GREEN APPLE

Hazard statements (CLP)

H400, H411

Code

Statements

H400

Very toxic to aquatic life

SECTION 2: Hazards identification

Signal word

Warning

Hazard statements

H400, Very toxic to aquatic life. H411, Toxic to aquatic life with long lasting effects.

Additional information

EUH208, Contains Amyl Cinnamal, Dimethylcyclohex-3-ene-1-carboxaldehyde, Isocyclocitral. May produce an allergic reaction.

Precautionary statements

P273, Avoid release to the environment. P391, Collect spillage. P501, Dispose of contents/container to approved disposal site, in accordance with local regulations.

Hazard pictograms

Unique Formula Identifier (UFI) GQ23-VWG8-V00D-9G6Q

Other hazards

None

2.1 Classification of the substance or mixture

Classification under Regulation (EC) No 1272/2008 Class and category of Hazardous to the Aquatic Environment - Acute Hazard Category 1 danger: Hazardous to the Aquatic Environment - Long-term Hazard Category 2 H400, Very toxic to aquatic life. H411, Toxic to aquatic life with long lasting effects. 2.2 Label elements Classification under Regulation (EC) No 1272/2008 Signal word: Warning Hazard statements: H400, Very toxic to aquatic life. H411, Toxic to aquatic life with long lasting effects. 2 Supplemental EUH208, Contains Amyl Cinnamal, Dimethylcyclohex-3-ene-1-carboxaldehyde, Isocyclocitral. Information: May produce an allergic reaction. Precautionary P273, Avoid release to the environment. statements: P391, Collect spillage. P501, Dispose of contents/container to approved disposal site, in accordance with local regulations. Pictograms: Unique Formula GQ23-VWG8-V00D-9G6Q Identifier (UFI): 2.3 Other hazards Other hazards: None Section 3. Composition / information on ingredients 3.2 Mixtures Contains: REACH Registration Classification for Name CAS EC % No. (CLP) 1272/2008 Acute Tox. 4-Aquatic Benzyl Benzoate 120-51-4 204-402-9 01-2119976371-33-XXXX 10-<20% Acute 1-Aquatic Chronic 2;H302-H400- H411,- Acute Tox. 3-Acute Tox. 3-Aquatic Acute 1- Allyl heptanoate 142-19-8 205-527-1 01-2119488961-23-XXXX 5-<10% Aquatic Chronic 3; H301-H311-H400- H412,- cis-2-tert- 20298-69-5, 243-718-1, 01-2119970713-33-XXXX 5-<10% Aquatic Chronic 2; Butylcyclohexyl acetate 88-41-5 201-828-7 H411,- gamma-Undecalactone 104-67-6 203-225-4 01-2119959333-34-XXXX 1-<5% Aquatic Chronic 3; H412,- 1,3,4,6,7,8-Hexahydro- Aquatic Acute 1- 4,6,6,7,8,8- 1222-05-5 214-946-9 01-2119488227-29-XXXX 1-<5% Aquatic Chronic 1; Hexamethylcyclopenta- H410,- gamma-2-benzopyran Diethyl malonate 105-53-3 203-305-9 01-2119886972-18-XXXX 1-<5% Eye Irrit. 2;H319,- alpha-Ionone 127-41-3 204-841-6 01-2120138061-71-XXXX 1-<5% Aquatic Chronic 3; or natural source H412,- 5-Acetyl-3-isopropyl- Acute Tox. 4-Aquatic 1,1,2,6- 68140-48-7 268-799-0 Exempt <1 tonne/pa 1-<5% Acute 1-Aquatic tetramethylindane Chronic 1;H302-H410,- 2 Skin Irrit. 2-Eye Irrit. 2- Isocyclocitral 1335-66-6 215-638-7 Exempt < 1 Tonne/PA 0.1-<1% Skin Sens. 1B-Aquatic Chronic 3;H315-H317- H319-H412,- 1-(5,6,7,8-Tetrahydro- 1506-02-1, Acute Tox. 4-Aquatic 3,5,5,6,8,8-hexamethyl- 21145-77-7 216-133-4 01-2119539433-40-XXXX 0.1-<1% Acute 1-Aquatic 2-naphthyl)ethan-1-one Chronic 1;H302-H410,- 248-742-6, 27939-60-2, Skin Irrit. 2-Skin Sens. Dimethylcyclohex-3- 68039-49-6, 268-264-1, 01-2119982384-28-XXXX 0.1-<1% 1-Aquatic Chronic 2; ene-1-carboxaldehyde 68039-48-5 268-263-6, H315-H317-H411,- 943-728-2 01-2120756398-40-XXXX Aquatic Acute 1- Ethyl heptanoate 106-30-9 203-382-9 01-2120104876-54-XXXX 0.1-<1% Aquatic Chronic 3; H400-H412,- Amyl Cinnamal 122-40-7 204-541-5 01-2119978288-18-XXXX 0.1-<1% Skin Sens. 1B-Aquatic Chronic 2;H317-H411,- Substances with Community workplace exposure limits: REACH Registration Classification for Name CAS EC % No. (CLP) 1272/2008 Diethyl Phthalate 84-66-2 201-550-6 01-2119486682-27-XXXX 50-100% -;-,- Substances that are persistent, bioaccumulative and toxic or very persistent and very bioaccumulative, greater than 0.1%: Not Applicable Section 4. First-aid measures 4.1 Description of first aid measures Inhalation: Remove from exposure site to fresh air, keep at rest, and obtain medical attention. Eye exposure: Flush immediately with water for at least 15 minutes. Contact physician if symptoms persist. Skin exposure: Remove contaminated clothes. Wash thoroughly with soap and water. Contact physician if irritation persists. Ingestion: Rinse mouth with water and obtain medical attention. 4.2 Most important symptoms and effects, both acute and delayed None expected, see Section 4.1 for further information. 4.3 Indication of any immediate medical attention and special treatment needed None expected, see Section 4.1 for further information. SECTION 5: Firefighting measures 5.1 Extinguishing media Suitable media: Carbon dioxide, Dry chemical, Foam. 5.2 Special hazards arising from the substance or mixture In case of fire, may be liberated: Carbon monoxide, Unidentified organic compounds. 2 5.3 Advice for fire fighters: In case of insufficient ventilation, wear suitable respiratory equipment. Section 6. Accidental release measures 6.1 Personal precautions, protective equipment and emergency procedures: Avoid inhalation. Avoid contact with skin and eyes. See protective measures under Section 7 and 8. 