GALAXOLIDE 50% IPM

Hazard statements (CLP)

H400, H410

Code

Statements

H400

Very toxic to aquatic life

SECTION 2: Hazards identification

Regulation (EC) No. 1272/2008 Classification of the substance or mixture

Signal word

Warning

Hazard statements

H410 - Very toxic to aquatic life with long lasting effects

Precautionary statements

P102 - Keep out of reach of children P273 - Avoid release to the environment P501 - Dispose of contents/container in accordance with local, regional, national, and international regulations as applicable

2.3 Other hazards

Causes mild skin irritation.

2.1 Classification of the substance or mixture

Regulation (EC) No 1272/2008 Acute aquatic toxicity Category 1 - (H400) Chronic aquatic toxicity Category 1 - (H410) 2.2. Label elements Signal word Warning Hazard statements H410 - Very toxic to aquatic life with long lasting effects Precautionary Statements - EU (§28, 1272/2008) P102 - Keep out of reach of children P273 - Avoid release to the environment P501 - Dispose of contents/container in accordance with local, regional, national, and international regulations as applicable 2.3. Other hazards Causes mild skin irritation. SECTION 3: Composition/information on ingredients 3.1 Substances Not applicable 3.2 Mixtures Chemical name Weight-% REACH registration EC No (EU Classification Specific M-Factor number Index No) according to concentration (long-term) Regulation (EC) No. limit (SCL) 1272/2008 [CLP] Galaxolide 50 - <60 01-2119488227-29- - Skin Irrit. 3 (H316) - 1222-05-5 Aquatic Acute 1 (H400) Aquatic Chronic 1 (H410) Isopropyl 40 - <50 01-2119541806-35- - Not classified - myristate 110-27-0 Full text of H- and EUH-phrases: see section 16 Acute Toxicity Estimate No information available This product does not contain candidate substances of very high concern at a concentration >=0.1% (Regulation (EC) No. 1907/2006 (REACH), Article 59) SECTION 4: First aid measures 4.1. Description of first aid measures Inhalation Remove to fresh air. Eye contact Rinse thoroughly with plenty of water for at least 15 minutes, lifting lower and upper eyelids. Consult a physician. Skin contact Wash skin with soap and water. In the case of skin irritation or allergic reactions see a physician. Ingestion Rinse mouth. 4.2. Most important symptoms and effects, both acute and delayed Symptoms No information available. 4.3. Indication of any immediate medical attention and special treatment needed Note to physicians Treat symptomatically. SECTION 5: Firefighting measures 5.1. Extinguishing media Suitable Extinguishing Media Use extinguishing measures that are appropriate to local circumstances and the surrounding environment. Large Fire CAUTION: Use of water spray when fighting fire may be inefficient. Unsuitable extinguishing media Do not scatter spilled material with high pressure water streams. 5.2. Special hazards arising from the substance or mixture Specific hazards arising from the No information available. chemical Hazardous combustion products Irritating or toxic substances may be emitted upon burning, combustion, or decomposition. 5.3. Advice for firefighters Special protective equipment and Firefighters should wear self-contained breathing apparatus and full firefighting turnout precautions for fire-fighters gear. Use personal protection equipment. SECTION 6: Accidental release measures 6.1. Personal precautions, protective equipment and emergency procedures Personal precautions Ensure adequate ventilation. For emergency responders Use personal protection recommended in Section 8. 6.2. Environmental precautions Environmental precautions See Section 12 for additional Ecological Information. 6.3. Methods and material for containment and cleaning up Methods for containment Prevent further leakage or spillage if safe to do so. Methods for cleaning up Take up mechanically, placing in appropriate containers for disposal. Prevention of secondary hazards Clean contaminated objects and areas thoroughly observing environmental regulations. 6.4. Reference to other sections Reference to other sections See section 8 for more information. See section 13 for more information. SECTION 7: Handling and storage 7.1. Precautions for safe handling Advice on safe handling Ensure adequate ventilation. General hygiene considerations Handle in accordance with good industrial hygiene and safety practice. 7.2. Conditions for safe storage, including any incompatibilities Storage Conditions Keep container tightly closed in a dry and well-ventilated place. 