HEXYL CINNAMIC ALDEHYDE, ALPHA HEXYL

Hazard statements (CLP)

H303, H316, H317, H400, H410, H411

Code

Statements

H303

May be harmful if swallowed

SECTION 2: Hazards identification

Classification of the substance or mixture Acute Tox. 5 (oral) - H303 Skin lrrit. 3 - H316 Skin Sens. 1 B - H317 Aquatic Acute 1 - H400 Aquatic Chronic 2 - H411

Signal word

Warning

Hazard statements

H303 - May be harmful if swallowed. H316 - Causes mild skin irritation. H317 - May cause an allergic skin reaction. H410 - Very toxic to aquatic life with long lasting effects.

Precautionary statements

P261 -Avoid breathing dust/fume/gas/mist/vapours/spray. P280 - Wear protective gloves/protective clothing/eye protection/face protection. P302+P352+P333+P313 - IF ON SKIN Wash with plenty of soap and water. If skin irritation or rash occurs Get medical advice/attention P312 - Call a POISON CENTER or doctor/physician if you feel unwell.

2.3 Other hazards

This product is oxidized by the oxygen in the air, giving off heat. Paper or tissue soaked in this product may spontaneously ignite. To collect spills of this product, it is necessary to use fireproof materials and then soak them in water.

