BUTYRICACID

Hazard statements (CLP)

H202, H302, H314, H318

Code

Statements

H202

Explosive; severe projection hazard

Hazard pictograms

��

Signal word

Danger (

Hazard statements

H202 - Harmful if swallowed. H3;4 - Causes severe skin burns and eye damage.

Precautionary statements

P260 - Do not breathe dust/fume/gas/mist/vapours/spray. P280 - Wear protective gloves/protective clothing/eye protection/face protection. . . .. 1' P301+P312+P330+P331 - IF SWALLOWED: Call a POISON CENTER or doctor/physician if you feel u_nwell. IF SWAlLQWE!x ri)ise mouth. Do NOT induc v_omiting. P303+P361+P353+P310 - IF ON SKIN (or hair) Remove/Take off immediately ;!II 1=ontaminated clothing. l{irtse·skin with water/shower JmniediatelyC aUa POISON CENTER or doctor/physician. · • , ·.: ·· P305+P351+P338+P310 - IF IN EYES: Rinse cautiously with water for several minutes. Remove-contact lenses, if present and easy to do. Continue rinsig. Imme­ diately call a POISON CENTER or doctor/physician.

2.3 Other hazards

No Information available 3.1. Substances Chemical name: BUTYRIC ACID CAS number: 107-92-6 EC number: 203-532-3 Hazardous constituents: CAS No Chemical Name %(w/w) EC No

