Four Thieves Madar Corp

MADAR Corporation Limited

Revision date : 2018-11-23

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GHS02 GHS07 GHS08 GHS09
Health risk rating 4
Safety risk rating 2
Environmental risk rating 5

Note: Ingredients listed on restricted chemical lists

EC/CAS

202-589-1/97-53-0

Name of the chemical

eugenol

Concentration

20-<50%

EC/CAS

227-813-5/5989-27-5

Name of the chemical

(R)-p-mentha-1,8-diene

Concentration

20-<50%

EC/CAS

203-213-9/104-55-2

Name of the chemical

Cinnamaldehyde/3-phenyl-propen-2-al

Concentration

10-<20%

EC/CAS

201-746-1/87-44-5

Name of the chemical

(1R,4E,9S)-4,11,11-Trimethyl-8-methylenebicyclo[7.2.0]undec-4-ene (40)

Concentration

5-<10%

EC/CAS

202-235-6/93-28-7

Name of the chemical

Phenol, 2-methoxy-4-(2-propenyl)-, acetate (40)

Concentration

1-<5%

EC/CAS

204-872-5/127-91-3

Name of the chemical

β-pinene

Concentration

1-<5%

EC/CAS

202-794-6/99-85-4

Name of the chemical

gamma-Terpinene; p-Mentha-1,4-diene

Concentration

1-<5%

EC/CAS

201-291-9/80-56-8

Name of the chemical

α-pinene

Concentration

1-<5%

EC/CAS

203-375-0/106-22-9

Name of the chemical

Citronellol/ (±) 3,7-Dimethyl-6-octen-1-ol

Concentration

1-<5%

EC/CAS

201-134-4/78-70-6

Name of the chemical

1,6-Octadien-3-ol, 3,7-dimethyl

Concentration

1-<5%

EC/CAS

200-945-0/76-22-2

Name of the chemical

camphor

Concentration

1-<5%

EC/CAS

226-394-6/5392-40-5

Name of the chemical

Citral

Concentration

0.1-<1%

EC/CAS

209-578-0/586-62-9

Name of the chemical

p-Mentha-1,4(8)-diene (38)

Concentration

0.1-<1%

EC/CAS

202-086-7/91-64-5

Name of the chemical

2H-1-Benzopyran-2-one

Concentration

0.1-<1%

EC/CAS

204-402-9/120-51-4

Name of the chemical

Benzyl benzoate

Concentration

0.1-<1%

EC/CAS

202-590-7/97-54-1

Name of the chemical

Isoeugenol

Concentration

<0.1%

General Information

Version

1 (16/05/2025

Revision date

2018-11-23

Product name

Four Thieves Madar Corp

Product Synonyms

None

1.2.1 Relevant identified uses

Fragrances

Icons in SDS

M004 M009 M013 M017 GHS02 GHS07 GHS08 GHS09

Company Information

company name

MADAR Corporation Limited

e-mail address of the competent person responsible for the Safety Data Sheet

technical@madarcorporation.co.uk

GHS Information

Signal word

Danger

Hazard Codes

Hazard statements (CLP)

H226, H304, H315, H317, H319, H410

Hazard statements

Code

Statements

H226

Flammable liquid and vapour

Section 2

SECTION 2: Hazards identification

Signal word

Danger

Hazard statements

H226, Flammable liquid and vapour. H304, May be fatal if swallowed and enters airways. H315, Causes skin irritation. H317, May cause an allergic skin reaction. H319, Causes serious eye irritation. H410, Very toxic to aquatic life with long lasting effects.

Additional information

EUH208, Contains Citral, Coumarin, Eucalyptol, Isoeugenol, Linalool, Neryl acetate, Terpinolene, Verbenone, alpha-Pinene, beta-Caryophyllene, beta-Pinene, dl-Citronellol, l-.beta. -Bisabolene. May produce an allergic reaction.

