BUTYRI C AC ID

Hazard statements (CLP)

H302, H314, H318

Code

Statements

H302

Harmful if swallowed

SECTION 2: Hazards identification

Classification of the substance or mixture Acute Toxicity- Category 4 (oral)- H302 Skin Corrosion - Category 1B - H314 Serious eye damage - Category 1 - H318

Signal word

Danger

Hazard statements

H302 - Harmful if swallowed. H314 - Causes severe skin burns and eye damage.

Precautionary statements

P260 -Do not breathe dust/fume/gas/mist/vapours/spray. P280 -Wear protective gloves/protective clothing/eye protection/face protection. P301+P312+P330+P331 -IF S WALLOWED Call a POISON CENTER or doctor/physician if you feel unwell. IF S WALLOWED rinse mouth. Do NO T induce vomiting P303+P361+P353+P310 -IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower. I mmediately call a POISON CENTER or doctor/physician. P305+P351+P338+P310 - I F IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. I mme­ diately call a POISON CENTER or doctor/physician.

2.3 Other hazards

Product not containing any component that meets the criteria for PBT or vPvB according to Regulation (E C) 1907 /2006, Annex XI II. Product not containing any component identified as having endocrine disrupting properties according to Regulation (EU) 2017 {2100.

2.1 Classification of the substance or mixture

Acute Toxicity- Category 4 (oral)- H302 Skin Corrosion - Category 1B - H314 Serious eye damage - Category 1 - H318 2.2. Label Elements Signal Word: Danger Hazard statements: H302 - Harmful if swallowed. H314 - Causes severe skin burns and eye damage. Precautionary statements: P260 -Do not breathe dust/fume/gas/mist/vapours/spray. P280 -Wear protective gloves/protective clothing/eye protection/face protection. P301+P312+P330+P331 -IF S WALLOWED: Call a POISON CENTER or doctor/physician if you feel unwell. IF S WALLOWED: rinse mouth. Do NO T induce vomiting. P303+P361+P353+P310 -IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower. I mmediately call a POISON CENTER or doctor/physician. P305+P351+P338+P310 - I F IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. I mme­ diately call a POISON CENTER or doctor/physician. 2.3. Other hazards Product not containing any component that meets the criteria for PBT or vPvB according to Regulation (E C) 1907 /2006, Annex XI II. Product not containing any component identified as having endocrine disrupting properties according to Regulation (EU) 2017 {2100. SECTION 3. COMPOSITION/INFORMATION ON INGREDIENTS 3.1. Substances Chemical name: BUlYRICACID CAS number: 107-92-6 EC number: 203-532-3 Hazardous constituents: CASNo. Chemical Name %(w/w) EC No. Classifiction according to Specific Conc:entrat.ion limit, Regulation 1272/2008 M-factor, ATE, SVHC Index No. Acute Tox. 4 (oral) -H302 BUlYRIC ACID 107-92-6 Skin Corr. 18 -H314 ATE (oral): 1630 mg/kg 50 203-532-3 Eye Dam.1-H318 See the full text of the hazard statements in section 16. 3.2. Mixtures Not applicable. SECTION 4. FIRST-AID MEASURES 4.1. Description of necessary first aid measures Ingestion: Rinse mouth with water. Obtain medical advice. Keep at rest. Do not induce vomiting. Eye contact: In case of contact with eyes, rinse immediately with plenty of water for at least 15 minutes and seek medical advice. Inhalation: Remove person to fresh air and keep at rest. Seek immediate medical advice. Skin contact: Take off immediately all contaminated dothing. Thoroughly wash affected skin with soap and water. Seek medical attention if symptoms persist. 4.2. Most important symptoms and effects, both acute and delayed No information available. 4.3. Indication of any immediate medical attention and special treatment needed No information available. SECTION 5. FIRE-FIGHTING MEASURES 5.1. Extinguishing Media Water spray, carbon dioxide, dry chemical powder or appropriate foam. For safety reasons do not use full water Jet. 5.2. Special hazards arising from the substance or mixture Known or Anticipated Hazardous Products of Combustion: Emits toxic fumes under fire conditions. 5.3. Advice for firefighters High temperatures can lead to high pressures inside closed containers. Avoid inhalation of vapors that are created. Use appropriate respiratory protection. Do not allow spillage of fire to be poured into drains or watercourses. Wear self-contained breathing apparatus and protective clothing. SECTION 6. ACCIDENTAL RELEASE MEASURES 6.1. Personal precautions, protective equipment and emergency procedures Evacuate surronding areas. Ensure adequate ventilation. Keep unnecessary and unprotected personnel from entering. Do not breathe vapor/spray. Avoid contact with skin and eyes. Information regarding personal protective measures: see section 8. 6.2. Environmental precautions To avoid possible contamination of the environment, do not discharge into any drains, surface waters or groundwaters. 