Additional information

No information available. 10.1. Reactivity No hazardous reactions if stored and handled as prescribed/indicated. 10.2. Chemical stability The product is stable if stored and handled as prescribed/indicated. 10.3. Possibility of hazardous reactions No hazardous reactions if stored and handled as prescribed/indicated. l<i.4. Conditions to Avoid C. ,nditions to Avoid Excessive heat, flame or other ignition sources 10.5. Incompatible materials Avoid contact with strong acids and bases and oxidizing agents. 10.6. Hazardous decomposition products During combustion may form carbon monoxide and unidentified organic compounds. 11.1. Information on toxicological effects Acute toxicity Harmful if swallowed. Skin corrosion/irritation Causes severe skin burns and eye damage. Serious eye damage/irritation Based on the data available, the criteria for classification are not met. Respiratory or skin sensitisation Based on the data available, the criteria for classification are not met. Germ cell mutagenicity Based on the data available, the criteria for classification are not met. Carcinogenicity Based on the data available, the criteria for classification are not met. Reproductive toxicity Based on the data available, the criteria for classification are not met. STOT-single exposure Based on the data available, the criteria for classification are not met. STOT-repeated exposure Based on the data available, the criteria for classification are not met. Aspiration hazard Based on the data available, the criteria for classification are not met. 12.1. Toxicity Assessment: Baed on the data available, the criteria for classification are not met. Experimental/calculated data: No information available. 12.2. Degradability No information available. 12.3. Bioaccumulative potential No information available. 12.4. Soil mobility No information available. 12.5. Results of PBT and vPvB assessment The product does not contain substances fulfilling the PBT or vPvB criteria at 0.1% or above. 12.6. Other adverse effects See also sections 6, 7, 13 and 15 Do not allow to get into waste water or waterways. 13.1. Waste treatment methods Dispose of in accordance with national and local environmental regulations. ADR/RID/ADN IMDG IATA-ICAO 14.1. UN Number UN2820 14.2. UN Proper Shipping Name BUTYRIC ACID 14.3. Transport Hazard Class(es) 8 14.4. Packing Group Ill 14.5. Environmental hazards No Additional information 14.6 Special precautions for user None known 14.7. Transport in bulk according to Annex II of MAR POL 73/78 and the IBC Code Ne, information available 15.1. Safety, health and environmental regulations/legislation specific for the substance or mixture No information available 15.2. Chemical safety assessment No chemical safety assessment has been carried out for the subsance or mixture by the supplier Full text of the R-phrases, hazard statements and precautionary statements mentioned in section 3: H302 - Harmful if swallowed. H314 - Causes severe skin burns and eye damage. H318 - Causes serious eye damage. The information included in this safety data sheet is based on the available data at the moment this document is issued. It is meant to be a description of safety requirements for our product and does not stand for a guarantee of its properties .. The.user is responsible for;taking all_nesessary steps leading to compliance· · with local rules and legislation. --· \· ., SPECIFICATION SHEET VERSION 6,00 VERSION DATE 10/11/21 PRINT DATE 25/07/22 PRODUCT BUTYRIC ACID (RM.BUTY.ACID) APPLICATIONS Raw material for industrial use intended for the manufacture of flavours and/or fragrances. IUPAC NAME BUTANOIC ACID SYNONYMS BUTANOIC ACID, ETHYLACETIC ACID FORMULA C4 HS 02 MOLECULAR WEIGHT 88,11 CAS 107-92-6 /,,,/_,/'·---..," ,,,.,,✓COO H EINECS 203-532-3 FEMA 2221 TARIFF NUMBER 2915601990 FOOD GRADE CERTIFICATE AVAILABLE ON REQUEST REACH REGISTRATION NO. 01-2119488986-ll SPECIFICATIONS ASPECT AT 20°c CLEAR MOBILE LIQUID COLOUR COLORLESS ODOUR RANCID BUTTER, SOUR TASTE DENSITY AT 20°c (g / ml) 0,954 - 0,960 DENSITY 25/25 0,952 - 0,956 REFRACTIVE INDEX nD20 1,3970 - 1,3990 REFRACTIVE INDEX nD25 OPTICAL ROTATION (0) BOILING POINT (°C) 162 - 164 MEL TING POINT (°C) CA. -5 FLASH POINT (°C) 69,00 ASSAY(% GC) > 99,5 ACID VALUE (mg KOH/g) SOLUBILITY SOLUBLE IN WATER VAPOUR PRESSURE 1 hPa (20°C);6,5 hPa (50°C) OTHER SOLUBILITIES SOLUBLE IN ETHANOL OTHER TECHNICAL DATA WATER CONTENTS <0,1%. STABILITY AND STORAGE KEEP IN TIGHTLY CLOSED CONTAINER IN A COOL AND DRY PLACE, PROTECTED FROM LIGHT. WHEN STORED FOR MORE THAN 24 MONTHS, QUALITY SHOULD BE CHECKED BEFORE USE. WE BELIEVE THE ABOVE INFORMATION TO BE CORRECT BUT WE DO NOT PRESENT IT AS ALL INCLUSIVE AND AS SUCH SHOULD BE USED AS A GUIDE. IT IS THE SOLE RESPONSIBILITY OF THE RECEIVER OF OUR PRODUCT TO COMPLY WITH EXISTING REGULATIONS AND INSTRUCTIONS. THIS PRODUCT HAS NOT BEEN FILTERED DUE TO TECHNOLOGICAL REASONS. WE RECOMMEND NOT TO USE IT UNLESS FILTERED WHEN USED AS A RAW MATERIAL IN FOOD INTENDED FOR FINAL CONSUMERS. 29 June 2021 VEGAN / VEGETARIAN DECLARATION Product: BUTYRIC ACID We hereby inform that, to the best of our knowledge, the above-mentioned material is suitable for the following diets: Vegan Does not contain any ingredient of animal origin (mammalian, poultry, fish, crustacean, mollusc) or animal derivatives (dairy, egg and bee products) including additives and processing aids. □ Does not contain any ingredient of animal origin (mammalian, poultry, fish, crustacean, mollusc) Vegetarian or dairy and egg products, including additives and processing aids. Bee products (e.g. honey, bees wax) are acceptable. □ Does not contain any ingredient of animal origin (mammalian, poultry, fish, crustacean, mollusc), Ovo-Lacto Vegetarian including additives and processing aids. Dairy, egg and bee products (e.g. honey, bees wax) are acceptable. ( 'Animal' refers to the entire animal kingdom, i.e. vertebrates and , multicellular-invertebrates. ,. ·u•' , ' - • ·J" -;, '< ·,-:- . The information contained herein is to the best of our knowledge reliable. However, it should be noted that it is the reponsibility of 1he manufacturer of the material containing this ingredient to iden1ify anq comply with all relevant legal requiremnts. This document is electronically generated and 1herefore it is not signed.

