Cocamidopropyl Betaine

Hazard statements (CLP)

H318, H412

Code

Statements

H318

Causes serious eye damage

SECTION 2: Hazards identification

Regulation (EC) No. 1272/2008 CLASSIFICATION OF THE SUBSTANCE OR MIXTURE Classification according to Regulation S.I. 2019/720 (GB CLP) Classification according to Regulation (EC) No

Hazard categories

Target Organs statements Serious eye damage Category 1 H318 Long-term (chronic) aquatic Category H412 hazard

Most important adverse effects

Human Health See section 11 for toxicological information Physical and chemical See section 9/10 for physicochemical information hazards Potential environmental See section 12 for environmental information effects

Signal word

Danger

Hazard statements

H318 Causes serious eye damage. H412 Harmful to aquatic life with long lasting effects.

Prevention

P264 Wash hands thoroughly after handling. P273 Avoid release to the environment. P280 Wear eye protection/ face protection.

Response

P305 + P351 + P338 + P310 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Immediately call a POISON CENTER/ doctor.

Disposal

P501 Dispose of contents/ container to an approved waste disposal plant.

Hazardous Ingredients

• 1-Propanaminium, 3-amino-N-(carboxymethyl)-N,N-dimethyl-, N-C8-18(even numbered) acyl derivs.,hydroxides, inner salts

2.3 Other hazards

This substance/mixture contains no components considered to be either persistent, bioaccumulative and toxic (PBT), or very persistent and very bioaccumulative (vPvB) at levels of 0.1% or higher.

ECOLOGICAL INFORMATION

The substance/mixture does not contain components considered to have endocrine disrupting properties according to REACH Article 57(f) or Commission Delegated regulation (EU) 2017/2100 or Commission Regulation (EU) 2018/605 at levels of 0.1% or higher.

TOXICOLOGICAL INFORMATION

The substance/mixture does not contain components considered to have endocrine disrupting properties according to REACH Article 57(f) or Commission Delegated regulation (EU) 2017/2100 or Commission Regulation (EU) 2018/605 at levels of 0.1% or higher.

