Bug Repellent EOB

Madar Corporation Limited

Revision date : 2025-03-03

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GHS05 GHS09 GHS07 GHS08
Health risk rating 4
Safety risk rating 1
Environmental risk rating 4

Note: Ingredients listed on restricted chemical lists

EC/CAS

201-944-8/89-83-8

Name of the chemical

Thymol

Concentration

9.50%

Listed in

EC/CAS

202-794-6/99-85-4

Name of the chemical

gamma-Terpinene; p-Mentha-1,4-diene

Concentration

2.18%

EC/CAS

231-415-7/7540-51-4

Name of the chemical

(3S)-3,7-dimethyloct-6-en-1-ol

Concentration

2.11%

EC/CAS

201-134-4/78-70-6

Name of the chemical

1,6-Octadien-3-ol, 3,7-dimethyl

Concentration

1.81%

EC/CAS

203-377-1/106-24-1

Name of the chemical

2,6-Octadien-1-ol, 3,7-dimethyl-, (2E)

Concentration

1.79%

EC/CAS

227-815-6/5989-54-8

Name of the chemical

(S)-p-mentha-1,8-diene; (l-limonene) (37)

Concentration

1.76%

EC/CAS

201-291-9/80-56-8

Name of the chemical

α-pinene

Concentration

0.87%

EC/CAS

201-746-1/87-44-5

Name of the chemical

(1R,4E,9S)-4,11,11-Trimethyl-8-methylenebicyclo[7.2.0]undec-4-ene (40)

Concentration

0.44%

EC/CAS

204-872-5/127-91-3

Name of the chemical

β-pinene

Concentration

0.19%

EC/CAS

200-945-0/76-22-2

Name of the chemical

camphor

Concentration

0.15%

EC/CAS

209-578-0/586-62-9

Name of the chemical

p-Mentha-1,4(8)-diene (38)

Concentration

0.10%

General Information

Version

Madar Corporation Limited, 19-20 Sandleheath Industrial Estate, Fordingbridge, Hampshire, SP6 1PA

Revision date

2025-03-03

Product name

Bug Repellent EOB

Product Synonyms

None

1.2.1 Relevant identified uses

Essential Oil

Icons in SDS

GHS05 GHS07 GHS08 GHS09 M004 M009 M013 M017

Company Information

company name

Madar Corporation Limited

e-mail address of the competent person responsible for the Safety Data Sheet

technical@madarcorporation.co.uk

GHS Information

Signal word

Danger

Hazard Codes

Hazard statements (CLP)

H304, H314, H317, H361, H400, H411

Hazard statements

Code

Statements

H304

May be fatal if swallowed and enters airways

Section 2

SECTION 2: Hazards identification

Signal word

Danger

Hazard statements

H304, May be fatal if swallowed and enters airways. H314, Causes severe skin burns and eye damage. H317, May cause an allergic skin reaction. H361, Suspected of damaging fertility or the unborn child (exposure route). H400, Very toxic to aquatic life. H411, Toxic to aquatic life with long lasting effects.

Additional information

EUH208, Contains 1-Octen-3-ol, Carvacrol, Citronellyl formate, Citronellyl tiglate, Eucalyptol, Geraniol, Geranyl formate, Linalool, Menthone, Nerol, Terpinolene, alpha-Pinene, beta- Caryophyllene, beta-Pinene, d,l-Isomenthone, l-Citronellol, l-Limonene. May produce an allergic reaction.

Precautionary statements

P101, If medical advice is needed, have product container or label at hand. P102, Keep out of reach of children. P202, Do not handle until all safety precautions have been read and understood. P260, Do not breathe vapour or dust. P264, Wash hands and other contacted skin thoroughly after handling. P272, Contaminated work clothing should not be allowed out of the workplace. P273, Avoid release to the environment. P280, Wear protective gloves/eye protection/face protection. P301/310, IF SWALLOWED: Immediately call a POISON CENTER or doctor/physician. P301/330/331, If swallowed: Rinse mouth. Do not induce vomiting. P303/361/353, IF ON SKIN (or hair): Remove/take off immediately all contaminated clothing. Rinse skin with water/shower. P304/340, IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing. P305/351/338, IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P308/313, IF exposed or concerned: Get medical advice/attention. P310, Immediately call a POISON CENTER or doctor/physician. P331, Do not induce vomiting. P333/313, If skin irritation or rash occurs: Get medical advice/attention. P363, Wash contaminated clothing before reuse. P370/378, In case of fire: Use carbon dioxide, dry chemical, foam for extinction. P391, Collect spillage. P403/235, Store in a well-ventilated place. Keep cool. P405, Store locked up. P501, Dispose of contents/container to approved disposal site, in accordance with local regulations.

