Hot Apple Pie

Hazard statements (CLP)

H317, H319

Code

Statements

H317

May cause an allergic skin reaction

SECTION 2: Hazards identification

Signal word

Warning

Hazard statements

H317, May cause an allergic skin reaction. H319, Causes serious eye irritation. EUH208, Contains Eucalyptol. May produce an allergic reaction.

Precautionary statements

P243, Take precautionary measures against static discharge. P261, Avoid breathing vapour or dust. P264, Wash hands and other contacted skin thoroughly after handling. P272, Contaminated work clothing should not be allowed out of the workplace. P280, Wear protective gloves/eye protection/face protection. P303/361/353, IF ON SKIN (or hair): Remove/take off immediately all contaminated clothing. Rinse skin with water/shower. P305/351/338, IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P333/313, If skin irritation or rash occurs: Get medical advice/attention. P337/313, If eye irritation persists: Get medical advice/attention. P363, Wash contaminated clothing before reuse. P403/235, Store in a well-ventilated place. Keep cool. P501, Dispose of contents/container to approved disposal site, in accordance with local regulations.

2.3 Other hazards

None

2.1 Classification of the substance or mixture

Classification under Regulation (EC) No 1272/2008 Class and category of Eye Damage / Irritation Category 2 danger: Sensitization - Skin Category 1 H317, May cause an allergic skin reaction. H319, Causes serious eye irritation. 2.2 Label elements Signal word: Warning Hazard statements: H317, May cause an allergic skin reaction. H319, Causes serious eye irritation. EUH208, Contains Eucalyptol. May produce an allergic reaction. Supplemental Information: 1 Precautionary P243, Take precautionary measures against static discharge. statements: P261, Avoid breathing vapour or dust. P264, Wash hands and other contacted skin thoroughly after handling. P272, Contaminated work clothing should not be allowed out of the workplace. P280, Wear protective gloves/eye protection/face protection. P303/361/353, IF ON SKIN (or hair): Remove/take off immediately all contaminated clothing. Rinse skin with water/shower. P305/351/338, IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P333/313, If skin irritation or rash occurs: Get medical advice/attention. P337/313, If eye irritation persists: Get medical advice/attention. P363, Wash contaminated clothing before reuse. P403/235, Store in a well-ventilated place. Keep cool. P501, Dispose of contents/container to approved disposal site, in accordance with local regulations. Pictograms: Other hazards: None Section 3. Composition / information on ingredients 3.2 Mixtures Contains: REACH Registration Classification for Name CAS EC % No. (CLP) 1272/2008 Eugenol 97-53-0 202-589-1 10-<20% EDI 2-SS 1B;H317- H319,- Ethyl maltol 4940-11-8 225-582-5 5-<10% ATO 4;H302,- ATD 4-SCI 2-EDI 2-SS Cinnamaldehyde 104-55-2 203-213-9 5-<10% 1A;H312-H315-H317- H319,- Linalool 78-70-6 201-134-4 1-<5% SCI 2-EDI 2-SS 1B; H315-H317-H319,- 1 Coumarin 91-64-5 202-086-7 1-<5% ATO 4-SS 1B;H302- H317,- Eucalyptol 470-82-6 207-431-5 0.1-<1% FL 3-SS 1B;H226- H317,- Substances with Community workplace exposure limits: Not Applicable Substances that are persistent, bioaccumulative and toxic or very persistent and very bioaccumulative, greater than 0.1%: Not Applicable Section 4. First-aid measures 4.1 Description of first aid measures IF ON SKIN (or hair): Remove/take off immediately all contaminated clothing. Rinse skin with water/shower. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. 4.2 Most important symptoms and effects, both acute and delayed May cause an allergic skin reaction. Causes serious eye irritation. 4.3 Indication of any immediate medical attention and special treatment needed None expected, see Section 4.1 for further information. SECTION 5: Firefighting measures 5.1 Extinguishing media Suitable media: Carbon dioxide, Dry chemical, Foam. 5.2 Special hazards arising from the substance or mixture In case of fire, may be liberated: Carbon monoxide, Unidentified organic compounds. 5.3 Advice for fire fighters: In case of insufficient ventilation, wear suitable respiratory equipment. Section 6. Accidental release measures 6.1 Personal precautions, protective equipment and emergency procedures: Avoid inhalation. Avoid contact with skin and eyes. See protective measures under Section 7 and 8. 