7.3. Specific end use(s) Risk Management Methods (RMM) The information required is contained in this Safety Data Sheet. SECTION 8: Exposure controls/personal protection 8.1. Control parameters Exposure Limits This product, as supplied, does not contain any hazardous materials with occupational exposure limits established by the region specific regulatory bodies. Biological occupational exposure This product, as supplied, does not contain any hazardous materials with biological limits limits established by the region specific regulatory bodies. Derived No Effect Level (DNEL) No information available. Predicted No Effect Concentration No information available. (PNEC) 8.2. Exposure controls Engineering controls No information available. Personal Protective Equipment Eye/face protection No special protective equipment required. Skin and body protection No special protective equipment required. Respiratory protection No protective equipment is needed under normal use conditions. If exposure limits are exceeded or irritation is experienced, ventilation and evacuation may be required. General hygiene considerations Handle in accordance with good industrial hygiene and safety practice. Environmental exposure controls No information available. SECTION 9: Physical and chemical properties 9.1. Information on basic physical and chemical properties Physical state Liquid Appearance Clear Color Colorless to almost colorless Odor Characteristic odor. Odor threshold No information available Property Values Remarks • Method Melting point / freezing point No data available None known Boiling point / boiling range No data available Flammability (solid, gas) No data available None known Flammability Limit in Air None known Upper flammability limit: No data available Lower flammability limit: No data available Flash Point > 100 °C CC (closed cup) Autoignition Temperature No data available None known Decomposition temperature None known pH No data available None known pH (as aqueous solution) No data available None known Kinematic viscosity No data available None known Dynamic viscosity No data available None known Water solubility No data available None known solubility(ies) No data available None known Partition coefficient No data available None known Vapor pressure No data available Relative density 0.938 - 0.950 (25°C) Bulk Density No data available Density No data available Vapor Density No data available None known Particle characteristics Particle Size No information available Particle Size Distribution No information available 9.2. Other information 9.2.1. Information with regard to physical hazard classes Not applicable 9.2.2. Other safety characteristics No information available SECTION 10: Stability and reactivity 10.1. Reactivity Reactivity No information available. 10.2. Chemical stability Stability Stable under normal conditions. Explosion data Sensitivity to mechanical impact None. Sensitivity to static discharge None. 10.3. Possibility of hazardous reactions Possibility of hazardous reactions None under normal processing. 10.4. Conditions to avoid Conditions to avoid None known based on information supplied. 10.5. Incompatible materials Incompatible materials None known based on information supplied. 10.6. Hazardous decomposition products Hazardous Decomposition Products None known based on information supplied. SECTION 11: Toxicological information 11.1. Information on hazard classes as defined in Regulation (EC) No 1272/2008 Information on likely routes of exposure Product Information Inhalation Specific test data for the substance or mixture is not available. Eye contact Specific test data for the substance or mixture is not available. Skin contact Specific test data for the substance or mixture is not available. Ingestion Specific test data for the substance or mixture is not available. Symptoms related to the physical, chemical and toxicological characteristics Symptoms No information available. Acute toxicity Numerical measures of toxicity No information available 100 % of the mixture consists of ingredient(s) of unknown acute oral toxicity. 100 % of the mixture consists of ingredient(s) of unknown acute dermal toxicity. 100 % of the mixture consists of ingredient(s) of unknown acute inhalation toxicity (gas). 100 % of the mixture consists of ingredient(s) of unknown acute inhalation toxicity (vapor). 