HELIONAL

Hazard statements (CLP)

H317, H361, H411

Code

Statements

H317

May cause an allergic skin reaction

SECTION 2: Hazards identification

1272/2008 Classification of the substance or mixture Skin sensitizer - Category 1 B - H317 Toxic to reproduction - Category 2 • H361 Hazardous to the aquatic environment, long-term (chronic)- Category 2 - H411

2.2 Label elements

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Signal word

Warning

Hazard statements

H317 - May cause an allergic skin reaction. H361 - Suspected of damaging fertility or the unborn child. H411 - Toxic to aquatic life with long lasting effects.

Precautionary statements

P261 -Avoid breathing dust/fume/gas/mist/vapours/spray. P280 -Wear protective gloves/protective clothing/eye protection/face protection. P302+P352+P333+P313 - IF ON SKIN Wash with plenty of soap and water. If skin irritation or rash occurs Get medical advice/attention

Supplemental label elements

Contains ALPHA-METHYL-3,4-METHYLENDIOXYHIDROCINNAMALDEHYDE. May produce an allergic reaction.

2.3 Other hazards

Product not containing any component that meets the criteria for PBT or vPvB according to Regulation (EC) 1907 /2006, Annex XIII. Product not containing any component identified as having endocrine disrupting properties according to Regulation (EU) 2017 /2100. 3.1. Substances Chemical name: ALPHA-M ETHYL-3,4-M ETHYLEN DIOXYH I DROCI N NAMALDEHYDE CAS number: 1205-17-0 EC number: 214-881-6 Hazardous constituents: CAS No. Classification according Specific Concentration Chemical Name 0/o(w/w) EC No.