Other hazards

Sensitisers declared on a CLP 1-Octen-3-ol, Carvacrol, Citronellyl formate, Citronellyl tiglate, Hazard Label: Eucalyptol, Geraniol, Geranyl formate, Linalool, Menthone, Nerol, Terpinolene, alpha-Pinene, beta-Caryophyllene, beta- Pinene, d,l-Isomenthone, l-Citronellol, l-Limonene Hydrocarbon Concentration %: 43.1740%

2.1 Classification of the substance or mixture

Classification under Regulation (EC) No 1272/2008 Class and category of Skin Corrosion / Irritation Category 1B danger: Eye Damage / Irritation Category 1 Sensitization - Skin Category 1 Toxic to Reproduction Category 2 Aspiration Hazard Category 1 Hazardous to the Aquatic Environment - Acute Hazard Category 1 Hazardous to the Aquatic Environment - Long-term Hazard Category 2 H304, May be fatal if swallowed and enters airways. H314, Causes severe skin burns and eye damage. H317, May cause an allergic skin reaction. H361, Suspected of damaging fertility or the unborn child (exposure route). H400, Very toxic to aquatic life. H411, Toxic to aquatic life with long lasting effects. 1 2.2 Label elements Classification under Regulation (EC) No 1272/2008 Signal word: Danger Hazard statements: H304, May be fatal if swallowed and enters airways. H314, Causes severe skin burns and eye damage. H317, May cause an allergic skin reaction. H361, Suspected of damaging fertility or the unborn child (exposure route). H400, Very toxic to aquatic life. H411, Toxic to aquatic life with long lasting effects. Supplemental EUH208, Contains 1-Octen-3-ol, Carvacrol, Citronellyl formate, Citronellyl tiglate, Eucalyptol, Information: Geraniol, Geranyl formate, Linalool, Menthone, Nerol, Terpinolene, alpha-Pinene, beta- Caryophyllene, beta-Pinene, d,l-Isomenthone, l-Citronellol, l-Limonene. May produce an allergic reaction. Precautionary P101, If medical advice is needed, have product container or label at hand. statements: P102, Keep out of reach of children. P202, Do not handle until all safety precautions have been read and understood. P260, Do not breathe vapour or dust. P264, Wash hands and other contacted skin thoroughly after handling. P272, Contaminated work clothing should not be allowed out of the workplace. P273, Avoid release to the environment. P280, Wear protective gloves/eye protection/face protection. P301/310, IF SWALLOWED: Immediately call a POISON CENTER or doctor/physician. P301/330/331, If swallowed: Rinse mouth. Do not induce vomiting. P303/361/353, IF ON SKIN (or hair): Remove/take off immediately all contaminated clothing. Rinse skin with water/shower. P304/340, IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing. P305/351/338, IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P308/313, IF exposed or concerned: Get medical advice/attention. P310, Immediately call a POISON CENTER or doctor/physician. P331, Do not induce vomiting. P333/313, If skin irritation or rash occurs: Get medical advice/attention. P363, Wash contaminated clothing before reuse. 