100 % of the mixture consists of ingredient(s) of unknown acute inhalation toxicity (dust/mist). Chemical name Oral LD50 Dermal LD50 Inhalation LC50 Galaxolide 1 Rat > 4640 mg/kg Female 2 - (reliable with restrictions) 2 Rat > 5000 mg/kg Female, Male 2 (reliable with restrictions) Isopropyl myristate 1 Mouse > 5000 mg/kg Female, - Male 2 (reliable with restrictions) 2 Rat > 2000 mg/kg Female, Male 1 (reliable without restriction) 3 Rat > 4300 mg/kg Female, Male 2 (reliable with restrictions) Delayed and immediate effects as well as chronic effects from short and long-term exposure Skin corrosion/irritation Causes mild skin irritation. Serious eye damage/eye irritation No information available. Respiratory or skin sensitization No information available. Germ cell mutagenicity No information available. Carcinogenicity No information available. Reproductive toxicity No information available. STOT - single exposure No information available. STOT - repeated exposure No information available. Aspiration hazard No information available. 11.2. Information on other hazards 11.2.1. Endocrine disrupting properties Endocrine disrupting properties No information available. 11.2.2. Other information Other adverse effects No information available. SECTION 12: Ecological information 12.1. Toxicity Ecotoxicity Toxic to aquatic life with long lasting effects. Unknown aquatic toxicity Contains 50 % of components with unknown hazards to the aquatic environment. 12.2. Persistence and degradability Persistence and degradability No information available. _____________________________________________________________________________________________ 12.3. Bioaccumulative potential Bioaccumulation There is no data for this product. Chemical name Partition coefficient Isopropyl myristate 7.17 12.4. Mobility in soil Mobility in soil No information available. 12.5. Results of PBT and vPvB assessment PBT and vPvB assessment 12.6. Other adverse effects Endocrine disrupting properties No information available. 12.7. Other adverse effects No information available. SECTION 13: Disposal considerations 13.1. Waste treatment methods Waste from residues/unused Dispose of in accordance with local regulations. Dispose of waste in accordance with products environmental legislation. Contaminated packaging Do not reuse empty containers. SECTION 14: Transport information IATA 14.1 UN number or ID number 3082 14.2 UN proper shipping name Environmentally hazardous substance, liquid, n.o.s. 14.3 Transport hazard class(es) 9 14.4 Packing group III Description (1,3,4,6,7,8-Hexahydro-4,6,6,7,8,8-hexamethylcyclopenta-y-2-benzopyran) 14.5 Environmental hazard Yes 14.6 Special precautions for user Special Provisions A97, A158, A197 ERG Code 9L IMDG 14.1 UN number or ID number 3082 14.2 UN proper shipping name Environmentally hazardous substance, liquid, n.o.s. 14.3 Transport hazard class(es) 9 14.4 Packing group III Description (1,3,4,6,7,8-Hexahydro-4,6,6,7,8,8-hexamethylcyclopenta-y-2-benzopyran) 14.5 Environmental hazard Yes 14.6 Special precautions for user Special Provisions 274, 335, 969 EmS-No F-A, S-F 14.7 Maritime transport in bulk IBC02 according to IMO instruments RID 14.1 UN/ID no 3082 14.2 UN proper shipping name Environmentally hazardous substance, liquid, n.o.s. 14.3 Transport hazard class(es) 9 14.4 Packing group III Description (1,3,4,6,7,8-Hexahydro-4,6,6,7,8,8-hexamethylcyclopenta-y-2-benzopyran) 14.5 Environmental hazard Yes 14.6 Special precautions for user Special Provisions None ADR 14.1 UN number or ID number 3082 14.2 UN proper shipping name Environmentally hazardous substance, liquid, n.o.s. 14.3 Transport hazard class(es) 9 14.4 Packing group III Description (1,3,4,6,7,8-Hexahydro-4,6,6,7,8,8-hexamethylcyclopenta-y-2-benzopyran) 14.5 Environmental hazard Yes 14.6 Special precautions for user Special Provisions 274, 335, 375, 601 Classification code M6 Tunnel restriction code (-) SECTION 15: Regulatory information 15.1. Safety, health and environmental regulations/legislation specific for the substance or mixture Water hazard class (WGK) obviously hazardous to water (WGK 2) European Union Take note of Directive 98/24/EC on the protection of the health and safety of workers from the risks related to chemical agents at work. Authorizations and/or restrictions on use: This product does not contain substances subject to authorization (Regulation (EC) No. 1907/2006 (REACH), Annex XIV) This product does not contain substances subject to restriction (Regulation (EC) No. 1907/2006 (REACH), Annex XVII) Persistent Organic Pollutants Not applicable Ozone-depleting substances (ODS) regulation (EC) 1005/2009 Not applicable International Inventories TSCA Contact supplier for inventory compliance status DSL/NDSL Contact supplier for inventory compliance status EINECS/ELINCS Contact supplier for inventory compliance status ENCS Contact supplier for inventory compliance status IECSC Contact supplier for inventory compliance status KECL Contact supplier for inventory compliance status PICCS Contact supplier for inventory compliance status AICS Contact supplier for inventory compliance status NZIoC Contact supplier for inventory compliance status