh air in case of accidental inhalation of vapors or decomposition products. Skin contact Immediate medical attention is not required. Wash off immediately with soap and plenty of water while removing all contaminated clothes and shoes. If skin irritation persists, call a physician. Eye Contact Immediately flush with plenty of water. After initial flushing, remove any contact lenses and continue flushing for at least 15 minutes. Keep eye wide open while rinsing. If symptoms persist, call a physician. Ingestion Clean mouth with water and drink afterwards plenty of water. Never give anything by mouth to an unconscious person. Call a physician. Do NOT induce vomiting. Self-protection of the first aider Use personal protective equipment as required. 4.2. Most important symptoms and effects, both acute and delayed Symptoms None known. 4.3. Indication of any immediate medical attention and special treatment needed Note to physicians Treat symptomatically. SECTION 5: Firefighting measures 5.1. Extinguishing media Suitable Extinguishing Media Use Dry chemical Carbon dioxide (CO2) Water spray (fog) Alcohol resistant foam Unsuitable extinguishing media Do not use a solid water stream as it may scatter and spread fire 5.2. Special hazards arising from the substance or mixture Keep product and empty container away from heat and sources of ignition Risk of ignition Hazardous combustion productsIrritating or toxic substances may be emitted upon burning, combustion, or decomposition. 5.3. Advice for firefighters Wear self-contained breathing apparatus and protective suit. Use personal protective equipment as required. SECTION 6: Accidental release measures 6.1. Personal precautions, protective equipment and emergency procedures Personal precautions Use personal protective equipment as required. Remove all sources of ignition. Evacuate personnel to safe areas. Keep people away from and upwind of spill/leak. Pay attention to flashback. Take precautionary measures against static discharges. For emergency responders Use personal protection recommended in Section 8. 6.2. Environmental precautions Do not flush into surface water or sanitary sewer system. Prevent further leakage or spillage if safe to do so. Prevent product from entering drains. 6.3. Methods and material for containment and cleaning up Methods for Containment Prevent further leakage or spillage if safe to do so. Cover with DRY earth, DRY sand or other non-combustible material followed with plastic sheet to minimize spreading or contact with rain. Methods for cleaning up Soak up with inert absorbent material. Dam up. Pick up and transfer to properly labeled containers. Take precautionary measures against static discharges. 6.4. Reference to other sections See Section 12: ECOLOGICAL INFORMATION. SECTION 7: Handling and storage 7.1. Precautions for safe handling Advice on safe handling Use with local exhaust ventilation. All equipment used when handling the product must be grounded. Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Use personal protective equipment as required. Do not breathe dust/fume/gas/mist/vapors/spray. Take necessary action to avoid static electricity discharge (which might cause ignition of organic vapors). General hygiene considerations When using do not eat, drink or smoke. Regular cleaning of equipment, work area and clothing is recommended. 7.2. Conditions for safe storage, including any incompatibilities Storage Conditions Keep away from heat, sparks, flame and other sources of ignition (i.e., pilot lights, electric motors and static electricity). Keep containers tightly closed in a cool, well-ventilated place. Keep away from heat. Keep in properly labeled containers. 7.3. Specific end use(s) Risk Management Methods (RMM) The information required is contained in this Material Safety Data Sheet. SECTION 8: Exposure controls/personal protection 8.1. Control parameters Derived No Effect Level (DNEL) No information available Predicted No Effect Concentration No information available (PNEC) 8.2. Exposure controls Engineering controls Showers Eyewash stations Ventilation systems Ensure adequate ventilation, especially in confined areas Personal Protective Equipment Eye/Face Protection Tight sealing safety goggles. Hand protection Wear protective nitrile rubber gloves. Skin and Body Protection Suitable protective clothing. Wear chemical resistant clothing such as gloves, apron, boots or whole bodysuits made from neoprene, as appropriate. Antistatic footwear. Gloves made of plastic or rubber. Respiratory protection Ensure adequate ventilation, especially in confined areas. No protective equipment is needed under normal use conditions. If exposure limits are exceeded or irritation is experienced, ventilation and evacuation may be required. Environmental exposure controls Prevent product from entering drains. SECTION 9: Physical and chemical properties 9.1. Information on basic physical and chemical properties Physical state Liquid Appearance Clear Odor Characteristic odor Color Yellow Odor threshold Not applicable Property Values Remarks • Method pH Melting point / freezing point Boiling point / boiling range Flash Point 66 °C / 151 °F Evaporation Rate Flammability (solid, gas) Flammability Limit in Air Upper flammability limit: Lower flammability limit: Vapor pressure Vapor Density Specific gravity 0.914 - 0.923 (25°C) Water solubility solubility(ies) Partition coefficient Autoignition Temperature Decomposition temperature Kinematic viscosity Dynamic viscosity Explosive properties Not an explosive Oxidizing properties Not oxidising 9.2. Other information Molecular weight 152.23 VOC content (%) Not applicable Density Not applicable Bulk Density Not applicable SECTION 10: Stability and reactivity 10.1. Reactivity 10.2. Chemical stability Stable under recommended storage conditions. Explosion data Sensitivity to Mechanical Impact None. Sensitivity to Static Discharge None. 10.3. Possibility of hazardous reactions Possibility of Hazardous Reactions None under normal processing. 10.4. Conditions to avoid Heat, flames and sparks. 10.5. Incompatible materials No information available. 10.6. Hazardous decomposition products None under normal use conditions. SECTION 11: Toxicological information 11.1. Information on toxicological effects Acute toxicity Product Information Inhalation Avoid breathing vapors or mists. Eye Contact Avoid contact with eyes. Causes serious eye irritation. Skin contact Avoid contact with skin. May cause an allergic skin reaction. Causes skin irritation. Ingestion May be harmful if swallowed. The following values are calculated based on chapter 3.1 of the GHS document 0 % of the mixture consists of ingredient(s) of unknown acute oral toxicity. 100 % of the mixture consists of ingredient(s) of unknown acute dermal toxicity. 100 % of the mixture consists of ingredient(s) of unknown acute inhalation toxicity (gas) 100 % of the mixture consists of ingredient(s) of unknown acute inhalation toxicity (vapor) 100 % of the mixture consists of ingredient(s) of unknown acute inhalation toxicity (dust/mist) Chemical Name Oral LD50 Dermal LD50 Inhalation LC50 Isocyclocitral 3,220 mg/kg (Rat) Skin corrosion/irritation Irritating to skin. Serious eye damage/eye irritation Causes serious eye irritation. Sensitization Not expected to cause skin sensitization. Germ cell mutagenicity Not classified. Carcinogenicity Not classified. Reproductive toxicity This product does not contain any known or suspected reproductive hazards above the threshold value. STOT - single exposure Not classified. STOT - repeated exposure Not classified. Aspiration hazard Not classified. SECTION 12: Ecological information 12.1. Toxicity Toxic to aquatic life Harmful to aquatic life with long lasting effects 0 % of the mixture consists of component(s) of unknown hazards to the aquatic environment 12.2. Persistence and degradability No information available. 12.3. Bioaccumulative potential No information available. 12.4. Mobility in soil Mobility in soil No information available 12.5. Results of PBT and vPvB assessment