6.3. Methods and materials for containment and cleaning up Cover with an Inert, inorganic, non-combustible absorbent material (e.g. dry-lime, sand, soda ash). Place in covered containers using non-sparking tools and transport outdoors. Avoid open flames or sources of ignition (e.g. pilot lights on gas hot water heater). Ventilate area and wash spill site after material pickup is complete. 6.4. Reference to other sections Information regarding exposure controls, personal protection and disposal considerations can be found in sections 8 and 13. SECTION 7. HANDLING AND STORAGE 7.1. Precautions for safe handling Do not store or handle this material near food or drinking water. Do not smoke. Avoid contact with the eyes, skin and clothing. Wear protective clothing and use glasses. Observe the rules of safety and hygiene at work. Keep in the original container or an alternative made from a compatible material. 7.2. Conditions for safe storage, including any incompatibilities Store in tightly closed and preferably full containers in a cool, dry and ventilated area, protected from light. Keep away from sources of ignition (e.g_ hot surfaces, sparks, flame and static discharges). Keep away from incompatible materials (see section 10). 7.3. Specific end use(s) No information available. SECTION 8. EXPOSURE CONTROLS AND PERSONAL PROTECTION 8.1. Control parameters Components with occupational exposure limits: None known_ 8.2. Exposure controls Appropriate engineering controls: Measures should be taken to prevent materials from being splashed into the body. Provide adequate ventilation, according to the conditions of use. Use a mechanical exhaust if required. Eye/ Face protection: Chemical safety goggles are recommended_ Wash contaminated goggles before reuse. Hand Protection: Chemical-resistant gloves are recommended. Wash contaminated gloves before reuse. Body protection: Personal protective equipment for the body should be selected based on the task being perfonned and the risks involved. Respiratory Protection: In case of insufficient ventilation, use suitable respiratory equipment. Environmental exposure controls: Emissions from ventilation or process equipment should be checked to ensure they comply with environmental protection legislation. In some cases, filters or engineering modifications to the process equipment will be necessary to reduce emissions to acceptable levels. SECTION 9. PHYSICAL AND CHEMICAL PROPERTIES 9.1. Information on basic physical and chemical properties Physical sate: Liquid Colour. Conforms to standard Odour. Conforms to standard Melting point/freezing point: CA.-5 Boiling point or initial bolling point and range (0C): 162 -164 Flammability: Not determined Lower and upper explosion limit: Not determined Flash point: 69 °c Auto-ignition temperature: 425°C Decomposition temperature: Not determined pH: Not determined Kinematic viscosity: Not determined Solubility: SOLUBLE IN WATER/ SOLUBLE IN ETHANOL Partition coefficient n-octanol/ water (log value): log Pow 0,79 Vapour pressure: I hPa (20"C);6,5 hPa (50°() Density and/or relative density: 0,954-0,96 g/ml (20°C) / 0,954-0,96 (20°C) Relative vapour density: Not determined Particle characteristics: Not determined 9.2. Other information 9.2.1. Information with regard to phyical hazard classes: No information avaliable. 9.2.2. Other safety characteristics: No information avaliable SECTION 10. STABILITY AND REACTIVITY 10.1. Reactivity No hazardous reactions if stored and handled as prescribed/indicated. 10.2. Chemical stability The product is stable if stored and handled as prescribed/indicated. 10.3. Possibility of hazardous reactions No hazardous reactions if stored and handled as prescribed/indicated. 10.4. Conditions to Avoid Conditions to Avoid: Excessive heat, ftame or other ignition sources. 10.5. Incompatible materials Avoid contact with strong acids and bases and oxidizing agents. 10.6. Hazardous decomposition products During combustion may form carbon monoxide and unidentified organic compounds. SECTION 11. TOXICOLOGICAL INFORMATION 11.1. Information on hazard classes as defined in Regulation (EC) No 1272/2008 Acute toxicity Harmful if swallowed. Skin corrosi.on/lrrltation Causes severe skin burns and eye damage. SMious eye damage/irritation Based on the data available, the criteria for classification are not met. Respiratory or skin sensitisation Based on the data available, the criteria for classification are not met. Germ cell mutagenicity Based on the data available, the criteria for classification are not met. Carcinogenicity Based on the data available, the criteria for classification are not met. Reproductive toxicity Based on the data available, the criteria for classification are not met. STOT-single exposure Based on the data available, the criteria for classification are not met. STOT-repeated exposure Based on the data available, the criteria for classification are not met. Aspiration hazard Based on the data available, the criteria for classification are not met. 11.2. Information on other hazards 11.2.1. Endocrine disrupting properties: Product not containing any component identified as having endocrine disrupting properties according to Regulation ( EU) 2017 /2100. 