Photometer PF-3 Fish, case

Hazard statements (CLP)

H225, H226, H290, H302, H314, H315, H317, H318, H319, H334, H411, H412

Code

Statements

H225

Highly Flammable liquid and vapour

SECTION 2: Hazards identification

2.0 Classification of the complete product GHS02 GHS05 GHS07 GHS08 GHS09

Signal word

DANGER Hazard classes/categories EUH031 031 not defined H225 Flam. Liq. 2 H226 Flam. Liq. 3 H290 Met. Corr. 1 H302 Acute Tox. 4 oral H314 Skin Corr. 1A H315 Skin Irrit. 2 H317 Skin Sens. 1 H318 Eye Dam. 1 H319 Eye Irrit. 2 H334 Resp. Sens. 1 H411 Aquatic Chronic 2 H412 Aquatic Chronic 3 - No hazard class Button cell CR2032, built-in Do not need labelling as hazardous - No hazard class 30 mL Cu-1 Do not need labelling as hazardous - No hazard class 20 mL Cu-2 Do not need labelling as hazardous - No hazard class 17 mL Fe-1 Do not need labelling as hazardous - No hazard class 5 g Fe-2 Do not need labelling as hazardous - No hazard class 10 mL Indicator m GHS02 DANGER Hazard classes/categories H225 Flam. Liq. 2 50 capsules NANOFIX pH 6.5-8.2 Do not need labelling as hazardous - No hazard class 100 mL P-1 GHS05 DANGER Hazard classes/categories H290 Met. Corr. 1 H314 Skin Corr. 1A 100 mL P-2 GHS05 DANGER Hazard classes/categories EUH031 031 not defined H318 Eye Dam. 1 100 test strips Do not need labelling as hazardous - No hazard class 100 mL TL AL 7 Do not need labelling as hazardous - No hazard class 28 g Cl 2 -1 Do not need labelling as hazardous - No hazard class 30 mL NH 4 -1 GHS05 DANGER Hazard classes/categories H290 Met. Corr. 1 H314 Skin Corr. 1A 2,5 g NH 4 -2 Do not need labelling as hazardous - No hazard class 6 mL NH 4 -3 GHS02 GHS05 DANGER Hazard classes/categories H226 Flam. Liq. 3 H314 Skin Corr. 1B H412 Aquatic Chronic 3 30 mL NO 3 -1 Do not need labelling as hazardous - No hazard class 5 g NO 3 -2 GHS09 WARNING Hazard classes/categories H411 Aquatic Chronic 2 30 mL NO 2 -1 Do not need labelling as hazardous - Hazard classes/categories H290 Met. Corr. 1 5 g NO 2 -2 Do not need labelling as hazardous - No hazard class 25 mL PO 4 -1 GHS07 WARNING Hazard classes/categories H315 Skin Irrit. 2 H319 Eye Irrit. 2 25 mL PO 4 -2 GHS05 DANGER Hazard classes/categories EUH031 031 not defined H318 Eye Dam. 1 15 mL O 2 -1 GHS07 GHS09 WARNING Hazard classes/categories H302 Acute Tox. 4 oral H411 Aquatic Chronic 2 15 mL O 2 -2 GHS05 DANGER Hazard classes/categories H290 Met. Corr. 1 H314 Skin Corr. 1A 30 mL O 2 -3 GHS05 GHS07 GHS08 DANGER Hazard classes/categories H314 Skin Corr. 1A H317 Skin Sens. 1 H334 Resp. Sens. 1 25 mL SiO 2 -3 GHS05 DANGER Hazard classes/categories EUH031 031 not defined H318 Eye Dam. 1 25 mL SiO 2 -2 Do not need labelling as hazardous - No hazard class 25 mL SiO 2 -1 GHS07 WARNING Hazard classes/categories H315 Skin Irrit. 2 H319 Eye Irrit. 2 30 mL Cl 2 -2 Do not need labelling as hazardous - No hazard class - Button cell CR2032, built-in Do not need labelling as hazardous - 30 mL Cu-1 Do not need labelling as hazardous - 20 mL Cu-2 Do not need labelling as hazardous - 17 mL Fe-1 Do not need labelling as hazardous - 5 g Fe-2 Do not need labelling as hazardous - 10 mL Indicator m GHS02 DANGER 50 capsules NANOFIX pH 6.5-8.2 Do not need labelling as hazardous - 100 mL P-1 GHS05 DANGER H314 Causes severe skin burns and eye damage. P260sh, P280sh, P303+361+353, P305+351+338, P310 Do not breathe dust/vapours. Wear protective gloves/eye protection. IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water [or shower]. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Immediately call a POISON CENTER/doctor. 100 mL P-2 GHS05 DANGER H318 Causes serious eye damage. P280sh, P305+351+338, P310 Wear protective gloves/eye protection. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Immediately call a POISON CENTER/doctor. 100 test strips Do not need labelling as hazardous - 100 mL TL AL 7 Do not need labelling as hazardous - 28 g Cl 2 -1 Do not need labelling as hazardous - 30 mL NH 4 -1 GHS05 DANGER H314 Causes severe skin burns and eye damage. P260sh, P280sh, P303+361+353, P305+351+338, P310 Do not breathe dust/vapours. Wear protective gloves/eye protection. IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water [or shower]. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Immediately call a POISON CENTER/doctor. 2,5 g NH 4 -2 Do not need labelling as hazardous - 6 mL NH 4 -3 GHS02 GHS05 DANGER H314 Causes severe skin burns and eye damage. P260sh, P280sh, P303+361+353, P305+351+338, P310 Do not breathe dust/vapours. Wear protective gloves/eye protection. IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water [or shower]. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Immediately call a POISON CENTER/doctor. 30 mL NO 3 -1 Do not need labelling as hazardous - 5 g NO 3 -2 GHS09 30 mL NO 2 -1 Do not need labelling as hazardous - 5 g NO 2 -2 Do not need labelling as hazardous - 25 mL PO 4 -1 GHS07 25 mL PO 4 -2 GHS05 DANGER H318 Causes serious eye damage. P280sh, P305+351+338, P310 Wear protective gloves/eye protection. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Immediately call a POISON CENTER/doctor. 15 mL O 2 -1 GHS07 GHS09 15 mL O 2 -2 GHS05 DANGER H314 Causes severe skin burns and eye damage. P260sh, P280sh, P303+361+353, P305+351+338, P310 Do not breathe dust/vapours. Wear protective gloves/eye protection. IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water [or shower]. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Immediately call a POISON CENTER/doctor. 30 mL O 2 -3 GHS05 GHS07 GHS08 DANGER H314, H317, H334 Causes severe skin burns and eye damage. May cause an allergic skin reaction. May cause allergy or asthma symptoms or breathing difficulties if inhaled. P260sh, P280sh, P303+361+353, P305+351+338, P310 Do not breathe dust/vapours. Wear protective gloves/eye protection. IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water [or shower]. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Immediately call a POISON CENTER/doctor. 25 mL SiO 2 -3 GHS05 DANGER H318 Causes serious eye damage. P280sh, P305+351+338, P310 Wear protective gloves/eye protection. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Immediately call a POISON CENTER/doctor. 25 mL SiO 2 -2 Do not need labelling as hazardous - 25 mL SiO 2 -1 GHS07 30 mL Cl 2 -2 Do not need labelling as hazardous -