Precautionary statements

P210, Keep away from heat, sparks, open flames and hot surfaces. - No smoking. P240, Ground/bond container and receiving equipment. P233, Keep container tightly closed. P241, Use explosion-proof electrical, ventilating and lighting equipment. P242, Use only non-sparking tools. P243, Take precautionary measures against static discharge. P261, Avoid breathing vapour or dust. P272, Contaminated work clothing should not be allowed out of the workplace. P264, Wash hands and other contacted skin thoroughly after handling. P273, Avoid release to the environment. P280, Wear protective gloves/eye protection/face protection. P301/310, IF SWALLOWED: Immediately call a POISON CENTER or doctor/physician. P303/361/353, IF ON SKIN (or hair): Remove/take off immediately all contaminated clothing. Rinse skin with water/shower. P305/351/338, IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P331, Do not induce vomiting. P333/313, If skin irritation or rash occurs: Get medical advice/attention. P337/313, If eye irritation persists: Get medical advice/attention. P362, Take off contaminated clothing and wash before reuse. P370/378, In case of fire: Use carbon dioxide, dry chemical, foam for extinction. P391, Collect spillage. P403/235, Store in a well-ventilated place. Keep cool. P405, Store locked up. P501, Dispose of contents/container to approved disposal site, in accordance with local regulations.