1 P370/378, In case of fire: Use carbon dioxide, dry chemical, foam for extinction. P391, Collect spillage. P403/235, Store in a well-ventilated place. Keep cool. P405, Store locked up. P501, Dispose of contents/container to approved disposal site, in accordance with local regulations. Pictograms: 2.3 Other hazards Other hazards: Sensitisers declared on a CLP 1-Octen-3-ol, Carvacrol, Citronellyl formate, Citronellyl tiglate, Hazard Label: Eucalyptol, Geraniol, Geranyl formate, Linalool, Menthone, Nerol, Terpinolene, alpha-Pinene, beta-Caryophyllene, beta- Pinene, d,l-Isomenthone, l-Citronellol, l-Limonene Hydrocarbon Concentration %: 43.1740% Section 3. Composition / information on ingredients 3.2 Mixtures Contains: Name Specific Conc. CAS EC REACH Registration % Classification for Limits, M-factors No. (CLP) 1272/2008 and ATEs Skin Irrit. 2-Eye Dam. 1-Skin Sens. 1-Asp. Tox 1-Aquatic Acute 1- dermal: ATE = 4230 CITRONELLA JAVA 8000-29-1 25.00% Aquatic Chronic 2; mg/kg bw-oral: ATE = 4704 mg/kg bw H304-H315-H317- H318-H400-H411,- Skin Irrit. 2-Eye Dam. Lemongrass Oil Cochin 25.00% 1-Skin Sens. 1-Asp. Natural Tox 1;H304-H315- H317-H318,- Eucalyptol 470-82-6 207-431-5 16.10% 3-Skin Sens. oral: ATE = 2480 1B;H226-H317,- mg/kg bw Acute Tox. 4-Skin Corr. Thymol 89-83-8 201-944-8 9.50% 1B-Eye Dam. 1-Aquatic oral: ATE = 980 mg/kg Chronic 2;H302-H314- bw H411,- -Repr. 2- Asp. Tox p-Cymene 99-87-6 202-796-7 4.23% 1-Aquatic Chronic oral: ATE = 4750 2;H226-H304- mg/kg bw H361-H411,- Repr. 2- Asp. Tox oral: ATE = 3850 p-Mentha-1,4-diene 99-85-4 202-794-6 2.18% 1;H226-H304- H361,- mg/kg bw 1 Skin Irrit. 2-Eye Irrit. 2- dermal: ATE = 2650 l-Citronellol 7540-51-4 231-415-7 2.11% Skin Sens. 1B;H315- mg/kg bw-oral: ATE = H317-H319,- 3450 mg/kg bw Skin Irrit. 2-Eye Irrit. 2- oral: ATE = 2790 Linalool 78-70-6 201-134-4 1.81% Skin Sens. 1B;H315- mg/kg bw H317-H319,- Skin Irrit. 2-Eye Dam. oral: ATE = 3600 Geraniol 106-24-1 203-377-1 1.79% 1-Skin Sens. 1;H315- mg/kg bw H317-H318,- Flam. Liq. 3-Skin Irrit. 2-Skin Sens. 1B-Asp. Tox 1-Aquatic Acute 1- l-Limonene 5989-54-8 227-815-6 1.76% Aquatic Chronic 3; M = 1 H226-H304-H315- H317-H400-H412,- Flam. Liq. 3-Acute Tox. 4-Skin Irrit. 2-Skin Sens. 1B-Asp. Tox 1- alpha-Pinene 80-56-8 201-291-9 0.87% Aquatic Acute 1- M = 1-oral: ATE = 500 Aquatic Chronic 1; mg/kg bw H226-H302-H304- H315-H317-H410,- d,l-Isomenthone 491-07-6 207-727-4 0.81% Skin Irrit. 2-Skin Sens. oral: ATE = 2500 1B;H315-H317,- mg/kg bw Citronellyl formate 105-85-1 203-338-9 0.79% Skin Irrit. 2-Skin Sens. 1B;H315-H317,- Skin Sens. 1B-Aquatic Geranyl formate 105-86-2 203-339-4 0.59% Acute 1-Aquatic M = 1 Chronic 2;H317-H400- H411,- Acute Tox. 4-Skin Irrit. Carvacrol 499-75-2 207-889-6 0.56% 2-Eye Irrit. 2-Skin oral: ATE = 810 mg/kg Sens. 1B;H302-H315- bw H317-H319,- Flam. Liq. 3-Skin Irrit. 2-Eye Irrit. 2-Asp. Tox 1-Aquatic Acute 1- Myrcene 123-35-3 204-622-5 0.48% Aquatic Chronic 2; M = 1 H226-H304-H315- H319-H400-H411,- Skin Sens. 1B-Asp. beta-Caryophyllene 87-44-5 201-746-1 0.44% Tox 1-Aquatic Chronic 4;H304-H317-H413,- Flam. Liq. 3-Skin Irrit. 2-Skin Sens. 1B-Asp. Tox 1-Aquatic Acute 1- beta-Pinene 127-91-3 204-872-5 0.19% Aquatic Chronic 1; M = 1 H226-H304-H315- H317-H410,- Acute Tox. 4-Skin Irrit. 2-Skin Sens. 1B- oral: ATE = 500 mg/kg Menthone

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