11.2.2. Other information: No information available SECTION 12. ECOLOGICAL INFORMATION 12.1. Toxicity Assessment: Based on the data available, the criteria for classification are not met. ExperimentaVcalculated data: No information available. 12.2. Persistence and degradability No information available. 12.3. Bioaccumulative potential No information available. 12.4. Soil mobility No information available. 12.S. Results of PBT and vPvB assessment Product not containing any component that meets the criteria for PBT orvPvB according to Regulation (EC) 1907 {2006, Annex XIII. 12.6. Endocrine disrupting properties Product not containing any component identified as having endocrine disrupting properties according to Regulation (EU) 2017 /2100. 12.7. Other adverse effects See also sections 6, 7, 13 and 15 Do not allow to get into waste water or waterways. SECTION 13. DISPOSAL CONSIDERATIONS 13.1. Waste treatment methods Dispose of in accordance with national and local environmental regulations. SECTION 14: TRANSPORT INFORMATION ADR/RID/ADN IMDG IATA-ICAO 14.1. UN Number UN2820 14.2. UN Proper Shipping Name BUTYRIC ACID 14.3. Transport Hazard Class(es) 8 14.4. Packing Group Ill 14.S. Environmental hazards No Additional information 14.6 Special precautions for user None known 14.7. Maritime transport in bulk according to IMO instruments No information available SECTION lS: REGULATORY INFORMATION 15.1. Safety, health and environmental regulations/legislation specific for the substance or mixture WGK:WGKl 15.2; Chemical safety assessment No chemical safety assessment has been carried out for the substance or mixture by the supplier SECTION 16: OTHER INFORMATION Full text of the R-phrases, hazard statements and precautionary statements mentioned in section 3: H302 -Harmful if swallowed. H314 - Causes severe skin burns and eye damage. H318 - Causes serious eye damage. SPECIFICATION SHEET PRODUCT BUTYRIC ACID IUPAC NAME SYNONYMS BUTANOIC ACID BUTANOIC ACID, ETHYLACETIC ACID FORMULA MOLECULAR WEIGHT C4 Ha02 CAS 88,11 EINECS 107-92-6 FEMA 203-532-3 TARIFF NUMBER 2221 2915601990 COOH SPECIFICATIONS VERSION 6 VERSION DATE 10/11/21 ASPECT AT 20°C CLEAR MOBILE LIQUID COLOUR COLORLESS ODOUR RANCID BUTTER, SOUR DENSITY AT 20°C (g I ml) 0,954-0,960 DENSITY 25{2S 0,952-0,956 REFRACTIVE INDEX nD20 1,3970-1,3990 REFRACTIVE INDEX nD2S OPTICAL ROTATION (0) I BOILING POINT (0C) 162-164 MELTING POINT (0C) CA.-5 FLASH POINT (0C) 69 ASSAY(O/oGC) >99,5 ACID VALUE (mg KOH/g) SOLUBILITY SOLUBLE IN WATER. VAPOUR PRESSURE 1 hPa (20°();6,5 hPa (50°C) OTHER SOLUBILITIES SOLUBLE IN ETHANOL OTHER TECHNICAL DATA WATER CONTENTS <0,1%. STABILITY AND STORAGE KEEP IN TIGHTLY CLOSED CONTAINER IN A COOL AND DRY PLACE, PROTECTED FROM LIGHT. WHEN STORED F.OR MORE THAN 24 MONTHS, QUALITY SHOULD BE CHECKED BEFORE USE. WE BELIEVE THE ABOVE INFORMATION TO BE CORRECT BUT WE DO NOT PRESENT IT AS ALL INCLUSIVE ANO AS SUCH SHOULD BE USED AS A GUIDE. IT IS THE SOLE RESPONSIBILITY OF THE RECEIVER OF OUR PRODUCT TO COMPLY WITH EXISTING REGULATIONS ANO INSTRUCTIONS. THIS PRODUCT HAS NOT BEEN FILTERED DUE TO TECHNICAL REASONS. WE RECOMMEND NOTTO USE IT UNLESS FILTERED WHEN USED ASA RAW MATERIAL IN FOOD INTENDED FOR FINAL CONSUMERS. VEGAN 05 February 2025 Product: BUTYRIC ACID This is to certify that, to the best of our knowledge, the above-mentioned material is suitable for the following diets: [Z] Vegan Does not contain any ingredient of animal origin (mammalian, poultry, fish, crustacean, mollusc) or animal derivatives {dairy, egg and bee products) including additives and processing aids. In addition, we confirm that it complies with the requirements listed on the Criteria of the V-label: Regulations, that can be found in Annex1: Criteri_afor the V-Label [Z] Vegetarian Does not contain any ingredient of animal origin (mammalian, poultry, fish, crustacean, mollusc) or dairy and egg products, including. additives and processing aids. Bee products (e.g. honey, bees wax) are acceptable. [{] Ovo-Lacto Vegetarian Does not contain any ingredient of animal origin (mammalian, poultry, fish, crustacean, mollusc), including additives and processing aids. Dairy, egg and bee products (e.g. honey, bees wax) are acceptable. 'Animal' refers to the entire animal kingdom, i.e. vertebrates and multicellular invertebrates. The information indicated above corresponds to our knowledge at the date of issue. This document is electronically generated and therefore it is not signed