2.1 Classification of the substance or mixture

Acute Tox. 5 (oral) - H303 Skin lrrit. 3 - H316 Skin Sens. 1 B - H317 Aquatic Acute 1 - H400 Aquatic Chronic 2 - H411 2.2. Label Elements Signal Word: Warning Hazard statements: H303 - May be harmful if swallowed. H316 - Causes mild skin irritation. H317 - May cause an allergic skin reaction. H410 - Very toxic to aquatic life with long lasting effects. Precautionary statements: P261 -Avoid breathing dust/fume/gas/mist/vapours/spray. P280 - Wear protective gloves/protective clothing/eye protection/face protection. P302+P352+P333+P313 - IF ON SKIN: Wash with plenty of soap and water. If skin irritation or rash occurs: Get medical advice/attention. P312 - Call a POISON CENTER or doctor/physician if you feel unwell. 2.3. Other hazards This product is oxidized by the oxygen in the air, giving off heat. Paper or tissue soaked in this product may spontaneously ignite. To collect spills of this product, it is necessary to use fireproof materials and then soak them in water. 3. COMPOSITION/INFORMATION ON INGREDIENTS 3.1. Substances Chemical name: HEXYL CINNAMIC CAS number: ALDEHYDE 165184-98-5 EC number: 639-566-4 Hazardous constituents: %(w/w) CASNo. Classification according to GHS Chemical Name EC No. Acute Toxicity - Category 5 (oral) - H303 Skin Irritant - Category 3 - H316 HEXYL CINNAMIC ALDEHYDE ?:SO 101-86-0 Skin sensitizer - Category 1 B- H317 202-983-3 Hazardous to the aquatic environment, short-tenn (acute} - Category 1 - H400 Hazardous to the aquatic environment, long-term (chronic} - Category 2 - H411 See the full text of the hazard statements in section 16. 3.2. Mixtures Not applicable. 4. FIRST-AID MEASURES 4.1. Description of first aid measures Ingestion: Rinse mouth with water. Obtain medical advice. Keep at rest. Do not induce vomiting. Eye contact: In case of contact with eyes, rinse immediately with plenty of water for at least 15 minutes and seek medical advice. Inhalation: Remove person to fresh air and keep at rest. Seek immediate medical advice. Skin contact: Take off immediately all contaminated clothing. Thoroughly wash affected skin with soap and water. Seek medical attention if symptoms persist. 4.2. Most important symptoms and effects, both acute and delayed No information available. 4.3. Indication of any immediate medical attention and special treatment needed No information available. 5. FIRE-FI GHTING MEASURES 5.1. Extinguishing media Water spray, carbon dioxide, dry chemical powder or appropriate foam. For safety reasons do not use full water jet. 5.2. Special hazards arising from the substance or mixture Known or Anticipated Hazardous Products of Combustion: Emits toxic fumes under fire conditions. 5.3. Advice for firefighters High temperatures can lead to high pressures inside closed containers. Avoid inhalation of vapors that are created. Use appropriate respiratory protection. Do not allow spillage of fire to be poured into drains or watercourses. Wear self-contained breathing apparatus and protective clothing. 6. ACCIDENTAL RELEASE MEASURES 6.1. Personal precautions, protective equipment and emergency procedures Evacuate surronding areas. Ensure adequate ventilation. Keep unnecessary and unprotected personnel from entering. Do not breathe vapor/spray. Avoid contact with skin and eyes. Information regarding personal protective measures: see section 8. 6.2. Environmental precautions To avoid possible contamination of the environment, do not discharge into any drains, surface waters or groundwaters. 6.3. Methods and materials for containment and cleaning up Cover with an inert, inorganic, non-combustible absorbent material (e.g. dry-lime, sand, soda ash}. Place in covered containers using non-sparking tools and transport outdoors. Avoid open flames or sources of ignition (e.g. pilot lights on gas hot water heater}. Ventilate area and wash spill site after material pickup is complete. 6.4. Reference to other sections Information regarding exposure controls, personal protection and disposal considerations can be found in sections 8 and 13. 7. HANDLING AND STORAGE 7.1. Precautions for safe handling Do not store or handle this material near food or drinking water. Do not smoke. Avoid contact with the eyes, skin and clothing. Wear protective clothing and use glasses. Observe the rules of safety and hygiene at work. Keep in the original container or an alternative made from a compatible material. 