NANOCOLOR Organic acids 3000

Hazard statements (CLP)

H290, H302, H312, H314, H315, H317, H319, H351, H373, H400

Code

Statements

H290

May be corrosive to metals

SECTION 2: Hazards identification

2.0 Classification of the complete product GHS05 GHS07 GHS08 GHS09

Signal word

DANGER Hazard classes/categories H290 Met. Corr. 1 H302 Acute Tox. 4 oral H312 Acute Tox. 4 derm. H314 Skin Corr. 1A H315 Skin Irrit. 2 H317 Skin Sens. 1 H319 Eye Irrit. 2 H351 Carc. 2 H373 STOT RE 2 H400 Aquatic Acute 1 WARNING Hazard classes/categories H315 Skin Irrit. 2 H319 Eye Irrit. 2 0.5 mL organic Acids 3000 (R0) GHS07 GHS08 WARNING Hazard classes/categories H302 Acute Tox. 4 oral H373 STOT RE 2 11 mL organic Acids 3000 (R2) GHS07 WARNING Hazard classes/categories H315 Skin Irrit. 2 H319 Eye Irrit. 2 1.5 g organic Acids 3000 (R3) GHS07 GHS08 GHS09 WARNING Hazard classes/categories H290 Met. Corr. 1 H302 Acute Tox. 4 oral H312 Acute Tox. 4 derm. H315 Skin Irrit. 2 H317 Skin Sens. 1 H319 Eye Irrit. 2 H351 Carc. 2 H373 STOT RE 2 H400 Aquatic Acute 1 22 mL organic Acids 3000 (R4) GHS05 DANGER Hazard classes/categories H290 Met. Corr. 1 H314 Skin Corr. 1A 45 mL organic Acids 3000 (R5) Do not need labelling as hazardous - No hazard class 0.5 mL organic Acids 3000 (R0) GHS07 GHS08 11 mL organic Acids 3000 (R2) GHS07 1.5 g organic Acids 3000 (R3) GHS07 GHS08 GHS09 H317, H351 May cause an allergic skin reaction. Suspected of causing cancer. P261sh, P280sh Avoid breathing dust/vapours. Wear protective gloves/eye protection. 22 mL organic Acids 3000 (R4) GHS05 DANGER H314 Causes severe skin burns and eye damage. P260sh, P280sh, P303+361+353, P305+351+338, P310 Do not breathe dust/vapours. Wear protective gloves/eye protection. IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water [or shower]. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Immediately call a POISON CENTER/doctor. 45 mL organic Acids 3000 (R5) Do not need labelling as hazardous -

2.1 Classification of the substance or mixture

5 mL Blank (NULL) GHS07

2.2 Label elements

According CLP directive inner packages must be only labelled with GHS symbol(s) and product identificator(s) (EU 1272/2008 Annex I - 1.5.1.2). Inner packages up to 10 mL need max. 2 symbols (Annex I - 1.5.2.4.1 / 2). Harmful chemicals/mixtures with signal word: WARNING must not be labelled with H and P phrases until 125 mL (EU 1272/2008 Annex I - 1.5.2). This labelling exemption is NOT valid for sensibilizing substances. Metal corrosive solutions do not have to be labelled with GHS symbol, signal word, H and P phrases until 125 mL (EU 1272/2008 Annex I - 1.5.2.1.3). 5 mL Blank (NULL) GHS07

2.3 Other hazards

Possible hazards from physicochemical properties Generally in the case of pH values are less than 2 or higher than 11.5 then it is corrosive. In the case of pH values are less than 5 or higher than 9 then it is irritant. H290 "May be corrosive to metals." has only relevance for higher concentrations and larger amounts. The labelling GHS05 would be creating an "OVERLABELLING" (see GHS Directive 1272/2008/EC Annex I, chapter 1.5.2.1.3., until 125 mL no labelling necessary). --- Information pertaining to particular risks to human and possible symptoms Causes varying degrees of acid burns on the skin, to the eyes and to the mucous membranes and wounds which do not heal quickly depending on the concentration, temperature and the exposure time. Vapours especially which steam from hot liquids and mist can have a severe irritant effect upon the eyes and the respiratory organs. Cause after oral intake, inhalation of vapours/dust, skin contact, impairments of health when ingested in small quantities. May cause sensitization by skin contact, also in repeated contact of small amounts. Suspected of causing cancer. - Information pertaining to particular risks to the environment Avoid contact of substance/mixture to environment.

PBT Substances

not applicable

vPvB Substances

not applicable