2.1 Classification of the substance or mixture

Skin sensitizer - Category 1 B - H317 Toxic to reproduction - Category 2 • H361 Hazardous to the aquatic environment, long-term (chronic)- Category 2 - H411 2.2. Label Elements ��� Signal Word: Warning Hazard statements: H317 - May cause an allergic skin reaction. H361 - Suspected of damaging fertility or the unborn child. H411 - Toxic to aquatic life with long lasting effects. Precautionary statements: P261 -Avoid breathing dust/fume/gas/mist/vapours/spray. P280 -Wear protective gloves/protective clothing/eye protection/face protection. P302+P352+P333+P313 - IF ON SKIN: Wash with plenty of soap and water. If skin irritation or rash occurs: Get medical advice/attention. Suplemental Hazard Information: Contains ALPHA-METHYL-3,4-METHYLENDIOXYHIDROCINNAMALDEHYDE. May produce an allergic reaction. 2.3. Other hazards Product not containing any component that meets the criteria for PBT or vPvB according to Regulation (EC) 1907 /2006, Annex XIII. Product not containing any component identified as having endocrine disrupting properties according to Regulation (EU) 2017 /2100. 3.1. Substances Chemical name: ALPHA-M ETHYL-3,4-M ETHYLEN DIOXYH I DROCI N NAMALDEHYDE CAS number: 1205-17-0 EC number: 214-881-6 Hazardous constituents: CAS No. Classification according Specific Concentration Chemical Name 0/o(w/w) EC No. to Regulation 1272/2008 Limit, M-factor, ATE, SVHC Index No. Skin Sens. l B • H317 ALPHA-METHYL-3,4- METHYL EN DIOXYH I DROCI N NAMALDE HYDE 1205-17-0 so Repr. 2 - H361 214-881-6 ATE (oral): 3562 mg/kg Aquatic Chronic 2 - H4ll See the full text of the hazard statements in section 16. 3.2. Mixtures Not applicable. SECTION 4. FIRST-AID MEASURES 4.1. Description of necessary first aid measures Ingestion: Rinse mouth with water. Obtain medical advice. Keep at rest. Do not induce vomiting. Eye contact: In case of contact with eyes, rinse immediately with plenty of water for at least 15 minutes and seek medical advice. Inhalation: Remove person to fresh air and keep at rest. Seek immediate medical advice. Skin contact: Take off immediately all contaminated clothing. Thoroughly wash affected skin with soap and water. Seek medical attention if symptoms persist. 4.2. Most important symptoms and effects, both acute and delayed No information available. 4.3. Indication of any immediate medical attention and special treatment needed No information available. SECTION 5. FIRE-FIGHTING MEASURES 5.1. Extinguishing Media Water spray, carbon dioxide, dry chemical powder or appropriate foam. For safety reasons do not use full water jet. 5.2. Special hazards arising from the substance or mixture Known or Anticipated Hazardous Products of Combustion: Emits toxic fumes under fire conditions. 5.3. Advice for firefighters High temperatures can lead to high pressures inside closed containers. Avoid inhalation of vapors that are created. Use appropriate respiratory protection. Do not allow spillage of fire to be poured into drains or watercourses. Wear self-contained breathing apparatus and protective clothing. .. . ·iSECTION 6. ACCIDENTAL RELEASE MEASURES -·-:_,·.; ,, .-, 6.1. Personal precautions, protective equipment and emergency procedures Evacuate surronding areas. Ensure adequate ventilation. Keep unnecessary and unprotected personnel from entering. Do not breathe vapor/spray. Avoid contact with skin and eyes. Information regarding personal protective measures: see section 8. 6.2. Environmental precautions To avoid possible contamination of the environment, do not discharge into any drains, surface waters or groundwaters. 6.3. Methods and materials for containment and cleaning up Cover with an inert, inorganic, non-combustible absorbent material (e.g. dry-lime, sand, soda ash). Place in covered containers using non-sparking tools and transport outdoors. Avoid open flames or sources of ignition (e.g. pilot lights on gas hot water heater). Ventilate area and wash spill site after material pickup is complete. 6.4. Reference to other sections Information regarding exposure controls, personal protection and disposal considerations can be found in sections 8 and 13. SECTION 7. HANDLING AND STORAGE 7.1. Precautions for safe handling Do not store or handle this material near food or drinking water. Do not smoke. Avoid contact with the eyes, skin and clothing. Wear protective clothing and use glasses. Observe the rules of safety and hygiene at work. Keep in the original container or an alternative made from a compatible material. 7.2. Conditions for safe storage, including any incompatibilities Store in tightly closed and preferably full containers in a cool, dry and ventilated area, protected from light. Keep away from sources of ignition (e.g. hot surfaces, sparks, flame and static discharges). Keep away from incompatible materials (see section 10). 