NANOCOLOR Sludge

Hazard statements (CLP)

H290, H314, H315, H319, H331, H335

Code

Statements

H290

May be corrosive to metals

SECTION 2: Hazards identification

2.0 Classification of the complete product GHS05 GHS06 GHS07

Signal word

DANGER Hazard classes/categories H290 Met. Corr. 1 H314 Skin Corr. 1A H315 Skin Irrit. 2 H319 Eye Irrit. 2 H331 Acute Tox. 3 inh. H335 STOT SE 3 Classification of the substance or mixture mL Sludge R1 GHS05 GHS07 DANGER Hazard identification Hazard classes/categories H290 Met. Corr. 1 H314 Skin Corr. 1B H335 STOT SE 3 mL Sludge R2 GHS05 GHS06 DANGER Hazard identification Hazard classes/categories H290 Met. Corr. 1 H314 Skin Corr. 1A H331 Acute Tox. 3 inh 100 mL Sludge R3 GHS07 WARNING Hazard identification Hazard classes/categories H315 Skin Irrit. 2 H319 Eye Irrit. 2 50 mL Sludge R4 GHS05 DANGER Hazard identification Hazard classes/categories H290 Met. Corr. 1 H314 Skin Corr. 1A 30 mL Sludge R5 Do not need labelling as hazardous No hazard class DANGER H314 Causes severe skin burns and eye damage. P260sh, P280sh, P303+361+353, P305+351+338, P310 Do not breathe dust/vapours. Wear protective gloves/eye protection. IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water [or shower]. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Immediately call a POISON CENTER/doctor. 2.3 mL Sludge R2 GHS05 GHS06 DANGER H314, H331 Causes severe skin burns and eye damage. Toxic if inhaled. P260sh, P280sh, P303+361+353, P305+351+338, P310, P311, P405 Do not breathe dust/vapours. Wear protective gloves/eye protection. IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water [or shower]. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Immediately call a POISON CENTER/doctor. Call a POISON CENTER/doctor. Store locked up. 100 mL Sludge R3 GHS07 50 mL Sludge R4 GHS05 DANGER H314 Causes severe skin burns and eye damage. P260sh, P280sh, P303+361+353, P305+351+338, P310 Do not breathe dust/vapours. Wear protective gloves/eye protection. IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water [or shower]. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Immediately call a POISON CENTER/doctor. 30 mL Sludge R5 Do not need labelling as hazardous -

2.2 Label elements

According CLP directive inner packages must be only labelled with GHS symbol(s) and product identificator(s) (EU 1272/2008 Annex I - 1.5.1.2). Harmful chemicals/mixtures with signal word: WARNING must not be labelled with H and P phrases until 125 mL (EU 1272/2008 Annex I - 1.5.2). Metal corrosive solutions do not have to be labelled with GHS symbol, signal word, H and P phrases until 125 mL (EU 1272/2008 Annex I - 1.5.2.1.3). 7 mL Sludge R1 GHS05 GHS07

2.3 Other hazards

Possible hazards from physicochemical properties Generally in the case of pH values are less than 2 or higher than 11.5 then it is corrosive. In the case of pH values are less than 5 or higher than 9 then it is irritant. The property H314 "Causes severe skin burns and eye damage." of some salts is not applicable, because the mixture is buffered to pH >3-4 (see GHS Directive 1272/2008/EC Annex I, chapter 3.2.3.1.2.). H290 "May be corrosive to metals." has only relevance for higher concentrations and larger amounts. The labelling GHS05 would be creating an "OVERLABELLING" (see GHS Directive 1272/2008/EC Annex I, chapter 1.5.2.1.3., until 125 mL no labelling necessary). --- Information pertaining to particular risks to human and possible symptoms Causes varying degrees of acid burns on the skin, to the eyes and to the mucous membranes and wounds which do not heal quickly depending on the concentration, temperature and the exposure time. Vapours especially which steam from hot liquids and mist can have a severe irritant effect upon the eyes and the respiratory organs. Cause severe after inhalation of vapours, impairments of health or can lead to death even when only ingested in small quantities. Cause after inhalation of vapours/dust, impairments of health when ingested in small quantities. - Information pertaining to particular risks to the environment Avoid contact of substance/mixture to environment.

PBT Substances

not applicable

vPvB Substances

not applicable

Other hazards

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2.1 Classification of the substance or mixture

7 mL Sludge R1 GHS05 GHS07 Signal word DANGER Hazard identification Hazard classes/categories H290 Met. Corr. 1 H314 Skin Corr. 1B H335 STOT SE 3 2.3 mL Sludge R2 GHS05 GHS06 Signal word DANGER Hazard identification Hazard classes/categories H290 Met. Corr. 1 H314 Skin Corr. 1A H331 Acute Tox. 3 inh. 100 mL Sludge R3 GHS07 Signal word WARNING Hazard identification Hazard classes/categories H315 Skin Irrit. 2 H319 Eye Irrit. 2 50 mL Sludge R4 GHS05 Signal word DANGER Hazard identification Hazard classes/categories H290 Met. Corr. 1 H314 Skin Corr. 1A 30 mL Sludge R5 Do not need labelling as hazardous Signal word - No hazard class