Legend: TSCA - United States Toxic Substances Control Act Section 8(b) Inventory DSL/NDSL - Canadian Domestic Substances List/Non-Domestic Substances List EINECS/ELINCS - European Inventory of Existing Chemical Substances/European List of Notified Chemical Substances ENCS - Japan Existing and New Chemical Substances IECSC - China Inventory of Existing Chemical Substances KECL - Korean Existing and Evaluated Chemical Substances PICCS - Philippines Inventory of Chemicals and Chemical Substances AICS - Australian Inventory of Chemical Substances NZIoC - New Zealand Inventory of Chemicals 15.2. Chemical safety assessment Chemical Safety Report No information available SECTION 16: Other information Key or legend to abbreviations and acronyms used in the safety data sheet Full text of H-Statements referred to under section 3 H400 - Very toxic to aquatic life H410 - Very toxic to aquatic life with long lasting effects Legend SVHCL LEG8 SECTION 8: Exposure controls/personal protection TWA TWA (time-weighted average) STEL STEL (Short Term Exposure Limit) Ceiling Maximum limit value * Skin designation + Sensitizers Key literature references and sources for data used to compile the SDS Agency for Toxic Substances and Disease Registry (ATSDR) U.S. Environmental Protection Agency ChemView Database European Food Safety Authority (EFSA) European Chemicals Agency (ECHA) Committee for Risk Assessment (ECHA_RAC) European Chemicals Agency (ECHA) (ECHA_API) EPA (Environmental Protection Agency) Acute Exposure Guideline Level(s) (AEGL(s)) U.S. Environmental Protection Agency Federal Insecticide, Fungicide, and Rodenticide Act U.S. Environmental Protection Agency High Production Volume Chemicals Food Research Journal Hazardous Substance Database International Uniform Chemical Information Database (IUCLID) National Institute of Technology and Evaluation (NITE) Australia National Industrial Chemicals Notification and Assessment Scheme (NICNAS) NIOSH (National Institute for Occupational Safety and Health) National Library of Medicine's ChemID Plus (NLM CIP) National Library of Medicine’s PubMed database (NLM PUBMED) National Toxicology Program (NTP) New Zealand's Chemical Classification and Information Database (CCID) Organization for Economic Co-operation and Development Environment, Health, and Safety Publications Organization for Economic Co-operation and Development High Production Volume Chemicals Program Organization for Economic Co-operation and Development Screening Information Data Set World Health Organization Revision date 09-Dec-2022 This material safety data sheet complies with the requirements of Regulation (EC) No. 1907/2006 Disclaimer The information provided in this Safety Data Sheet is correct to the best of our knowledge, information and belief at the date of its publication. The information given is designed only as a guidance for safe handling, use, processing, storage, transportation, disposal and release and is not to be considered a warranty or quality specification. The information relates only to the specific material designated and may not be valid for such material used in combination with any other materials or in any process, unless specified in the text This material has not been tested or proven safe for inhalation. With this document, we only attest to the safety of the product when used in the appropriate and suitable fragrance/flavor industry application. Classification and labeling according to the IFRA/IOFI labeling Manual 2020. End of Safety Data Sheet GAL0006 CAS#: FEMA#: PRODUCT SPECIFICATION PRODUCT IDENTIFICATION MOLECULAR FORM MOLECULAR WT MELTING POINT (C) BOILING POINT (C) FLASH POINT (F) 212 deg F SHELF LIFE (DAYS) 730 PHYSICAL SPECIFICATIONS RANGE METHOD APPEARANCE CLEAR COLORLESS TO SLIGHT OFF-WHITE VISUAL LIQUID ODOR CHARACTERISTIC OF POWERFUL, PERSISTENT ORGANOLEPTIC MUSK SPECIFIC GRAVITY (25C) 0.9380 to 0.9500 FCC METHOD REFRACTIVE INDEX (20C) 1.4880 to 1.4980 FCC METHOD ANALYTICAL SPECIFICATIONS RANGE METHOD GC ANALYSIS PROFILE TO MATCH STANDARD CHEM_20.M PURITY (BY GC) GALAXOLIDE PEAK: 48 - 52% STABILITY STABLE UNDER NORMAL CONDITIONS STORAGE STORE IN COOL DRY PLACE AWAY FROM HEAT AND SUNLIGHT. SHELF LIFE CONSIDERATIONS APPLY ONLY FOR ORIGINAL UNOPENED CONTAINERS 19-20 Sandleheath Industrial Estate, Fordingbridge, Hampshire, SP6 1PA, UK Tel: 01425 655555 Email: technical@madarcorporation.co.uk DIETS DECLARATION We hereby certify that: GALAXOLIDE 50% IPM To the best of our knowledge is suitable for: Yes No Ovo-lacto Vegetarians  Vegetarians  Vegans  Coeliacs  Kosher  Halal  (Not certified) Date of issue: 03/05/2023 19-20 Sandleheath Industrial Estate, Fordingbridge, Hampshire, SP6 1PA, UK