Note: Ingredients listed on restricted chemical lists
EC/CAS
201-069-1/77-92-9
Name of the chemical
Citric acid
Concentration
60-<80%
EC/CAS
215-185-5/1310-73-2
Name of the chemical
sodium hydroxide
Concentration
10-<20%
EC/CAS
7732-18-5
Name of the chemical
Water, distilled, conductivity or of similar purity H2O
Concentration
N/A
General Information
Version
M V
Revision date
2019-05-20
Product name
NANOCOLOR Nickel 7
REACH No
see
1.2.1 Relevant identified uses
Product for analytical use Exposure Scenario Classification according REACh, RIP 3.2 Codes: SU 0-2, PC 21, PROC 15, AC 0 The exposure scenario is integrated into sections 1-16
1.2.2. Uses advised against
not described
Manufacturer Name
MACHEREY-NAGEL GmbH & Co. KG
Emergency telephone
+49 361 730 730
Icons in SDS
Company Information
company name
MACHEREY-NAGEL GmbH & Co. KG
e-mail address of the competent person responsible for the Safety Data Sheet
sds@mn-net.com
GHS Information
Signal word
DANGER
Hazard Codes
Hazard statements (CLP)
H272, H290, H303, H314, H315, H316, H317, H319, H334, H335
Hazard statements
Code
Statements
H272
May intensify fire; oxidiser
Section 2
SECTION 2: Hazards identification
2.0 Classification of the complete product GHS03 GHS05 GHS07 GHS08
Signal word
DANGER Hazard classes/categories H272 Ox. Sol. 2 H290 Met. Corr. 1 H303 Acute Tox. 5 oral (non EU) H314 Skin Corr. 1A H315 Skin Irrit. 2 H316 Skin Irrit. 3 (non EU) H317 Skin Sens. 1 H319 Eye Irrit. 2 H334 Resp. Sens. 1 H335 STOT SE 3 Classification of the substance or mixture mg Nickel 7, lyophilizied (R0) GHS03 GHS07 GHS08 DANGER Hazard identification Hazard classes/categories H272 Ox. Sol. 2 H303 Acute Tox. 5 oral (non EU) H315 Skin Irrit. 2 H316 Skin Irrit. 3 (non EU) H317 Skin Sens. 1 H319 Eye Irrit. 2 H334 Resp. Sens. 1 H335 STOT SE 3 Sprache noch nicht definiert! GHS05 DANGER Hazard identification Hazard classes/categories H290 Met. Corr. 1 H314 Skin Corr. 1A DANGER H317, H334 May cause an allergic skin reaction. May cause allergy or asthma symptoms or breathing difficulties if inhaled. P261sh, P280sh, P342+311 Avoid breathing dust/vapours. Wear protective gloves/eye protection. If experiencing respiratory symptoms: Call a POISON CENTER/doctor. Sprache noch nicht definiert! GHS05 DANGER H314 Causes severe skin burns and eye damage. P260sh, P280sh, P303+361+353, P305+351+338, P310 Do not breathe dust/vapours. Wear protective gloves/eye protection. IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water [or shower]. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Immediately call a POISON CENTER/doctor.
2.2 Label elements
According CLP directive inner packages must be only labelled with GHS symbol(s) and product identificator(s) (EU 1272/2008 Annex I - 1.5.1.2). Inner packages up to 10 mL need max. 2 symbols (Annex I - 1.5.2.4.1 / 2). Harmful chemicals/mixtures with signal word: WARNING must not be labelled with H and P phrases until 125 mL (EU 1272/2008 Annex I - 1.5.2). This labelling exemption is NOT valid for sensibilizing substances. Oxidizing mixtures with signal word: DANGER and H272 must not be labelled with H and P phrases until 125 mL . Metal corrosive solutions do not have to be labelled with GHS symbol, signal word, H and P phrases until 125 mL (EU 1272/2008 Annex I - 1.5.2.1.3). 10 mg Nickel 7, lyophilizied (R0) GHS03 GHS07 GHS08
2.3 Other hazards
Possible hazards from physicochemical properties Generally in the case of pH values are less than 2 or higher than 11.5 then it is corrosive. In the case of pH values are less than 5 or higher than 9 then it is irritant. H290 "May be corrosive to metals." has only relevance for higher concentrations and larger amounts. The labelling GHS05 would be creating an "OVERLABELLING" (see GHS Directive 1272/2008/EC Annex I, chapter 1.5.2.1.3., until 125 mL no labelling necessary). --- Information pertaining to particular risks to human and possible symptoms Causes varying degrees of acid burns on the skin, to the eyes and to the mucous membranes and wounds which do not heal quickly depending on the concentration, temperature and the exposure time. Vapours especially which steam from hot liquids and mist can have a severe irritant effect upon the eyes and the respiratory organs. Cause after inhalation of vapours/dust, skin contact, impairments of health when ingested in small quantities. May cause sensitization by skin contact, also in repeated contact of small amounts. May cause allergy or asthma symptoms or breathing difficulties if inhaled. - Information pertaining to particular risks to the environment Avoid contact of substance/mixture to environment.
PBT Substances
not applicable
vPvB Substances
not applicable
Other hazards
---
2.1 Classification of the substance or mixture
10 mg Nickel 7, lyophilizied (R0) GHS03 GHS07 GHS08 Signal word DANGER Hazard identification Hazard classes/categories H272 Ox. Sol. 2 H303 Acute Tox. 5 oral (non EU) H315 Skin Irrit. 2 H316 Skin Irrit. 3 (non EU) H317 Skin Sens. 1 H319 Eye Irrit. 2 H334 Resp. Sens. 1 H335 STOT SE 3 Sprache noch nicht definiert! GHS05 Signal word DANGER Hazard identification Hazard classes/categories H290 Met. Corr. 1 H314 Skin Corr. 1A