2.1 Classification of the substance or mixture

Acute Toxicity - Category 4 (oral)- H302 Skin Corrosion - Category 18- H314 Serious eye damage -Category 1 - H318 2.2. Label Elements Hazard pictograms: �� Signal Word: Danger ( Hazard statements: H202 - Harmful if swallowed. H3;4 - Causes severe skin burns and eye damage. Precautionary statements: P260 - Do not breathe dust/fume/gas/mist/vapours/spray. P280 - Wear protective gloves/protective clothing/eye protection/face protection. . . .. 1' P301+P312+P330+P331 - IF SWALLOWED: Call a POISON CENTER or doctor/physician if you feel u_nwell. IF SWAlLQWE!x ri)ise mouth. Do NOT induc v_omiting. P303+P361+P353+P310 - IF ON SKIN (or hair): Remove/Take off immediately ;!II 1=ontaminated clothing. l{irtse·skin with water/shower: JmniediatelyC:aUa POISON CENTER or doctor/physician. · • , ·.: ·· P305+P351+P338+P310 - IF IN EYES: Rinse cautiously with water for several minutes. Remove-contact lenses, if present and easy to do. Continue rinsig. Imme­ diately call a POISON CENTER or doctor/physician. 2.3. Other hazards No Information available 3.1. Substances Chemical name: BUTYRIC ACID CAS number: 107-92-6 EC number: 203-532-3 Hazardous constituents: CAS No Chemical Name %(w/w) EC No Classification according to Regulation 1272/2008 Acute Tox. 4 (oral) - H302 BUTYRIC ACID ?:SO 107-92-6 Skin Corr. 1 B - H314 203-532-3 Eye Darn. 1 - H318 See the full text of the hazard statements ,n section 16. 3.2. Mixtures Not applicable. 4.1. Description of necessary first aid measures Ingestion: Rinse mouth with water. Obtain medical advice. Keep at rest. Do not induce vomiting. Eye contact: In case of contact with eyes, rinse immediately with plenty of water for at least 15 minutes and seek medical advice. Inhalation: Remove person to fresh air and keep at rest. Seek immediate medical advice. Skin contact: Take off immediately all contaminated clothing. Thoroughly wash affected skin with soap and water. Seek medical attention if symptoms persist. 4.2. Most important symptoms and effects, both acute and delayed No information available. 4.3. Indication of any immediate medical attention and special treatment needed No information available. 5.1. Extinguishing Media Water spray, carbon dioxide, dry chemical powder or appropriate foam. For safety reasons do not use full water jet. 5.2. Special hazards arising from the substance or mixture Known or Anticipated Hazardous Products of Combustion: Emits toxic fumes under fire conditions. 5.3. A dvice for firefighters High temperatures can lead to high pressures inside closed containers. Avoid inhalation of vapors that are created. Use appropriate respiratory protection. Do not allow spillage of fire to be poured into drains or watercourses. Wear self-contained breathing apparatus and protective clothing. 6.1. Personal precautions, protective equipment and emergency procedures Evacuate surronding areas. Ensure adequate ventilation. Keep unnecessary and unprtected personnel frorn·entering. .., Do not breathe vapor/spray. Avoid contact with skin and eyes. Information regarding personal protective measures: see section 8. -! < 6.2. Environmental precautions To avoid possible contamination of the environment, do not discharge into any drains, surface water,s -;,,.· or groundwaters. 6.3. Methods and materials for containment and cleaning up Cover with an inert, inorganic, non-combustible absorbent material (e.g. dry,lime, sand, soda ash). Place in covered containers using non-sparking tools and transport outdoors. Avoid open flames or sources of ignition (e.g. pilot lights on gas hot water heater). Ventilate area and wash spill site after material pickup is complete. 6.4. Reference to other sections Information regarding exposure controls, personal protection and disposal considerations can.be found in sections 8 and 13. 7.1. Precautions for safe handling Do not store or handle this material near food or drinking water. Do not smoke. Avoid contact with the eyes, skin and clothing. Wear protective clothing and use glasses. Observe the rules of safety and hygiene at work. Keep in the original container or an alternative made from a compatible material. 7.2. Conditions for safe storage, including any incompatibilities Store in tightly closed and preferably full containers in a cool, dry and ventilated area, protected from light. Keep away from sources of ignition (e.g. hot surfaces, sparks, flame and static discharges). Keep away from incompatible materials (see section 10). 