7.3. Specific end use(s) No information available. SECTION 8. EXPOSURE CONTROLS AND PERSONAL PROTECTION 8.1. Control parameters Components with occupational exposure limits: None known. 8.2. Exposure controls Appropriate engineering controls: Measures should be taken to prevent materials from being splashed into the body. Provide adequate ventilation, according to the conditions of use. Use a mechanical exhaust if required. Eye/Face protection: Chemical safety goggles are recommended. Wash contaminated goggles before reuse. Hand Protection: Chemical-resistant gloves are recommended. Wash contaminated gloves before reuse. Body protection: Personal protective equipment for the body should be selected based on the task being performed and the risks involved. Respiratory Protection: In case of insufficient ventilation, use suitable respiratory equipment. Environmental exposure controls: Emissions from ventilation or process equipment should be checked to ensure they comply with environmental protection legislation. In some cases, filters or engineering modifications to the process equipment will be necessary to reduce emissions to acceptable levels. SECTION 9. PHYSICAL AND CHEMICAL PROPERTIES 9.1. Information on basic physical and chemical properties Physical sate: Liquid Colour: Conforms to standard Odour: Conforms to standard Melting point/freezing point: Not determined Boiling point or initial boiling point and range (0C): 282 Flammability: Not determined Lower and upper explosion limit: Not determined Flash point: 101 °c Auto-ignition temperature: Not Decomposition temperature: determined Not pH: determined Kinematic viscosity: Not determined Solubility: Not ESSENTIALLY determined INSOLUBLE IN WATER/SOLUBLE IN ETHANOL Partition coefficient n-octanol/water (log value): Not determined Vapour pressure: Not determined Density and/or relative density: 1,159-1,167 g/mL (20°c) / 1,159-1,167 (20°() Relative vapour density: Not determined Particle characteristics: Not determined 9.2. Other information 9.2.1. Information with regard to phyical hazard classes: No information avaliable. 9.2.2. Other safety characteristics: No information avaliable SECTION 10. STABILITY AND REACTIVITY 10.1. Reactivity No hazardous reactions if stored and handled as prescribed/indicated. 10.2. Chemical stability The product is stable if stored and handled as prescribed/indicated. 10.3. Possibility of hazardous reactions No hazardous reactions if stored and handled as prescribed/indicated. 10.4. Conditions to Avoid Conditions to Avoid: Excessive heat, flame or other ignition sources. 10.5. Incompatible materials Avoid contact with strong acids and bases and oxidizing agents. 10.6. Hazardous decomposition products During combustion may form carbon monoxide and unidentified organic compounds. SECTION 11. TOXICOLOGICAL INFORMATION 11.1. Information on hazard classes as defined in Regulation (EC) No 1272/2008 Acute toxicity Based on the data avaitable, the criteria for classification are not met. Skin corrosion/irritation Based on the data available, the criteria for classification are not met. Serious eye damage/irritation Based on the data available, the criteria for classification are not met. Respiratory or skin sensitisation May cause an allergic skin reaction. Germ cell mutagenicity Based on the data available, the criteria for classification are not met. Carcinogenicity Based on the data available, the criteria for classification are not met. Reproductive toxicity Suspected of damaging fertility or the unborn child. STOT-single exposure Based on the data available, the criteria for classification are not met. STOT-repeated exposure Based on the data available, the criteria for classification are not met. Aspiration hazard Based on the data available, the criteria for classification are not met. 11.2. Information on other hazards 11.2.1. Endocrine disrupting properties: Product not containing any component identified as having endocrine disrupting properties according to Regulation (EU) 2017/2100. 11.2.2. Other information: No information available r���!•§ijlr .�.c��P.§.!. £�1-!��§���fi§]}lfl{[)i��};I11[k ::,"tb:·;gJ:t :J.· .. 12.1. Toxicity Assessment: Toxic to aquatic life with long lasting effects. Experimental/calculated data: No information available. 12.2. Persistence and degradability The product is not readily biodegradable 12.3. Bioaccumulative potential No information available. 12.4. Soil mobility No information available. 