NucleoSpin RNA Plus (50)

Hazard statements (CLP)

H226, H302, H315, H317, H318, H319, H411

Code

Statements

H226

Flammable liquid and vapour

SECTION 2: Hazards identification

2.0 Classification of the complete Product GHS02 GHS05 GHS07 GHS09

Signal word

DANGER Hazard Classes/Categories H226 Flam. Liq. 3 H302 Acute Tox. 4 oral H315 Skin Irrit. 2 H317 Skin Sens. 1 H318 Eye Dam. 1 H411 Aquatic Chronic 2 Classification of the substance or mixture 25 mL LBP GHS05 GHS07 GHS09 DANGER Hazard Identification Hazard Classes/Categories H302 Acute Tox. 4 oral H317 Skin Sens. 1 H318 Eye Dam. 1 H411 Aquatic Chronic 2 mL BS Do not need labelling as hazardous No Hazard Class mL WB1 GHS02 GHS07 WARNING Hazard Identification Hazard Classes/Categories H226 Flam. Liq. 3 H302 Acute Tox. 4 oral H315 Skin Irrit. 2 H319 Eye Irrit. 2 mL RNase-free H 2 O Do not need labelling as hazardous No Hazard Class mL WB2 Do not need labelling as hazardous No Hazard Class List of H phrases: see section 16.2 Safety, Health and Environmental Regulations/Legislation specific for the Substance or Mixture According the implementation of GHS immediate packages only must be labelled with product identificator(s), GHS symbol(s), signal word, manufacturer name and phone number (OSHA's interpretation of HCS 2012). Harmful chemicals/mixtures with signal word WARNING and highly flammable chemicals/mixtures must not be labelled with H and P phrases until 125 mL (EU 1272/2008 Annex I - 1.5.2) / until 100 mL (Canada WHMIS 2015). This labelling exemption does not apply to U.S.A. This labelling exemption is NOT valid for sensibilizing substances 25 mL LBP GHS05 GHS09 Signal Word: DANGER H317, H318 May cause an allergic skin reaction.Causes serious eye damage P261sh, P280sh, P305+351+338, P310 Avoid breathing dust/vapors.Immediately call a POISON CENTER/doctor.Wear protective gloves/eye protection.IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing mL BS Do not need labelling as hazardous - mL WB1 GHS02 GHS07 mL RNase-free H 2 O Do not need labelling as hazardous - mL WB2 Do not need labelling as hazardous - Label elements of the complete product GHS02 GHS05 GHS09 DANGER H317, H318 May cause an allergic skin reaction.Causes serious eye damage. P261sh, P280sh, P305+351+338, P310 Avoid breathing dust/vapors.Immediately call a POISON CENTER/doctor.Wear protective gloves/eye protection.IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.

2.3 Other hazards

Possible Hazards from physicochemical Properties Generally in the case of pH values are less than 2 or higher than 11.5 then it is corrosive. In the case of pH values are less than 5 or higher than 9 then it is irritant. Flammable properties. For guanidine thiocyanate CAS 593-84-0: The properties H314, H332 "Causes severe skin burns and eye damage. Harmful if inhaled." are not relevant, because the mixture solution is buffered to pH 4-9 (see GHS Directive 1272/2008/EC Annex I, chapter 3.2.3.1.2.). Information pertaining to particular Risks to Human and possible Symptoms Causes varying degrees of acid burns on the skin, to the eyes and to the mucous membranes and wounds which do not heal quickly depending on the concentration, temperature and the exposure time. Vapors especially which steam from hot liquids and mist can have a severe irritant effect upon the eyes and the respiratory organs. Cause after oral intake, skin contact, impairments of health when ingested in small quantities. May cause sensitization by skin contact, also in repeated contact of small amounts. Information pertaining to particular Risks to the Environment

PBT Substances

not applicable

vPvB Substances

not applicable Possible endocrine disrupting effects data not available

2.1 Classification of the substance or mixture

25 mL LBP GHS05 GHS07 GHS09 Signal Word DANGER Hazard Identification Hazard Classes/Categories H302 Acute Tox. 4 oral H317 Skin Sens. 1 H318 Eye Dam. 1 H411 Aquatic Chronic 2 6 mL BS Do not need labelling as hazardous Signal Word - No Hazard Class 12 mL WB1 GHS02 GHS07 Signal Word WARNING Hazard Identification Hazard Classes/Categories H226 Flam. Liq. 3 H302 Acute Tox. 4 oral H315 Skin Irrit. 2 H319 Eye Irrit. 2 13 mL RNase-free H 2 O Do not need labelling as hazardous Signal Word - No Hazard Class 12 mL WB2 Do not need labelling as hazardous Signal Word - No Hazard Class List of H phrases: see section 16.2 2.2 Safety, Health and Environmental Regulations/Legislation specific for the Substance or Mixture According the implementation of GHS immediate packages only must be labelled with product identificator(s), GHS symbol(s), signal word, manufacturer name and phone number (OSHA's interpretation of HCS 2012). Harmful chemicals/mixtures with signal word: WARNING and highly flammable chemicals/mixtures must not be labelled with H and P phrases until 125 mL (EU 1272/2008 Annex I - 1.5.2) / until 100 mL (Canada WHMIS 2015). This labelling exemption does not apply to U.S.A. This labelling exemption is NOT valid for sensibilizing substances. 25 mL LBP GHS05 GHS09 Signal Word: DANGER H317, H318 May cause an allergic skin reaction.Causes serious eye damage. P261sh, P280sh, P305+351+338, P310 Avoid breathing dust/vapors.Immediately call a POISON CENTER/doctor.Wear protective gloves/eye protection.IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. 6 mL BS Do not need labelling as hazardous Signal Word: - 12 mL WB1 GHS02 GHS07 Signal Word: WARNING 13 mL RNase-free H 2 O Do not need labelling as hazardous Signal Word: - 12 mL WB2 Do not need labelling as hazardous Signal Word: -