7.2. Conditions for safe storage, including any incompatibilities Store in tightly closed and preferably full containers in a cool, dry and ventilated area, protected from light. Keep away from sources of ignition (e.g. hot surfaces, sparks, flame and static discharges). Keep away from incompatible materials (see section 10). 7.3. Specific end use(s) No information available. 8. EXPOSURE CONTROLS AND PERSONAL PROTECTION 8.1. Control parameters Components with occupational exposure limits: None known. 8.2. Exposure controls Measures should be taken to prevent materials from being splashed into the body. Provide adequate ventilation, according to the conditions of use. Use a mechanical exhaust if required. 8.3. Individual protection measures, such as personal protective equipment ( Eye/Face protection: Chemical safety goggles are recommended. Wash contaminated goggles before reuse. Hand Protection: Chemical-resistant gloves are recommended. Wash contaminated gloves before reuse. Body protection: Personal protective equipment for the body should be selected based on the task being performed and the risks involved. Respiratory Protection: In case of insufficient ventilation, use suitable respiratory equipment. Environmental exposure controls: Emissions from ventilation or process equipment should be checked to ensure they comply with environmental protection legislation. In some cases, filters or engineering modifications to the process equipment will be necessary to reduce emissions to acceptable levels. 9. PHYSICAL AND CHEMICAL PROPERTIES Appearance: Liquid/solid Colour: Conforms to standard Odour: Conforms to standard Not Odour theshold: determined pH: Not determined Melting point/freezing point: CA. 4-15 Boling point/boiling range (°C): 305 (760 mm Hg) Flash point: 165 °C Evaporation rate: < 0,01 (BUTYL ACETATE= Flammability: 1) Not determined Lower flammability/Explosive limit: Not determined Upper flammability/Explosive limit: Not determined Vapour pressure: < 0,02 mm Hg (20°C) Vapour Density: 7 (AIR=l) Density: 0,95-0,96 g/mL (20°C) Relative density: 0,95-0,96 (20°C) Water solubility: INSOLUBLE IN WATER Solubility in other solvents: SOLUBLE IN ETHANOL Partition coefficient n-octanol/water: logPow 5,3 Auto-ignition temperature: >300°C Decomposition temperature: Not determined Viscosity, dynamic: 0 est (CINETICA) Viscosity, kinematic: Not determined Explosive properties: Not determined Oxidising properties: NONE EXPECTED 10. STABILITY AND REACTIVITY 10.1. Reactivity No hazardous reactions if stored and handled as prescribed/indicated. 10.2. Chemical stability The product is stable if stored and handled as prescribed/indicated. 10.3. Possibility of hazardous reactions No hazardous reactions if stored and handled as prescribed/indicated. 10.4. Conditions to avoid Conditions to Avoid: Excessive heat, flame or other ignition sources. 10.5. Incompatible materials Avoid contact with strong acids and bases and oxidizing agents. 10.6. Hazardous decomposition products During combustion may form carbon monoxide and unidentified organic compounds. 11. TOXICOLOGICAL INFORMATION Acute toxicity May be harmful if swallowed. Skin corrosion/irritation Causes mild skin irritation. Serious eye damage/irritation Based on the data available, the criteria for classification are not met. Respiratory or skin sensitisation May cause an allergic reaction. Germ cell mutagenicity Based on the data available, the criteria for classification are not met. Carcinogenicity Based on the data available, the criteria for classification are not met. Reproductive toxicity Based on the data available, the criteria for classification are not met. STOT-single exposure Based on the data available, the criteria for classification are not met. STOT-repeated exposure Based on the data available, the criteria for classification are not met. Aspiration hazard Based on the data available, the criteria for classification are not met. 12. ECOLOGICAL INFORMATION 12.1. Toxicity Assessment: Very toxic to aquatic life with long lasting effects. Experimental/calculated data: No information available. 12.2. Persistence and degradability No information available. 12.3. Bioaccumulative potential No information available. 12.4. Mobility in soil No information available. 12.5. Other adverse effects See also sections 6, 7, 13 and 15 Do not allow to get into waste water or waterways. 