6.2 Environmental precautions: Keep away from drains, surface and ground water, and soil. 6.3 Methods and material for containment and cleaning up: Remove ignition sources. Provide adequate ventilation. Avoid excessive inhalation of vapours. Contain spillage immediately by use of sand or inert powder. Dispose of according to local regulations. 6.4 Reference to other sections: Also refer to sections 8 and 13. Section 7. Handling and storage 7.1 Precautions for safe handling: Keep away from heat, sparks, open flames and hot surfaces. - No smoking. Use personal protective equipment as required. Use in accordance with good manufacturing and industrial hygiene practices. Use in areas with adequate ventilation Do not eat, drink or smoke when using this product. 7.2 Conditions for safe storage, including any incompatibilities: Store in a well-ventilated place. Keep container tightly closed. Keep cool. Ground/bond container and receiving equipment. Use explosion-proof electrical, ventilating and lighting equipment. Use only non-sparking tools. Take precautionary measures against static discharge. 7.3 Specific end use(s): Fragrances: Use in accordance with good manufacturing and industrial hygiene practices. Section 8. Exposure controls/personal protection 8.1 Control parameters Workplace exposure limits: 2 Ingredient CAS EC Description Value UK WEL Long term mgm3 5 mg/m³ UK WEL Short term mgm3 10 mg/m³ Diethyl Phthalate 84-66-2 201-550-6 EU Long-term exposure limit (8-hour TWA) 5 (mg/m3) EU Short-term exposure limit (15-minute) 10 (mg/m3) 8.2 Exposure Controls Eye / Skin Protection Wear protective gloves/eye protection/face protection Respiratory Protection Ensure adequate and ongoing ventilation is maintained in order to prevent build up of excessive vapour and to ensure occupational exposure limits are adhered to. If appropriate, and depending on your patterns and volumes of use, the following engineering controls may be required as additional protective measures: a) Isolate mixing rooms and other areas where this material is used or openly handled. Maintain these areas under negative air pressure relative to the rest of the plant. b) Employ the use of Personal protective equipment - an approved, properly fitted respirator with organic vapour cartridges or canisters and particulate filters. c) Use local exhaust ventilation around open tanks and other open sources of potential exposures in order to avoid excessive inhalation, including places where this material is openly weighed or measured. In addition, use general dilution ventilation of the work area to eliminate or reduce possible worker exposures. d) Use closed systems for transferring and processing this material. Also refer to Sections 2 and 7. Section 9. Physical and chemical properties 9.1 Information on basic physical and chemical properties Appearance: COLOURLESS TO PALE YELLOW LIQUID Odour: CHARACTERISTIC Odour threshold: Not determined pH: Not determined Melting point / freezing point: Not determined Initial boiling point / range: Not determined Flash point (CC): > 62 °C Evaporation rate: Not determined Flammability (solid, gas): Not determined Upper/lower flammability or explosive limits: Product does not present an explosion hazard Vapour pressure: Not determined Vapour density: Not determined Relative density: 1.0490 - 1.0690 2 Solubility(ies): Not determined Partition coefficient: n-octanol/water: Not determined Auto-ignition temperature: Not determined Decomposition temperature: Not determined Viscosity: Not determined Explosive properties: Not expected Oxidising properties: Not expected 9.2 Other information: None available Section 10. Stability and reactivity 10.1 Reactivity: Presents no significant reactivity hazard, by itself or in contact with water. 10.2 Chemical stability: Good stability under normal storage conditions. 10.3 Possibility of hazardous reactions: Not expected under normal conditions of use. 10.4 Conditions to avoid: Avoid extreme heat. 10.5 Incompatible materials: Avoid contact with strong acids, alkalis or oxidising agents. 10.6 Hazardous decomposition products: Not expected. Section 11. Toxicological information 11.1 Information on toxicological effects This mixture has not been tested as a whole for health effects. The health effects have been calculated using the methods outlined in Regulation (EC) No 1272/2008 (CLP). This material does not meet the criteria for classification for health hazards under Regulation (EC) No 1272/2008. Acute Toxicity: Based on available data the classification criteria are not met. Acute Toxicity Oral 2212 Acute Toxicity Dermal >5000 Acute Toxicity Inhalation Not Available Skin corrosion/irritation: Based on available data the classification criteria are not met. Serious eye damage/irritation: Based on available data the classification criteria are not met. Respiratory or skin sensitisation: Based on available data the classification criteria are not met. Germ cell mutagenicity: Based on available data the classification criteria are not met. Carcinogenicity