2.1 Classification of the substance or mixture

Classification according to Regulation S.I. 2019/720 (GB CLP) Classification according to Regulation (EC) No 1272/2008 Regulation S.I. 2019/720 (GB CLP) Hazard Hazard class Hazard category Target Organs statements Serious eye damage Category 1 --- H318 Long-term (chronic) aquatic Category 3 --- H412 hazard Most important adverse effects Human Health : See section 11 for toxicological information. Physical and chemical : See section 9/10 for physicochemical information. hazards Potential environmental : See section 12 for environmental information. effects 2.2. LABEL ELEMENTS: Labelling according to Regulation (EC) No 1272/2008: Hazard symbols : Signal word (CLP): Danger Hazard statements : H318 Causes serious eye damage. H412 Harmful to aquatic life with long lasting effects. Precautionary statements Prevention : P264 Wash hands thoroughly after handling. P273 Avoid release to the environment. P280 Wear eye protection/ face protection. Response : P305 + P351 + P338 + P310 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Immediately call a POISON CENTER/ doctor. Disposal : P501 Dispose of contents/ container to an approved waste disposal plant. Hazardous components which must be listed on the label: • 1-Propanaminium, 3-amino-N-(carboxymethyl)-N,N-dimethyl-, N-C8-18(even numbered) acyl derivs.,hydroxides, inner salts 2.3. OTHER HAZARDS This substance/mixture contains no components considered to be either persistent, bioaccumulative and toxic (PBT), or very persistent and very bioaccumulative (vPvB) at levels of 0.1% or higher. Ecological information: The substance/mixture does not contain components considered to have endocrine disrupting properties according to REACH Article 57(f) or Commission Delegated regulation (EU) 2017/2100 or Commission Regulation (EU) 2018/605 at levels of 0.1% or higher. Toxicological information: The substance/mixture does not contain components considered to have endocrine disrupting properties according to REACH Article 57(f) or Commission Delegated regulation (EU) 2017/2100 or Commission Regulation (EU) 2018/605 at levels of 0.1% or higher. 3. COMPOSITION/INFORMATION ON INGREDIENTS 3.2. MIXTURES: Classification (Regulation S.I. 2019/720 (GB CLP)) Hazardous components Amount [%] Hazard class / Hazard Hazard statements category 1-Propanaminium, 3-amino-N-(carboxymethyl)-N,N-dimethyl-, N-C8-18(even numbered) acyl derivs.,hydroxides, inner salts EC-No.: 931-296-8 >= 28 - <= 30 Eye Dam.1 H318 Aquatic Chronic3 H412 EU REACH-Reg. No.: 01- specific concentration 2119488533-30-xxxx limit Eye Dam. 1; H318 > 10 % Eye Irrit. 2; H319 > 4 - 10 % For the full text of the H-Statements mentioned in this Section, see Section 16. Non-hazardous component Chemical name Identification Number Amount [%] Sodium chloride CAS-No. : 7647-14-5 <= 6 EC-No. 231-598-3 REACH-Reg. No. 01-2119485491-33-xxxx Sodium benzoate 0.4 CAS-No. : 532-32-1 - 0.6 EC-No. 208-534-8 REACH-Reg. No. 01-2119460683-35-xxxx 4. FIRST AID MEASURES 4.1. DESCRIPTION OF FIRST AID MEASURES: General advice: Take off all contaminated clothing immediately. Inhilation: Remove to fresh air. If symptoms persist, call a physician. In case of eye contact: Rinse immediately with plenty of water, also under the eyelids, for at least 15 minutes. Consult an eye specialist immediately. Go to an ophthalmic hospital if possible. If swallowed: Rinse mouth with water. Never give anything by mouth to an unconscious person. Call a physician immediately. If swallowed: IF SWALLOWED: Get medical attention immediately. Rinse mouth thoroughly with water. Consult a physician for specific advice. Show this Safety Data Sheet to the medical personnel. Protection of First Aid Responders: First Aid responders should pay attention to self-protection and use the recommended protective clothing. Cocamidopropyl Betaine 4.2. MOST IMPORTANT SYMPTOMS AND EFFECTS, BOTH ACUTE AND DELAYED: Symptoms: See Section 11 for more detailed information on health effects and symptoms. Effects: Causes serious eye damage. See Section 11 for more detailed information on health effects and symptoms. 4.3. INDICATION OF ANY IMMEDIATE MEDICAL ATTENTION AND SPECIAL TREATMENT NEEDED: Treatment: Treat symptomatically.For specialist advice physicians should contact the Poisons Information Service. 5. FIRE FIGHTING MEASURES 5.1. EXTINGUISHING MEDIA: Suitable extinguishing media: Water spray, Foam, Dry chemical, Carbon dioxide (CO2), Use extinguishing measures that are appropriate to local circumstances and the surrounding environment. Unsuitable extinguishing media High volume water 5.2. SPECIAL HAZARDS ARISING FROM THE SUBSTANCE OR MIXTURE: Specific hazards: Incomplete combustion may form toxic pyrolysis products. Hazardous Combustion products: Carbon monoxide, Carbon dioxide (CO2), Nitrogen oxides (NOx) 5.3. ADVICE FOR FIREFIGHTERS: Special protective equipment for firefighters: In the event of fire, wear self-contained breathing apparatus.Wear personal protective equipment. Special Further advice: Cool closed containers exposed to fire with water spray.Isolate fire area and deny unnecessary entry.Collect contaminated fire extinguishing water separately. This must not be discharged into drains. 6. ACCIDENTAL RELEASE MEASURES 6.1.PERSONAL PRECAUTIONS, PROTECTIVE EQUIPMENT AND EMERGENCY PROCEDURES: Personal precautions: Use personal protective equipment. Keep away unprotected persons. Ensure adequate ventilation. Avoid contact with skin and eyes. 6.2. ENVIRONMENTAL PRECAUTIONS: Environmental precautions: Do not flush into surface water or sanitary sewer system. Avoid subsoil penetration. 6.3. METHODS AND MATERIALS FOR CONTAINMENT AND CLEANING UP: Methods for cleaning up: Soak up with inert absorbent material. Shovel or sweep up. Keep in suitable, closed containers for disposal. Further information: Treat recovered material as described in the section "Disposal considerations". 6.4. REFERENCE TO OTHER SECTIONS: See Section 1 for emergency contact information. See Section 8 for information on personal protective equipment. See Section 13 for waste treatment information. Cocamidopropyl Betaine 7. HANDLING AND STORAGE 7.1. PRECAUTIONS FOR SAFE HANDLING: Advice on safe handling: Keep container tightly closed. Wear personal protective equipment. Avoid contact with skin, eyes and clothing. Emergency eye wash fountains and emergency showers should be available in the immediate vicinity. Hygiene measures: Keep away from food, drink and animal feedingstuffs. Smoking, eating and drinking should be prohibited in the application area. Wash hands before breaks and at the end of workday. Take off all contaminated clothing immediately 7.2.CONDITIONS FOR SAFE STORAGE, INCLUDING ANY INCOMPATIBILITIES: Requirements for storage areas and containers: Store in original container. Keep away from incompatible materials. Advice on protection against fire and explosion: Normal measures for preventive fire protection. Further information on storage conditions: Keep tightly closed in a dry and cool place. Keep in a well-ventilated place. Advice on common storage: Keep away from food, drink and animal feedingstuffs. Storage temperature: 10 - 50 °C 7.3. SPECIFIC END USES: No information available. 8. EXPOSURE CONTROLS/PERSONAL PROTECTION 8.1. CONTROL PARAMETERS (Additional) Information: Contains no substances with occupational exposure limit values. Component: 1-Propanaminium, 3-amino-N- (carboxymethyl)-N,N-dimethyl-, N-C818(even numbered) acyl derivs.,hydroxides, inner salts Derived No Effect Level (DNEL)/Derived Minimal Effect Level (DMEL) DNEL Workers, Long-term - systemic effects, Skin contact