7.3. Specific end use(s) No information available. 8.1. Control parameters Components with occupational exposure limits: None known. 8.2. Exposure controls Appropriate engineering controls: Measures should be taken to prevent materials from being splashed into the body. Provide adequate ventilation, according to the conditions of use. Use a mechanical exhaust if required. Eye/Face protection: Chemical safety goggles are recommended. Wash contaminated goggles before reuse. Hand Protection: Chemical-resistant gloves are recommended. Wash contaminated gloves before reuse. Body protection: Personal protective equipment for the body should be selected based on the task being performed and the risks involved. Respiratory Protection: In case of insufficient ventilation, use suitable respiratory equipment. Emiironmental exposure controls: Emissions from ventilation or process equipment should be checked to ensure they comply with environmental protection legislation. In some cases, filters or engineering modifications to the process equipment will be necessary to reduce emissions to acceptable levels. 9.1. Information on basic physical and chemical properties App ea ranee: Liquid Colour: Conforms to standard Odour: Conforms to standard Odour theshold: Not determined pH: Not determined Melting point/freezing point: CA. -5 Boling point/boiling range (°C): 162-164 Flash point: 69 °C Evaporation rate: Not determined Flammability: Not determined Lower flammability/Explosive limit: Not determined Upper flammability/Explosive limit: Not determined Vapour pressure: 1 hPa (20°C);6,5 hPa (S0°C) Vapour Density: Not determined Density: 0,953-0,96 g/rill (20°() Relative density: o,953-0,96 (20°cJ Water solubility: SOLUBLE IN WATER Solubility in other solvents: SOLUBLE IN ETHANOL Partition coefficient n-octanol/water: Not determined Auto-ignition temperature: Not determined Decomposition temperature: Not determined Viscosity, dynamic: Not determined Viscosity, kinematic: Not determined Explosive properties: Not determined Oxidising properties: Not determined 9.2. Additional information No information available. 10.1. Reactivity No hazardous reactions if stored and handled as prescribed/indicated. 10.2. Chemical stability The product is stable if stored and handled as prescribed/indicated. 10.3. Possibility of hazardous reactions No hazardous reactions if stored and handled as prescribed/indicated. l<i.4. Conditions to Avoid C.:,nditions to Avoid: Excessive heat, flame or other ignition sources. 10.5. Incompatible materials Avoid contact with strong acids and bases and oxidizing agents. 10.6. Hazardous decomposition products During combustion may form carbon monoxide and unidentified organic compounds. 11.1. Information on toxicological effects Acute toxicity Harmful if swallowed. Skin corrosion/irritation Causes severe skin burns and eye damage. Serious eye damage/irritation Based on the data available, the criteria for classification are not met. Respiratory or skin sensitisation Based on the data available, the criteria for classification are not met. Germ cell mutagenicity Based on the data available, the criteria for classification are not met. Carcinogenicity Based on the data available, the criteria for classification are not met. Reproductive toxicity Based on the data available, the criteria for classification are not met. STOT-single exposure Based on the data available, the criteria for classification are not met. STOT-repeated exposure Based on the data available, the criteria for classification are not met. Aspiration hazard Based on the data available, the criteria for classification are not met. 12.1. Toxicity Assessment: Baed on the data available, the criteria for classification are not met. Experimental/calculated data: No information available. 12.2. Degradability No information available. 12.3. Bioaccumulative potential No information available. 12.4. Soil mobility No information available. 12.5. Results of PBT and vPvB assessment The product does not contain substances fulfilling the PBT or vPvB criteria at 0.1% or above. 12.6. Other adverse effects See also sections 6, 7, 13 and 15 Do not allow to get into waste water or waterways. 13.1. Waste treatment methods Dispose of in accordance with national and local environmental regulations.