2.1 Classification of the substance or mixture

Alkaline Manganese Batteries Type AA Do not need labelling as hazardous

2.2 Label elements

According CLP directive inner packages must be only labelled with GHS symbol(s) and product identificator(s) (EU 1272/2008 Annex I - 1.5.1.2). Harmful chemicals/mixtures with signal word: WARNING and highly flammable chemicals/mixtures must not be labelled with H and P phrases until 125 mL (EU 1272/2008 Annex I - 1.5.2). This labelling exemption is NOT valid for sensibilizing substances. Metal corrosive solutions do not have to be labelled with GHS symbol, signal word, H and P phrases until 125 mL (EU 1272/2008 Annex I - 1.5.2.1.3). Alkaline Manganese Batteries Type AA Do not need labelling as hazardous

2.3 Other hazards

Possible hazards from physicochemical properties Generally in the case of pH values are less than 2 or higher than 11.5 then it is corrosive. In the case of pH values are less than 5 or higher than 9 then it is irritant. Flammable properties. The property H314 "Causes severe skin burns and eye damage." of some salts is not applicable, because the mixture is buffered to pH >3-4 (see GHS Directive 1272/2008/EC Annex I, chapter 3.2.3.1.2.). H290 "May be corrosive to metals." has only relevance for higher concentrations and larger amounts. The labelling GHS05 would be creating an "OVERLABELLING" (see GHS Directive 1272/2008/EC Annex I, chapter 1.5.2.1.3., until 125 mL no labelling necessary). --- Information pertaining to particular risks to human and possible symptoms Causes varying degrees of acid burns on the skin, to the eyes and to the mucous membranes and wounds which do not heal quickly depending on the concentration, temperature and the exposure time. Vapours especially which steam from hot liquids and mist can have a severe irritant effect upon the eyes and the respiratory organs. Cause after oral intake, skin contact, impairments of health when ingested in small quantities. May cause sensitization by skin contact, also in repeated contact of small amounts. May cause allergy or asthma symptoms or breathing difficulties if inhaled. - Information pertaining to particular risks to the environment Avoid contact of substance/mixture to environment.

PBT Substances

not applicable

vPvB Substances

not applicable

Other hazards

Contains an odor intensive reagent. This SDS contains information on shipping and transport safety. ---