13. DISPOSAL CONSIDERATIONS 13.1. Waste treatment methods Dispose of in accordance with national and local environmental regulations. 14. TRANSPORT INFORMATION ADR/RID/ADN IMDG IATA-ICAO 14.1. UN Number or ID number U N3082 UN3082 14.2. UN proper shipping name ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N. O. S . SUB STANCE, LIQUID, N.O. S . CINNAMIC ALDEHYDE) (HEXYL CINNAMIC ALDEHYDE) (HEXYL CINNAMIC ALDEHYDE) (HEXYL 14.3. Transport hazard class(es) 9 14.4. Packing group Ill 14.5. Environmental hazards Yes Additional information 14.6 Special precautions for user None known 14.7. Maritime transport in bulk according to IMO instruments No information available 15. REGULATORY INFORMATION 15.1. Safety, health and environmental regulations/legislation specific for the substance or mixture No information available 16. OTHER INFORMATION Full text of the R-phrases, hazard statements and precautionary statements mentioned in section 3: H303 - May be harmful if swallowed. H316 - Causes mild skin irritation. H317 - May cause an allergic skin reaction. H400 - Very toxic to aquatic life. H411 - Toxic to aquatic life with long lasting effects. The information included in this safety data sheet is based on the available data at the moment this document is issued. It is meant to be a description of safety requirements for our product and does not stand for a guarantee of its properties. The user is responsible for taking all necessary steps leading to compliance with local rules and legislation. SPECIFICATION SHEET VERSION 4,00 VERSION DATE 23/01/23 PRINT DATE 26/01/2 6 PRODUCT HEXYL CINNAMIC ALDEHYDE Industrial APPLICATIONS raw material not intended for direct use. IUPAC NAME 2-(PHENYLMETHYLENE)-OCTANAL SYNONYMS ALPHA-N-HEXYLCINNAMIC ALDEHYDE FORMULA C15 H20 0 MOLECULAR WEIGHT 216,00 CAS 165184-98-5 CAS 2 101-86-0 EINECS 639-566-4 EINECS 2 202-983-3 FEMA 2569 TARIFF NUMBER 2912290090 KOSHER CERTIFICATE AVAILABLE ON REQUEST ( REACH REGISTRATION NO. 01-2119533092-50 SPECIFICATIONS ASPECT AT 20°C CLEAR MOBILE LIQUID / SOLID COLOUR PALE YELLOW TO YELLOW ODOUR FLORAL,JASMIN,ROSE, GERANIUM LEAVES TASTE DENSITY AT 20°c (g / ml) 0,952 - 0,960 DENSITY 25/25 REFRACTIVE INDEX nD20 1,5470 - 1,5530 REFRACTIVE INDEX nD25 OPTICAL ROTATION (0) BOILING POINT {0C} 305 (760 mm Hg) MELTING POINT (°C} CA. 4 - 15 FLASH POINT (°C) 165,00 ASSAY(% GC) > 96%, TRANS > 90% ACID VALUE (mg KOH/g) < 0,5 SOLUBILITY INSOLUBLE IN WATER VAPOUR PRESSURE < 0,02 mm Hg (200C) OTHER SOLUBILITIES ( SOLUBLE IN ETHANOL OTHER TECHNICAL DATA IT MAY SOLIDIFY AT LOW TEMPERATURES. NITROGEN HEADSPACE ATMOSPHERE IS RECOMMENDED FOR PRESERVATION OF THE PRODUCT. STABILITY AND STORAGE KEEP IN TIGHTLY CLOSED CONTAINER IN A COOL AND DRY PLACE, PROTECTED FROM LIGHT. WHEN STORED FOR MORE THAN 18 MONTHS, QUALITY SHOULD BE CHECKED BEFORE USE. STABILIZED WITH 1000 ppm TBHQ (TERT·BUTYLHYDROQUINONE) AS ANTIOXIDANT. DO NOT HEAT AT MORE THAN 50°C WE BEl.!EVE THE ABOVE lNFORMATION TC BE CORRECT Bl.ff WE DO NOT ?RESENT FAS ALL INCLUSIVE AND ,;5 SUCH SHOULD BE USED AS A GUIDE. IT JS THE SOLE RESPONSIBTUTY OF THE Rf:CEIVER OF OUR r,PQDUCT TO COMPLY WiT!-1 EXISTiNG REGULATTONS AND INSTRUCTIONS. VEGAN iH Wlf· C:l lb f f' 09 October 2023 Product: HEXYL CINNAMIC ALDEHYDE This is to certify that, to the best of our knowledge. the above-mentioned material is suitable for the following diets: 0 Vegan Does not contain any ingredient of anirnal origin (mammalian, poultry, mollusc) or animar fish, crustacean, processing aids. derivatives (dairy, egg and bee products) including additives and V-label: In addition. we confirm that it complies with the requirements listed on Regulations, the Criteria of the that can be found in https://wvi1w.v-label.eu/regulations_text [2J Ve90t..iian Does not contain any ingredient of animal origin (mammalian, poultry, fish. mollusc) or dairy and crustacean. (e.g. honey, egg products. including additives and processing aids. Bee products bees wax) are acceptable. 0 Ovo-Lacto Vegetarian Does not contain any ingredient of animal origin (mammalian, mollusc), including poultry, fish, crustacean, honey, bees wax) are acceptable. additives and processing aids. Dairy. egg and bee products (e.g. 'An1rnaf' refers to the entire animal kinfJdom. i.e. vertebrates and multicellular invertebrates. The iPf0nnat1c,n indic.:ited abo·-;e orres{:'-cn-Js !c, aui knowledge at the d3t'= cf 1,;su-:' Th,s d;;curnent ,s fle·CT.ronicalfy g:;;ne=atJ;;d an<i ter2fore it iS not signr:d