English Rose Madar Corp

Hazard statements (CLP)

H315, H317, H318, H412

Code

Statements

H315

Causes skin irritation

SECTION 2: Hazards identification

Signal word

Danger

Hazard statements

H315, Causes skin irritation. H317, May cause an allergic skin reaction. H318, Causes serious eye damage. H412, Harmful to aquatic life with long lasting effects.

Additional information

EUH208, Contains 2-Methyl-3-(p-isopropylphenyl)propionaldehyde. May produce an allergic reaction.

Precautionary statements

P261, Avoid breathing vapour or dust. P264, Wash hands and other contacted skin thoroughly after handling. P272, Contaminated work clothing should not be allowed out of the workplace. P273, Avoid release to the environment. P280, Wear protective gloves/eye protection/face protection. P302/352, IF ON SKIN: Wash with plenty of soap and water. P305/351/338, IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P310, Immediately call a POISON CENTER or doctor/physician. P333/313, If skin irritation or rash occurs: Get medical advice/attention. P362, Take off contaminated clothing and wash before reuse. P501, Dispose of contents/container to approved disposal site, in accordance with local regulations.

2.3 Other hazards

None

2.1 Classification of the substance or mixture

Classification under Regulation (EC) No 1272/2008 Class and category of Skin Corrosion / Irritation Category 2 danger: Eye Damage / Irritation Category 1 Sensitization - Skin Category 1 Hazardous to the Aquatic Environment - Long-term Hazard Category 3 H315, Causes skin irritation. H317, May cause an allergic skin reaction. H318, Causes serious eye damage. H412, Harmful to aquatic life with long lasting effects. 2.2 Label elements Signal word: Danger Hazard statements: H315, Causes skin irritation. H317, May cause an allergic skin reaction. H318, Causes serious eye damage. 1 H412, Harmful to aquatic life with long lasting effects. Supplemental EUH208, Contains 2-Methyl-3-(p-isopropylphenyl)propionaldehyde. May produce an allergic Information: reaction. Precautionary P261, Avoid breathing vapour or dust. statements: P264, Wash hands and other contacted skin thoroughly after handling. P272, Contaminated work clothing should not be allowed out of the workplace. P273, Avoid release to the environment. P280, Wear protective gloves/eye protection/face protection. P302/352, IF ON SKIN: Wash with plenty of soap and water. P305/351/338, IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P310, Immediately call a POISON CENTER or doctor/physician. P333/313, If skin irritation or rash occurs: Get medical advice/attention. P362, Take off contaminated clothing and wash before reuse. P501, Dispose of contents/container to approved disposal site, in accordance with local regulations. Pictograms: Other hazards: None Section 3. Composition / information on ingredients 3.2 Mixtures Contains: REACH Registration Classification for Name CAS EC % No. (CLP) 1272/2008 Phenethyl alcohol 60-12-8 200-456-2 20-<50% ATO 4-EDI 2;H302- H319,- Geraniol 106-24-1 203-377-1 10-<20% SCI 2-EDI 1-SS 1; H315-H317-H318,- dl-Citronellol 106-22-9 203-375-0 5-<10% SCI 2-EDI 2-SS 1B; H315-H317-H319,- 4-tert-Butylcyclohexyl 32210-23-4 250-954-9 1-<5% SS 1B;H317,- acetate 2-Methyl-3-(p- SCI 2-SS 1B-EH C3; isopropylphenyl) 103-95-7 203-161-7 1-<5% H315-H317-H412,- propionaldehyde 1,3,4,6,7,8-Hexahydro- 4,6,6,7,8,8- 1222-05-5 214-946-9 1-<5% EH A1-EH C1;H410,- hexamethylcyclopenta- gamma-2-benzopyran 1 Substances with Community workplace exposure limits: Not Applicable Substances that are persistent, bioaccumulative and toxic or very persistent and very bioaccumulative, greater than 0.1%: Not Applicable Section 4. First-aid measures 4.1 Description of first aid measures IF ON SKIN: Wash with plenty of soap and water. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Immediately call a POISON CENTER or doctor/physician. 4.2 Most important symptoms and effects, both acute and delayed Causes skin irritation. May cause an allergic skin reaction. Causes serious eye damage. 4.3 Indication of any immediate medical attention and special treatment needed None expected, see Section 4.1 for further information. SECTION 5: Firefighting measures 5.1 Extinguishing media Suitable media: Carbon dioxide, Dry chemical, Foam. 5.2 Special hazards arising from the substance or mixture In case of fire, may be liberated: Carbon monoxide, Unidentified organic compounds. 5.3 Advice for fire fighters: In case of insufficient ventilation, wear suitable respiratory equipment. Section 6. Accidental release measures 6.1 Personal precautions, protective equipment and emergency procedures: Avoid inhalation. Avoid contact with skin and eyes. See protective measures under Section 7 and 8. 6.2 Environmental precautions: Keep away from drains, surface and ground water, and soil. 1 6.3 Methods and material for containment and cleaning up: Remove ignition sources. Provide adequate ventilation. Avoid excessive inhalation of vapours. Contain spillage immediately by use of sand or inert powder. Dispose of according to local regulations. 6.4 Reference to other sections: Also refer to sections 8 and 13. Section 7. Handling and storage 7.1 Precautions for safe handling: Keep away from heat, sparks, open flames and hot surfaces. - No smoking. Use personal protective equipment as required. Use in accordance with good manufacturing and industrial hygiene practices. Use in areas with adequate ventilation Do not eat, drink or smoke when using this product. 7.2 Conditions for safe storage, including any incompatibilities: Store in a well-ventilated place. Keep container tightly closed. Keep cool. Ground/bond container and receiving equipment. Use explosion-proof electrical, ventilating and lighting equipment. Use only non-sparking tools. Take precautionary measures against static discharge. 7.3 Specific end use(s): Fragrances: Use in accordance with good manufacturing and industrial hygiene practices. Section 8. Exposure controls/personal protection 8.1 Control parameters Workplace exposure limits: Not Applicable 8.2 Exposure Controls Eye / Skin Protection Wear protective gloves/eye protection/face protection Respiratory Protection Under normal conditions of use and where adequate ventilation is available to prevent build up of excessive vapour, this material should not require special engineering controls. However, in conditions of high or prolonged use, or high temperature or other conditions which increase exposure, the following engineering controls can be used to minimise exposure to personnel: a) Increase ventilation of the area with local exhaust ventilation. b) Personnel can use an approved, appropriately fitted respirator with organic vapour cartridge or canisters and particulate filters. c) Use closed systems for transferring and processing this material. Also refer to Sections 2 and 7. Section 9. Physical and chemical properties 9.1 Information on basic physical and chemical properties Appearance: Clear 1 Odour: Floral Odour threshold: Not determined pH: Not determined Melting point / freezing point: Not determined Initial boiling point / range: Not determined Flash point: > 96°C Evaporation rate: Not determined Flammability (solid, gas): Not determined Upper/lower flammability or explosive limits: Product does not present an explosion Vapour pressure: hazard Not determined Vapour density: Not determined Relative density: 0.9 535 - 0.635 Solubility(ies): Not determined Partition coefficient: n-octanol/water: Not determined Auto-ignition temperature: Not determined Decomposition temperature: Not determined Viscosity: Not determined Explosive properties: Not expected Oxidising properties: Not expected Refractive Index: 1.46546 - 1.47535 Optical Rotation: -0.03° 9.2 Other information: None available Section 10. Stability and reactivity 10.1 Reactivity