6.2 Environmental precautions: Keep away from drains, surface and ground water, and soil. 1 6.3 Methods and material for containment and cleaning up: Provide adequate ventilation. Avoid excessive inhalation of vapours. Contain spillage immediately by use of sand or inert powder. Dispose of according to local regulations. 6.4 Reference to other sections: Also refer to sections 8 and 13. Section 7. Handling and storage 7.1 Precautions for safe handling: Not Dertermined 7.2 Conditions for safe storage, including any incompatibilities: Not Dertermined 7.3 Specific end use(s): Fragrances: Use in accordance with good manufacturing and industrial hygiene practices. Section 8. Exposure controls/personal protection 8.1 Control parameters Workplace exposure limits: Not Applicable 8.2 Exposure Controls Eye / Skin Protection Wear protective gloves/eye protection/face protection Respiratory Protection Under normal conditions of use and where adequate ventilation is available to prevent build up of excessive vapour, this material should not require special engineering controls. However, in conditions of high or prolonged use, or high temperature or other conditions which increase exposure, the following engineering controls can be used to minimise exposure to personnel: a) Increase ventilation of the area with local exhaust ventilation. b) Personnel can use an approved, appropriately fitted respirator with organic vapour cartridge or canisters and particulate filters. c) Use closed systems for transferring and processing this material. Also refer to Sections 2 and 7. Section 9. Physical and chemical properties 9.1 Information on basic physical and chemical properties Appearance: Not determined Odour: Sweet 1 Odour threshold: Not determined pH: Not determined Melting point / freezing point: Not determined Initial boiling point / range: Not determined Flash point: 1 0 5 °C Evaporation rate: Not determined Flammability (solid, gas): Not determined Upper/lower flammability or explosive limits: Product does not present an explosion hazard Vapour pressure: Not determined Vapour density: Not determined Relative density: 0.985269 - 1.0 88981 Solubility(ies): Not determined Partition coefficient: n-octanol/water: Not determined Auto-ignition temperature: Not determined Decomposition temperature: Not determined Viscosity: Not determined Explosive properties: Not expected Oxidising properties: Not expected Refractive Index: 1.48040 - 1.49071 Optical Rotation: 0.01 9.2 Other information: None available Section 10. Stability and reactivity 10.1 Reactivity: Presents no significant reactivity hazard, by itself or in contact with water. 10.2 Chemical stability: Good stability under normal storage conditions. 10.3 Possibility of hazardous reactions: Not expected under normal conditions of use. 10.4 Conditions to avoid: Not Dertermined 10.5 Incompatible materials: Avoid contact with strong acids, alkalis or oxidising agents. 10.6 Hazardous decomposition products: Not expected. 1 Section 11. Toxicological information 11.1 Information on toxicological effects This mixture has not been tested as a whole for health effects. The health effects have been calculated using the methods outlined in Regulation (EC) No 1272/2008 (CLP). Acute Toxicity: Based on available data the classification criteria are not met. Acute Toxicity Oral 4459 Acute Toxicity Dermal >5000 Acute Toxicity Inhalation Not Available Skin corrosion/irritation: Based on available data the classification criteria are not met. Serious eye damage/irritation: Eye Damage / Irritation Category 2 Respiratory or skin sensitisation: Sensitization - Skin Category 1 Germ cell mutagenicity: Based on available data the classification criteria are not met. Carcinogenicity: Based on available data the classification criteria are not met. Reproductive toxicity: Based on available data the classification criteria are not met. STOT-single exposure: Based on available data the classification criteria are not met. STOT-repeated exposure: Based on available data the classification criteria are not met. Aspiration hazard: Based on available data the classification criteria are not met. Information about hazardous ingredients in the mixture Ingredient CAS EC LD50/ATE Oral LD50/ATE