Other hazards

None

2.1 Classification of the substance or mixture

Classification under Regulation (EC) No 1272/2008 Class and category of Flammable Liquid, Hazard Category 3 danger: Skin Corrosion / Irritation Category 2 Eye Damage / Irritation Category 2 Sensitization - Skin Category 1 Aspiration Hazard Category 1 Hazardous to the Aquatic Environment - Acute Hazard Category 1 Hazardous to the Aquatic Environment - Long-term Hazard Category 1 H226, Flammable liquid and vapour. H304, May be fatal if swallowed and enters airways. H315, Causes skin irritation. H317, May cause an allergic skin reaction. H319, Causes serious eye irritation. H410, Very toxic to aquatic life with long lasting effects. 1 2.2 Label elements Classification under Regulation (EC) No 1272/2008 Signal word: Danger Hazard statements: H226, Flammable liquid and vapour. H304, May be fatal if swallowed and enters airways. H315, Causes skin irritation. H317, May cause an allergic skin reaction. H319, Causes serious eye irritation. H410, Very toxic to aquatic life with long lasting effects. Supplemental EUH208, Contains Citral, Coumarin, Eucalyptol, Isoeugenol, Linalool, Neryl acetate, Information: Terpinolene, Verbenone, alpha-Pinene, beta-Caryophyllene, beta-Pinene, dl-Citronellol, l-.beta. -Bisabolene. May produce an allergic reaction. Precautionary P210, Keep away from heat, sparks, open flames and hot surfaces. - No smoking. statements: P240, Ground/bond container and receiving equipment. P233, Keep container tightly closed. P241, Use explosion-proof electrical, ventilating and lighting equipment. P242, Use only non-sparking tools. P243, Take precautionary measures against static discharge. P261, Avoid breathing vapour or dust. P272, Contaminated work clothing should not be allowed out of the workplace. P264, Wash hands and other contacted skin thoroughly after handling. P273, Avoid release to the environment. P280, Wear protective gloves/eye protection/face protection. P301/310, IF SWALLOWED: Immediately call a POISON CENTER or doctor/physician. P303/361/353, IF ON SKIN (or hair): Remove/take off immediately all contaminated clothing. Rinse skin with water/shower. P305/351/338, IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P331, Do not induce vomiting. P333/313, If skin irritation or rash occurs: Get medical advice/attention. P337/313, If eye irritation persists: Get medical advice/attention. P362, Take off contaminated clothing and wash before reuse. P370/378, In case of fire: Use carbon dioxide, dry chemical, foam for extinction. P391, Collect spillage. P403/235, Store in a well-ventilated place. Keep cool. P405, Store locked up. P501, Dispose of contents/container to approved disposal site, in accordance with local regulations. 1 Pictograms: 2.3 Other hazards Other hazards: None Section 3. Composition / information on ingredients 3.2 Mixtures Contains: REACH Registration Classification for Name CAS EC No. % (CLP) 1272/2008 Eugenol Eye Irrit. 2-Skin Sens. 97-53-0 202-589-1 20-<50% 1B;H317-H319,- Flam. Liq. 3-Skin Irrit. 2-Skin Sens. 1B-Asp. Tox 1-Aquatic Acute 1- d-Limonene 5989-27-5 227-813-5 20-<50% Aquatic Chronic 1; H226-H304-H315- H317-H410,- Acute Tox. 4-Skin Irrit. Cinnamaldehyde 2-Eye Irrit. 2-Skin 104-55-2 203-213-9 10-<20% Sens. 1A;H312-H315- H317-H319,- Skin Irrit. 2-Eye Irrit. 2- Citronellal 106-23-0 203-376-6 10-<20% Skin Sens. 1B;H315- H317-H319,- Skin Sens. 1B-Asp. beta-Caryophyllene 87-44-5 201-746-1 5-<10% Tox 1-Aquatic Chronic 4;H304-H317-H413,- Eugenyl acetate 93-28-7 202-235-6 1-<5% Acute Tox. 4;H302,- Eucalyptol Flam. Liq. 3-Skin Sens. 470-82-6 207-431-5 1-<5% 1B;H226-H317,- Flam. Liq. 3-Skin Irrit. 2-Skin Sens. 1B-Asp. Tox 1-Aquatic Acute 1- beta-Pinene 127-91-3 204-872-5 1-<5% Aquatic Chronic 1; H226-H304-H315- H317-H410,- p-Mentha-1,4-diene Flam. Liq. 3-Asp. Tox 99-85-4 202-794-6 1-<5% 1;H226-H304,- Flam. Liq. 3-Acute Tox. 4-Skin Irrit. 2-Skin Sens. 1B-Asp. Tox 1- alpha-Pinene 80-56-8 201-291-9 1-<5% Aquatic Acute 1- Aquatic Chronic 1; H226-H302-H304- H315-H317-H410,- dl-Citronellol Skin Irrit. 2-Skin Sens. 106-22-9 203-375-0 1-<5% 1B;H315-H317,- 1 Skin Irrit. 2-Eye Irrit. 2- Linalool 78-70-6 201-134-4 1-<5% Skin Sens. 1B;H315- H317-H319,- Flam. Sol. 2-Acute Tox. 1,7,7-Trimethylbicyclo 4-Acute Tox. 4-STOT 76-22-2 200-945-0 1-<5% [2.2.1]heptan-2-one SE 2;H228-H302- H332-H371,- Skin Irrit. 2-Skin Sens. Citral 5392-40-5 226-394-6 0.1-<1% 1-Skin Sens. 1B;H315- H317,- Flam. Liq. 3-Flam. Sol. Camphene 2-Aquatic Acute 1- 79-92-5 201-234-8 0.1-<1% Aquatic Chronic 1; H226-H228-H410,- Flam. Liq. 3-Skin Irrit. 2-Eye Irrit. 2-Asp. Tox 1-Aquatic Acute 1- Myrcene 123-35-3 204-622-5 0.1-<1% Aquatic Chronic 2; H226-H304-H315- H319-H400-H411,- Verbenone Acute Tox. 4-Skin 80-57-9 201-292-4 0.1-<1% Sens. 1;H302-H317,- Skin Irrit. 2-Skin Sens. l-.beta.-Bisabolene 495-61-4 0.1-<1% 1B-Asp. Tox 1;H304- H315-H317,- Skin Sens. 1B-Asp. Terpinolene Tox 1-Aquatic Acute 1- 586-62-9 209-578-0 0.1-<1% Aquatic Chronic 1; H304-H317-H410,- Neryl acetate Skin Irrit. 2-Skin Sens. 141-12-8 205-459-2 0.1-<1% 1B;H315-H317,- Coumarin Acute Tox. 4-Skin 91-64-5 202-086-7 0.1-<1% Sens. 1B;H302-H317,- Acute Tox. 4-Aquatic Benzyl benzoate Acute 1-Aquatic 120-51-4 204-402-9 0.1-<1% Chronic 2;H302-H400- H411,- Acute Tox. 4-Acute Tox. 4-Acute Tox. 4- Skin Irrit. 2-Eye Irrit. 2- Isoeugenol 97-54-1 202-590-7 <0.1% Skin Sens. 1A-STOT SE 3;H302-H312- H315-H317-H319- H332-H335,- Substances with Community workplace exposure limits: Not Applicable Substances that are persistent, bioaccumulative and toxic or very persistent and very bioaccumulative, greater than 0.1%: Not Applicable Section 4. First-aid measures 4.1 Description of first aid measures Inhalation: Remove from exposure site to fresh air, keep at rest, and obtain medical attention. Eye exposure: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Skin exposure: IF ON SKIN (or hair): Remove/take off immediately all contaminated clothing. Rinse skin with water/shower.

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