12.S. Results of PBT and vPvB assessment Product not containing any component that meets the criteria for PBT or vPvB according to Regulation (EC) 1907 /2006, Annex XIII. 12.6. Endocrine disrupting properties Product not containing any component identified as having endocrine disrupting properties acco:_ding to Regulation (EU) 2017 /2100. 12.7. Other adverse effects See also sections 6, 7, 13 and 15 Do not allow to get into waste water or waterways. SECTION 13. DISPOSAL CONSIDERATIONS 13.1. Waste treatment methods Dispose of in accordance with national and local environmental regulations. SECTION 14: TRANSPORT INFORMATION ADR/RID/ADN IMDG IATA-ICAO 14.1. UN Number UN3082 14.2. UN Proper Shipping Name ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S. (ALPHA- METHYL-3,4- METHYLENDIOXYHIDROCINNAMALDEH M0ETHYLENDIOXYHIDROCINNAMALDEH ET HYLEN DI OXYH IDROCI N NAMALDEH IYDE) 14.3. Transport Hazard Class(es) 9 14.4. Packing Group Ill 14.5. Environmental hazards Yes Additional information 14.6 Special precautions for user None known 14.7. Maritime transport in bulk according to IMO instruments No information available SECTION 15: REGULATORY INFORMATION 15.1. Safety, health and environmental regulations/legislation specific for the substance or mixture No information available 15.2. Chemical safety assessment No chemical safety assessment has been carried out for the substance or mixture by the supplier SECTION 16: OTHER INFORMATION Full text of the R-phrases, hazard statements and precautionary statements mentioned in section 3: H317 - May cause an allergic skin reaction. H361 - Suspected of damaging fertility or the unborn child. H411 - Toxic to aquatic life with lorg lasting effects. SPECIFICATION SHEET VERSION 3,00 VERSION DATE 11/11/20 PRINT DATE 14/12/23 PRODUCT HELIONAL APPLICATIONS Industrial raw material not intended for direct use. IUPAC NAME ALPHA-METHYL-1,3-BENZODIOXOLE-5-PROPIONALDEHYDE SYNONYMS 3-(3,4-METHYLENDIOXYPHENYL)-2-METHYLPROPANAL, OCEAN PROPANAL, HELIONAL FORMULA Cll H12 03 MOLECULAR WEIGHT 192,21 CAS O-__ _.,,,..,.,.,.-"-- 1205-17-0 '"--, _ _,..-,-CHO .--... / 0 1(--<::-r/ ,_ /- <..___..-'_.,,,. \ ) l EINECS 214-881-6 FEMA 4599 "-._/" TARIFF NUMBER 2932990051 REACH REGISTRATION NO. 01-2120740119-58 SPECIFICATIONS ASPECT AT 20°C CLEAR MOBILE LIQUID COLOUR COLORLESS TO PALE YELLOW ODOUR FRESH,FLORAL,MELON,OZONE,MARINE TASTE DENSITY AT 20°c (g / ml) 1,159 - 1,167 DENSITY 25/25 1,157 - 1,165 REFRACTIVE INDEX nD20 1,5310 - 1,5380 REFRACTIVE INDEX nD25 1,5330 - 1,5400 OPTICAL ROTATION (0) I BOILING POINT (°C) 282 MEL TING POINT (°C) FLASH POINT (0C) 101,00 ASSAY(% GC) > 98 ACID VALUE (mg KOH/g) <5 SOLUBILITY ESSENTIALLY INSOLUBLE IN WATER VAPOUR PRESSURE NOT DETERMINED OTHER SOLUBILITIES SOLUBLE IN ETHANOL OTHER TECHNICAL DATA OTHER SYNONYM: ALPHA-METHYL -3 ,4-METHYLEN DIOXYHIDROCI N NAMALDEHYDE. COLOUR DARKENS WITH TIME. STABILITY AND STORAGE KEEP IN TIGHTLY CLOSED CONTAINER IN A COOL AND DRY PLACE, PROTECTED FROM LIGHT. WHEN STORED FOR MORE THAN 12 MONTHS, QUALITY SHOULD BE CHECKED BEFORE USE. IT MAY CONTAIN 0,1 % OF TBHQ AS STABILIZER. WE BELIEVE THE ABOVE INFORMATION TO BE CORRECT BUT WE DQ.NOT PRESENT IT AS ALL INCLUSIVE AND AS SUCH SHOULD BE USED I\._S A GUIDE. IT IS THE SOLE RESPONSJB!UTY OF THE RECEIVER OF OUR PRODUCT TO COMPLY WITH EXISTING REGULATIONS AND INSTRUCTIONS. THIS PRODUCT HAS NOT BEEN FILTERED DUE TO TECHNICAL REASONS. WE RECOMMEND NOT TO USE IT UNLESS FILTERED WHEN USED AS A RAW MATERIAL IN FOOD INTENDED FOR FINAL CONSUMERS. VEGAN CERTIFICATE 14 December 2023 Product: HELIONAL This is to certify that, to the best of our knowledge, the above-mentioned material is suitable for the following diets: [Z] Vegan Does not contain any ingredient of animal origin (mammalian, poultry, fish, crustacean, mollusc) or animal derivatives (dairy, egg and bee products) including additives and processing aids. In addition, we confirm that it complies with the requirements listed on the Criteria of the V-label: Regulations, that can be found in https://www.v-label.eu/regulations_text [Z] Vegetarian Does not contain any ingredient of animal origin (mammalian, poultry, fish, crustacean, mollusc) or dairy and egg products, including additives and processing aids. Bee products (e.g. honey, bees wax) are acceptable. [Z] Ovo-Lacto Vegetarian Does not contain any ingredient of animal origin (mammalian, poultry, fish, crustacean, mollusc), including additives and processing aids. Dairy, egg and bee products (e.g. honey, bees wax) are acceptable. 'Animal' refers to the entire animal kingdom, i.e. vertebrates and multicellular invertebrates. The information indicated above corresponds to our knowledge at the date of issue. This document is electronically generated and therefore it is not signed.